Structural modifications of CaGeO3-wollastonite under room temperature pressurization

 In-situ X-ray diffraction measurements of CaGeO₃-wollastonite at high pressure at room temperature have been performed using a diamond anvil cell with an X-ray source. A new structural modification of CaGeO₃-wollastonite is observed at about 6GPa and the characteristic reflections of the high pressure form are preserved on decompression to an ambient pressure. A rhodonite-like structure is proposed as a high pressure form from the crystal chemical consideration. The rhodonite-like phase is further transformed into a perovskite-form at about 15 GPa. The rhodonite-like-form of CaGeO₃ seems not to be a stable phase from the heating experiments under high pressures. The metastable transition path from the wollastonite to the perovskite polymorph through the rhodonite-like structure is kinetically favored under room temperature pressurization. No pressure-induced amorphization is observed during the transition into the perovskite-form, although the transition is accompanied by the coordination change of Ge atoms from fourfold to sixfold. Received: July 19, 1995 / Revised, accepted: August 1996     

Gamma-ray probe of cosmic ray pressure in galaxy clusters and cosmological implications

Cosmic rays produced in cluster accretion and merger shocks provide pressure to the intracluster medium (ICM) and affect the mass estimates of galaxy clusters. Although direct evidence for cosmic ray ions in the ICM is still lacking, they produce γ-ray emission through the decay of neutral pions produced in their collisions with ICM nucleons. We investigate the capability of the Gamma-ray Large Area Space Telescope ( GLAST ) and imaging atmospheric Čerenkov telescopes (IACTs) for constraining the cosmic ray pressure contribution to the ICM. We show that GLAST can be used to place stringent upper limits, a few per cent for individual nearby rich clusters, on the ratio of pressures of the cosmic rays and thermal gas. We further show that it is possible to place tight (≲10 per cent) constraints for distant  ( z ≲ 0.25)  clusters in the case of hard spectrum, by stacking signals from samples of known clusters. The GLAST limits could be made more precise with the constraint on the cosmic ray spectrum potentially provided by IACTs. Future γ-ray observations of clusters can constrain the evolution of cosmic ray energy density, which would have important implications for cosmological tests with upcoming X-ray and Sunyaev–Zel'dovich effect cluster surveys.     

A hypothesis of the Senoumi submarine megaslide in Suruga Bay in Japan—based on the undrained dynamic-loading ring shear tests and computer simulation

The distinctive bathymetric feature exists in the Suruga Bay, Japan. It has been called as Senoumi (Stone flower sea) from old times. Senoumi is a 30?km wide and 20?km long concave feature. Its origin has not been explained yet; however, the feature might be a combined consequence of intensive tectonic activity in the plate border, landslides, and a submarine flow coming from the Oi River. If the Senoumi was caused by a landslide, the latter would be larger than any on-land landslide in Japan. The downshelf “exit” from this feature is much narrower than its central part. This is not usual shape of landslides, but it is similar to the liquefied landslides such as those in quick clays which mobilize great strength reduction after failure. To study Senoumi as a landslide, the shear behaviors of the following three soil samples were investigated by the cyclic and seismic undrained stress control ring shear tests. One sample is volcanic ash taken from the base of landslide deposits (mass transport deposits), from 130 to 190?m deep layer below the submarine floor which was drilled and cored by the Integrated Ocean Drilling Program Expedition 333. Another two samples are the Neogene silty–sand and silt taken from the Omaezaki hill adjacent to the Senoumi, because the shear zone might have been formed in Neogene layers extending from on-land to the continental shelf. The largest strength reduction from peak to steady-state shear resistance in the undrained cyclic loading test was found in volcanic ash. The strength reduction in Neogene silty–sand was smaller than volcanic ash, while the Neogene silt mobilized the least post-failure strength reduction. An integrated model simulating the initiation and motion of earthquake-induced rapid landslides (landslide simulation (LS)-RAPID, Sassa et al. Landslides 7–3:219–236, 2010) was applied to this study. The steady-state shear resistance and other geotechnical parameters measured by the undrained ring shear tests and the greatest strong motion record in the 2011 off-the-Pacific Coast of Tohoku earthquake (M _w 9.0), also known as “2011 Tohoku Earthquake” at the observation point MYG004 (2,933?gal) were input to this model. As the result, it was found that landslides would be triggered by 0.30–1.0 times of MYG004 in volcanic ash, 0.4–1.0 times of MYG004 in Neogene silty–sand and Neogene silt, though the depth and area of triggered landslides were different in soils and intensity of shaking. Feature, created by LS-RAPID using the parameters of volcanic ash, was most similar to the Senoumi in depth and extent. The result obtained from this study includes a hypothesis to be proved, but presents the strong need to investigate the risk of the large-scale submarine landslides which could enhance tsunami wave and possibly enlarge the submarine landslide retrogressively into the adjacent coastal plain by the upcoming mega earthquake in the Nankai Trough.     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.     

Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.     

Differences in abundance and distribution of Alexandrium cysts in Sendai Bay,northern Japan,before and after the tsunami caused by the Great East Japan Earthquake

The tsunami caused by the Great East Japan Earthquake on 11 March 2011 greatly influenced the coastal benthic environment on the northern Pacific coast of Japan. We used the direct count method to investigate changes in the abundance and distribution of Alexandrium (Alexandrium tamarense and Alexandrium catenella) cysts before and after the tsunami in Sendai Bay. Densities of Alexandrium cysts in sediments collected in summer 2011 ranged from 0 to 8,190 cysts cm^?3. In the western part of the bay, the density increased greatly after the tsunami, the highest density being approximately 10 times the density recorded in 2005. Molecular identification of single cysts with multiplex polymerase chain reaction (PCR) showed that Alexandrium tamarense dominated the cyst population in the southwestern part of the bay in 2011. Furthermore, accumulation of cysts on the surface sediment after disturbance of the sediment was confirmed by a laboratory experiment. The main factor causing the drastic changes in abundance and distribution of Alexandrium cysts after the earthquake was considered to be vertical and horizontal redistribution of the cysts in sediments after the tsunami.     

Evolution of electron and proton temperatures in a flaring loop

We have investigated numerically how a temperature difference between electrons and protons is produced in a flaring loop by adopting a one-fluid, two-temperature model instead of a single-temperature model. We have treated a case in which flare energy is released in the form of heating of electrons located in the top part of the loop.In this case, a large temperature difference (T _e/T _p 10) appears in the corona in the energy-input phase of the flare. When the material evaporated from the chromosphere fills the corona, the temperature difference in the loop begins to shrink rapidly from below. Eventually, in the loop apex, the proton temperature exceeds the electron temperature mainly due to cooling of the electrons by conduction down the loop and heating of the protons by compression of the ascending material. In the late phase of the flare (t 15 min from the flare onset), the temperature difference becomes less than 2% of the mean temperature of electrons and protons at every point in the loop.     

Fluid Inclusion Study and Opaque Mineral Assemblage at the Deep and Shallow Part of the Batu Hijau Porphyry Copper-gold Deposit, Sumbawa, Indonesia

The Batu Hijau deposit is the only porphyry type deposit in production in the Sunda‐Banda arc, Indonesia. This study discusses the reason for the localization of copper grade at the deep part of the deposit based on the observation of opaque mineral assemblage. In addition, the formation condition of quartz veins and opaque minerals is discussed on the basis of the fluid inclusion microthermometry. Samples were selected from drill holes SBD100, SBD168, SBD194, SBD254, and SBD257 to cover the wide vertical range. At the Batu Hijau deposit, quartz veins have been classified mainly into four types called A, B, C and D veins, and the A veins contain mainly bornite, often associated with digenite and chalcocite. In addition, magnetite occurs in A veins. However, at the deep part of the deposit, there are quartz veins associated with magnetite, but few copper sulfides such as bornite and chalcopyrite in quartz veins, as observed in SBD257. Quartz veins at depth in SBD257 have abundant magnetite and pyrite. Pyrite in quartz veins at depth in SBD257 mainly occur at the rim of magnetite grains or interstices between them. In quartz veins in SBD254, there are abundant copper sulfides such as bornite and chalcopyrite in spite of the depth. Bornite and chalcopyrite occur as inclusions in magnetite grains in quartz veins in SBD254. Pyrite which often occurs in low grade zone in quartz veins in SBD254 is also recognized at the rims of copper sulfides. This indicates that pyrite in SBD257 and SBD254 formed later than magnetite. On the other hand, blebs of bornite and chalcopyrite inclusions in magnetite grains, which are recognized in quartz veins in SBD168 at shallow high grade part, suggest that the hydrothermal fluid, from which magnetite was deposited also brought the copper sulfides such as bornite and chalcopyrite to the deep part of the Batu Hijau deposit. Therefore, it is concluded that initially the high grade ore zone extended to depth without localization. However due to the later overprinting hydrothermal activity, copper sulfides and magnetite were replaced or dissolved and pyrite was formed, resulting the low grade zone at the deep part of the deposit. Dissolution temperatures (Td) of halite obtained by from fluid inclusion microthermometry show significant differences between SBD168 and other drill holes. The high Td obtained in SBD168 may indicate larger volume of NaCl crystals in hydrothermal fluid at the time of entrapment of the fluid inclusions and formation of other opaque minerals such as magnetite and copper‐iron sulfides. It suggests that the ratio of vapor to brine is also higher at the shallow part of the deposit. The higher vapor to brine ratio may suggest a higher degree of boiling. Removal of vapor phase separated from brine during boiling increases the concentration of substances dissolved in the brine, and this will result in saturation, as evidenced by the salinity and NaCl saturation. The higher degree of boiling suggested by the higher vapor to brine ratio at shallow part may have increased the copper concentration in the brine that may have lead the saturation, resulted in the deposition of copper‐bearing minerals.     

