排序方式: 共有33条查询结果,搜索用时 62 毫秒
1.
2.
3.
4.
5.
Pyrheliometer measurements have been carried out at the Physikalisches-Meteorologisches Observatorium Davos from 1909 to present which results in the longest stationary direct irradiance record worldwide. A variety of different instruments and measurement scales were homogenized and adjusted to the World Radiometric Reference. Following the pyrheliometric ratioing technique, a time?Cseries of apparent atmospheric transmission was calculated and analyzed for possible trends in column transparency over Davos. In order to assess the trend found in the transmission record, the long-term annual cycle in apparent atmospheric transmission was used to deseasonalize the daily transmission data. The trends of early brightening, dimming and brightening were localized and found to be small but highly significant. 相似文献
6.
Natacha Pasche Georges Alunga Keely Mills Fabrice Muvundja David B. Ryves Michael Schurter Bernhard Wehrli Martin Schmid 《Journal of Paleolimnology》2010,44(4):931-946
This study interprets the recent history of Lake Kivu, a tropical lake in the East African Rift Valley. The current gross
sedimentation was characterized from a moored sediment trap array deployed over 2 years. The past net sedimentation was investigated
with three short cores from two different basins. Diatom assemblages from cores were interpreted as reflecting changes in
mixing depth, surface salinity and nutrient availability. The contemporary sediment trap data indicate seasonal variability,
governed by diatom blooms during the annual mixing in the dry season, similar to Lakes Malawi and Tanganyika. The ratio of
settling fluxes to net sediment accumulation rates implies mineralization rates of 80–90% at the sediment-water interface.
The sediment cores revealed an abrupt change ~40 years ago, when carbonate precipitation started. Since the 1960s, deep-water
methane concentrations, nutrient fluxes and soil mineral inputs have increased considerably and diatom assemblages have altered.
These modifications probably resulted from a combination of three factors, commonly altering lake systems: the introduction
of a non-native fish species, eutrophication, and hydrological changes inducing greater upwelling. Both the fish introduction
and increased rainfall occurred at the time when the onset of carbonate precipitation was observed, whereas catchment population
growth accompanied by intensified land use increased the flux of soil minerals already since the early twentieth century due
to more intense erosion. 相似文献
7.
8.
9.
Tobias Schaller H. Christoph Moor Bernhard Wehrli 《Aquatic Sciences - Research Across Boundaries》1997,59(4):326-344
In Baldeggersee, the distributions of solid phase Fe, Mn, V, Cr, As and Mo were determined in different sediment strata, deposited
under various deep-water oxygen conditions. Iron concentrations are correlated with water depth when an anoxic sediment is
in contact with an oxic water column. Benthic redox gradients trigger iron transport towards the deepest site (geochemical
focusing) and loss of iron from the shallower parts through the outflow. Fe cycling in the lake is inhibited by oxygen penetration
into the sediment. Vanadium and arsenic can be used as tracers for the internal Fe cycle. Their distribution patterns are
highly correlated with iron. In case of a stable oxycline in the deep water, Mo is enriched in the sediment and correlates
with Mn. The horizontal distribution patterns of Fe, V, As and the correlation of Fe and Mn with trace metals are promising
proxy indicators for the reconstruction of deep-water oxygen conditions during deposition. 相似文献
10.
Analysis of the Major Fe Bearing Mineral Phases in Recent Lake Sediments by EXAFS Spectroscopy 总被引:1,自引:0,他引:1
Extended X-ray absorption fine structure (EXAFS) spectroscopy and chemical analyses were combined to determine the Fe bearing minerals in recent lake sediments from Baldeggersee (Switzerland). The upper section of a laminated sediment core, deposited under eutrophic conditions, was compared to the lower part from an oligotrophic period. Qualitative analysis of FeK EXAFS agreed well with chemical data: In the oligotrophic section Fe(II)–O and Fe(III)–O specieswere present, whereas a significant fraction of Fe(II)–S sulfides was strongly indicated in the eutrophic part. A statistical analysis was performed by least square fitting of normalized reference spectra. The set of reference minerals included Fe(III) oxides and Fe(II) sulfides, carbonates and phosphates. In the oligotrophic regime no satisfying fit was obtained using the set of reference spectra, indicating that siderite (FeCO3) was not present in a significant amount in these carbonate-rich sediments. Simulated EXAFS spectra for a(Cax, Fe1-x)CO3solid solution allowed reconstructing the specificfeatures of the experimental spectra, suggesting that this phase was the dominant Fe carrier in the oligotrophic section of the core. In the eutrophic part, mackinawite was positively identified and represented the dominant Fe(II) sulfide phase. This finding agreed with chemical extraction, which indicated that18–40 mol% of Fe was contained in the acid volatile iron sulfide fraction. EXAFS spectra of the eutrophic section were best fitted by considering the admixture of mackinawite and the Fe–Ca carbonate phase inferred to be predominant in the oligotrophic regime. 相似文献