Re-Os isotope systematics and fractionation of siderophile elements in metal phases from CBa chondrites

We report Os isotope compositions of metal grains in two CB_a chondrites (Bencubbin and Gujba) determined using a micromilling sampling coupled with thermal ionization mass spectrometry, together with the abundances of major and trace siderophile elements obtained by electron probe microanalysis and femtosecond laser ablation inductively coupled plasma–mass spectrometry. The CB_a metal grains presented ¹⁸⁷Os/¹⁸⁸Os ratios akin to carbonaceous chondrites with limited variations (0.1257–0.1270). Most of the CB_a metal grains were scattered along a ¹⁸⁷Re-¹⁸⁷Os reference isochron of IIIAB iron meteorites, indicating that the CB_a metals experienced limited Re-Os fractionation at the time of their formation. The Re/Os ratios of sampling spots for the CB_a metals, recast from the observed ¹⁸⁷Os/¹⁸⁸Os ratios, had a positive correlation with their Os/Ir ratios. In addition, the metal grains showed a positive correlation in a Pd/Fe versus Ni/Fe diagram. These correlations suggest that the CB_a metal grains have formed via equilibrium condensation or evaporation from a gaseous reservoir at ~10⁻⁴ bar with enhanced metal abundances. Compared to the Bencubbin metals, the Gujba metals are characterized by having systematically lower Pd/Fe and Ni/Fe ratios that span subchondritic values. Such a difference was most likely induced by the compositionally heterogeneous impact plume from which the metals were condensed.     

Molecular-scale mechanisms of distribution and isotopic fractionation of molybdenum between seawater and ferromanganese oxides

The distribution of Mo between seawater and marine ferromanganese oxides has great impacts on concentration and isotopic composition of Mo in modern oxic seawater. To reveal the adsorption chemistry of Mo to ferromanganese oxides, we performed (i) detailed structural analyses of Mo surface complexes on δ-MnO₂, ferrihydrite, and hydrogenetic ferromanganese oxides by L₃- and K-edge XAFS, and (ii) adsorption experiments of Mo to δ-MnO₂ and ferrihydrite over a wide range of pHs, ionic strengths, and Mo concentrations. XAFS analyses revealed that Mo forms distorted octahedral (Oh) inner-sphere complexes on δ-MnO₂ whereas it forms a tetrahedral (Td) outer-sphere complex on ferrihydrite. In the hydrogenetic ferromanganese oxides, the dominant host phase of Mo was revealed to be δ-MnO₂. These structural information are consistent with the macroscopic behaviors of Mo in adsorption experiments, and Mo concentration in modern oxic seawater can be explained by the equilibrium adsorption reaction on δ-MnO₂. In addition, the large isotopic fractionation of Mo between seawater and ferromanganese oxides detected in previous studies can be explained by the structural difference between and adsorbed species on the δ-MnO₂ phase in ferromanganese oxides. In contrast, smaller fractionation of Mo isotopes on ferrihydrite is due to little change in the Mo local structures during its adsorption to ferrihydrite.The structures of Mo species adsorbed on crystalline Fe (oxyhydr)oxides, goethite, and hematite were also investigated at pH 8 and I = 0.70 M (NaNO₃). Our XAFS analyses revealed that Mo forms inner-sphere complexes on both minerals: Td edge-sharing (46%) and Oh double corner-sharing (54%) for goethite, and Td double corner-sharing (14%) and Oh edge-sharing (86%) for hematite. These structural information, combined with those for amorphous ferrihydrite and δ-MnO₂, show the excellent correlation with the magnitude of adsorptive isotopic fractionation of Mo reported in previous studies: the proportion of Oh species or their magnitude of distortion in Mo surface complexes become larger in the order of ferrihydrite < goethite < hematite < δ-MnO₂, a trend identical to the magnitude of isotopic fractionation.Based on the comparison with previous reports for Mo surface species on various oxides, the chemical factors that affect Mo surface complex structures were also discussed. The hydrolysis constant of cation in oxides, log K_OH (or the acidity of the oxide surfaces, PZC) is well correlated with the mode of attachment (inner- or outer-sphere) of Mo surface complexes. Furthermore, the symmetric change in Mo species from Td to Oh is suggested to be driven by the formation of inner-sphere complexes on specific sites of the oxide surfaces.     