Neodymium isotopic variations in Northwest Pacific waters

Four vertical profiles of the concentration and isotopic composition of Nd in seawater were obtained in the western North Pacific. Two profiles from the Kuroshio Current regime showed congruently that although the Nd concentration increases gradually with depth, its isotopic composition varies significantly with depth depending upon the water mass occupying the water column. The high-salinity Kuroshio waters originating from the North Pacific Tropical Water (NPTW) carry the least radiogenic Nd (?_Nd = −7.4 to −8.7) to this region at ∼250 m from the western margin continental shelves, most likely from the East China Sea. The Nd isotopic compositions in the North Pacific Intermediate Water (NPIW) that occurs at 600 to 1000 m in the subtropical region are fairly uniform at ?_Nd = −3.7. The profile data from the ∼38° to 40°N Kuroshio/Oyashio mixed water region off Sanriku of Honshu, Japan, also suggest that the newest NPIW with ?_Nd = −3.2 is formed there by the mixing of various source waters, and the radiogenic component of Nd is derived mainly from the Oyashio waters.In the Pacific Deep Water (PDW) below ∼1000 m, the Nd isotopic composition is neither vertically nor horizontally homogeneous, suggesting that it serves as a useful tracer for sluggish deep water circulation as well. Two profiles from the Izu-Ogasawara Trench showed a minimum ?_Nd value at ∼2000 m, suggesting that there exists a horizontal advective flow in the vicinity of Honshu, Japan. There is some evidence from other chemical properties to support this observation. The waters below 4000 m including those within the trench in the subtropical region have ?_Nd values of around −5, suggesting that the deep waters are fed from the south along the western boundary, ultimately from the Antarctic Bottom Water (AABW) in the South Pacific. This extends up to ∼40°N along the Japanese Islands. In the subarctic region (>∼42°N), the waters have more radiogenic Nd with ?_Nd > −4.0 throughout the water column, presumably due to the supply of Nd by weathering in such igneous provinces as the Kuril-Kamchatska-Aleutian Island chain. The lateral inhomogeneity of the Nd isotopic composition in PDW suggests that there may be different circulation and mixing regimes in the North Pacific Basin.     

Middle Permian radiolarians from Anmenkou, Chaohu, Northeastern Yangtze platform, China

The biostratigraphy of the Middle Permian Gufeng Formation in the northeastern Yangtze platform is examined based on radiolarians. This study is concentrated on the Anmenkou section in the Chaohu area of Anhui Province, China. The Gufeng Formation is divided into the Phosphate Nodule-bearing Mudstone Member (PNMM) and the Siliceous Rock Member (SRM) in ascending order. The former primarily consists of mudstone including abundant phosphate nodules, and the latter consists mainly of alternating beds of chert, siliceous mudstone and mudstone, with intercalations of porous chert. Ammonoids in the mudstone of the lower PNMM are Wordian. Chert, siliceous mudstone and mudstone of the SRM include abundant radiolarians with sponge spicule assemblages suggestive of the Wordian–Capitanian. Albaillellaria are predominant in the lower SRM, while Entactinaria and Spumellaria are predominant in the middle and upper SRM. These radiolarians correspond to three radiolarian assemblage zones: Pseudoalbaillella longtanensis – Pseudoalbaillella fusiformis , Follicucullus monacanthus , and Follicucullus scholasticus – Ruzhencevispongus uralicus . The assemblage of radiolarians and sponge spicule fauna suggests a depositional depth of 150–500 m. The radiolarian fauna of the Gufeng Formation is considered to be representative of the relatively shallow, tropical radiolarian fauna of the Middle Permian eastern Paleotethys.