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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 下载免费PDF全文
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
用 1 5个随机引物对建鲤基因组DNA进行RAPD分析 ,结果显示 ,建鲤群体内的遗传相似系数为 0 91 81± 0 0 73 8,多态位点比例为 0 41 67,平均杂合度为 0 1 884。表明建鲤种质较纯 ,群体内的遗传变异程度较小。建鲤优良性状产生的分子学基础是等位基因的杂合程度较高 相似文献
3.
在回转椭球状降水粒子的假设下求出了降水粒子的散射截面,并且考虑了粒子轴线铅垂和随机取向两种重要的典型情况;推导了双极化雷达的回波方程以及降雨量公式。该方程除包含降水粒子的信息外,关于雷达与降水粒子间的几何关系都以雷达天线仰角及雷达与降水粒子间的距离表示,同时还考虑了地球的球面效应和大气折射效应。由于采用了并矢方法,使推导简捷明了 相似文献
4.
海岩的长篇小说《河流如血》再创出版高记录,但作家仍局限于特有的小说叙述模式,这部作品设能做到相应的创新。概言之,模式第一面是“刑侦+恋爱”;模式第二面是“财子+佳人”;模式第三面是“道德+法制”。文学创作需要不断创新,创新的过程也是对创作模式的不断突破过程。作家应该警惕的是,不要让模式成为创作的桎梏。 相似文献
5.
JIANGDong WANGNai-bin YANGXIao-huan WANGJi-hua 《中国地理科学(英文版)》2003,13(1):62-65
Daily and ten-day Normalized Difference Vegetation Index(NDVI) of crops were retrieved from meteorological statellite NOAA AVHRR images ,The temporal variations of the NDVI were analyzed during the whole growing season,and thus the principle of the interaction between NDIV profile and the growing status of crops was discussed,As a case in point,the relationship between integral NDVI and winter wheat yield of Henan Province in 1999 had been analyzed.By putting integral NDVI values of 60 sample counties into the winter wheat yield-integral NDVI coordination,scattering map was plotted. It demonstrated that integral NDVI had a close relation with winter wheat yield.These relation could be described with linear,cubic polynomial ,and exponential regression,and the cubic polynomial regression was the best way,In general ,NDVI reflects growing status of green vegetation ,so crop monitoring and crop yield estimation could be realized by using remote sensing technique on the basis of time serial NDVI data together with agriculture calendars. 相似文献
6.
Tidal effects on temperature front in the Yellow Sea 总被引:5,自引:0,他引:5
Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades
in autumn as thermocline declines. TF intensity ⋎S
T
⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution
in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results
are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming
and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the
TF.
Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No.
49736190). 相似文献
7.
PALEOSOLSOFSANDYLANDSANDENVIRONMENTALCHANGESINTHEWESTERNPARTOFNORTHEASTPLAINOFCHINAWESTERNDURINGHOLOCENE¥QiuShanwen(裘善文)LiQus... 相似文献
8.
In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series. 相似文献
9.
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