Effects of changes in canopy interception on stream runoff response and recovery following clear-cutting of a Japanese coniferous forest in Fukuroyamasawa Experimental Watershed in Japan

Understanding changes in evapotranspiration during forest regrowth is essential to predict changes of stream runoff and recovery after forest cutting. Canopy interception (Ic) is an important component of evapotranspiration, however Ic changes and the impact on stream runoff during regrowth after cutting remains unclear due to limited observations. The objective of this study was to examine the effects of Ic changes on long-term stream runoff in a regrowth Japanese cedar and Japanese cypress forest following clear-cutting. This study was conducted in two 1-ha paired headwater catchments at Fukuroyamasawa Experimental Watershed in Japan. The catchments were 100% covered by Japanese coniferous plantation forest, one of which was 100% clear-cut in 1999 when the forest was 70 years old. In the treated catchment, annual runoff increased by 301 mm/year (14% of precipitation) the year following clear-cutting, and remained 185 mm/year (7.9% of precipitation) higher in the young regrowth forest for 12–14 years compared to the estimated runoff assuming no clear-cutting. The Ic change was −358 mm/year (17% of precipitation) after cutting and was −168 mm/year (6.7% of precipitation) in the 12–14 years old regrowth forest compared to the observed Ic during the pre-cutting period. Stream runoff increased in all seasons, and the Ic change was the main fraction of evapotranspiration change in all seasons throughout the observation period. These results suggest that the change in Ic accounted for most of the runoff response following forest cutting and the subsequent runoff recovery in this coniferous forest.     

State Estimation of the North Pacific Ocean by a Four-Dimensional Variational Data Assimilation Experiment

A four-dimensional variational data assimilation system has been applied to an experiment to describe the dynamic state of the North Pacific Ocean. A synthesis of available observational records and a sophisticated ocean general circulation model produces a dynamically consistent dataset, which, in contrast to the nudging approach, provides realistic features of the seasonally-varying ocean circulation with no artificial sources/sinks for temperature and salinity fields. This new dataset enables us to estimate heat and water mass transports in addition to the qualification of water mass formation and movement processes. A sensitivity experiment on our assimilation system reveals that the origin of the North Pacific Intermediate Water can be traced back to the Sea of Okhotsk and the Bering Sea in the subarctic region and to the subtropical Kuroshio region further south. These results demonstrate that our data assimilation system is a very powerful tool for the identification and characterization of ocean variabilities and for our understanding of the dynamic state of ocean circulation. This revised version was published online in July 2006 with corrections to the Cover Date.     

The 11 March 2011 Tohoku Tsunami Survey in Rikuzentakata and Comparison with Historical Events

On 11 March 2011, a moment magnitude M _w = 9.0 earthquake occurred off the Japan Tohoku coast causing catastrophic damage and loss of human lives. In the immediate aftermath of the earthquake, we conducted the reconnaissance survey in the city of Rikuzentakata, Japan. In comparison with three previous historical tsunamis impacting the same region, the 2011 event presented the largest values with respect to the tsunami height, the inundation area and the inundation distance. A representative tsunami height of 15 m was recorded in Rikuzentakata, with increased heights of 20 m around rocky headlands. In terms of the inundation area, the 2011 Tohoku tsunami exceeded by almost 2.6 times the area flooded by the 1960 Chilean tsunami, which ranks second among the four events compared. The maximum tsunami inundation distance was 8.1 km along the Kesen River, exceeding the 1933 Showa and 1960 Chilean tsunami inundations by factors of 6.2 and 2.7, respectively. The overland tsunami inundation distance was less than 2 km. The tsunami inundation height linearly decreased along the Kesen River at a rate of approximately 1 m/km. Nevertheless, the measured inland tsunami heights exhibit significant variations on local and regional scales. A designated “tsunami control forest” planted with a cross-shore width of about 200 m along a 2 km stretch of Rikuzentakata coastline was completely overrun and failed to protect the local community during this extreme event. Similarly, many designated tsunami shelters were too low and were overwashed by tsunami waves, thereby failing to provide shelter for evacuees—a risk that had been underestimated.     

Predicting the displacement of triple pendulum™ bearings in a full‐scale shaking experiment using a three‐dimensional element

The accuracy of a series spring model to predict the peak displacement and displacement history of Triple Pendulum? (TP) bearings in a strongly shaken, full‐scale building is evaluated in this paper. The series spring model was implemented as a self‐contained three‐dimensional TP bearing element in OpenSees and is now available for general use. The TP bearing element contains the option for constant friction or a generalized friction model that accounts for the effect of instantaneous velocity and compression load on the friction coefficient. Comparison between numerical simulation and experimental data of a five‐story steel moment frame building shows that the peak displacement of isolation system can generally be predicted with confidence using a constant friction coefficient model. The friction coefficient model accounting for the effect of axial load and velocity leads to minor improvement over the constant friction coefficient models in some cases. Copyright © 2013 John Wiley & Sons, Ltd.     

A new photographic method for mapping lunar eclipse shadow

A new photographic method suitable for digital processing of a two-dimensional density distribution of lunar eclipse shadow has been developed and it has been applied to the observation of the eclipse of December 30, 1982. The principle of this method is to extract the terrestrial shadow by utilizing immediate post- or pre-eclipse full Moon image as a reference template. The uncertainties of the obtained shadow maps in density and position are mostly 0.03–0.05 and 10–15 respectively. Iso-density contours of the penumbra have revealed unknown systematic deviations from a geometrical (concentric) shadow model in terms of their directions of center and radii of curvature. A density map of the umbra has shown very irregular shapes of isophotoes and density variation in the outer umbra has been proved to be consistent with the optical depth measurement of the stratosphere performed in the same period of time with lidars and aircrafts. Geographic consideration of the shadow terminator on the Earth suggests that the remnant aerosols above the northern Pacific and northern Europe flown up by a Mexican volcano 8 months ago prior to this eclipse will be mainly responsible for the formation of such variation of density in the outer penumbra.On leave from Tokyo Astronomical Observatory as Visiting Scientist (from 28 Aug. 1984 to 27 Aug. 1985).     

A comparison of neighbourhood relations based on ordinary Delaunay diagrams and area Delaunay diagrams: an application to define the neighbourhood relations of buildings

ABSTRACT

The aim of this article is to describe a convenient but robust method for defining neighbourhood relations among buildings based on ordinary Delaunay diagrams (ODDs) and area Delaunay diagrams (ADDs). ODDs and ADDs are defined as a set of edges connecting the generators of adjacent ordinary Voronoi cells (points representing centroids of building polygons) and a set of edges connecting two centroids of building polygons, which are the generators of adjacent area Voronoi cells, respectively. Although ADDs are more robust than ODDs, computation time of ODDs is shorter than that of ADDs (the order of their computation time complexity is O(nlogn)). If ODDs can approximate ADDs with a certain degree of accuracy, the former can be used as an alternative. Therefore, we computed the ratio of the number of ADD edges to that of ODD edges overlapping ADDs at building and regional scales. The results indicate that: (1) for approximately 60% of all buildings, ODDs can exactly overlap ADDs with extra ODD edges; (2) at a regional scale, ODDs can overlap approximately 90% of ADDs with 10% extra ODD edges; and (3) focusing on judging errors, although ADDs are more accurate than ODDs, the difference is only approximately 1%.     

Development of a 2-km resolution ocean model covering the coastal seas around Japan for operational application

Ocean Dynamics - In order to expand the coastal ocean monitoring and forecasting system of the Japan Meteorological Agency from the Seto Inland Sea to the entire coastal seas of Japan, a 2-km...