Search for Young Giant Planets with the Subaru 8-Meter Telescope: Instrument and Strategy

Earth, Moon, and Planets -     

Low-temperature single crystal reflection spectra of forsterite

The infrared reflectivities of crystalline forsterite (Mg₂SiO₄) were measured for the temperature range 295–50 K for each crystal axis, between wavenumber 5000 and 100 cm⁻¹. The reflection spectra show clear dependence of temperature; most of the bands become more intense, sharper and their peak positions shift to higher wavenumber with decreasing temperature. Reflection spectra were fitted with dispersion formula of damped oscillator model of the dielectric constants and the oscillator parameters in the model were derived. The absorption spectra of forsterite particle are calculated with the derived dielectric constants to show that the forsterite features are good thermal indicator for cold temperature range below 295 K.     

Laboratory experiments and thermal calculations for the development of a next-generation glacier-ice exploration system: Development of an electro-thermal drilling device

A next-generation drilling system, equipped with a thermal drilling device, is proposed for glacier ice. The system is designed to penetrate glacier ice via melting of the ice and continuously analyze melt-water in a contamination-free sonde. This new type of drilling system is expected to provide analysis data in less time and at less cost than existing systems. Because of the limited number of parameters that can be measured, the proposed system will not take the place of conventional drilling systems that are used to obtain ice cores; however, it will provide a useful method for quickly and simply investigating glacier ice.An electro-thermal drilling device is one of the most important elements needed to develop the proposed system. To estimate the thermal supply required to reach a target depth in a reasonable time, laboratory experiments were conducted using ice blocks and a small sonde equipped solely with heaters. Thermal calculations were then performed under a limited range of conditions. The experiments were undertaken to investigate the effects of the shape and material of the drill head and heater temperature on the rate of penetration into the ice. Additional thermal calculations were then performed based on the experimental results.According to the simple thermal calculations, if the thermal loss that occurs while heat is transferred from the heater to ice (in melting the ice) is assumed to be 50%, the total thermal supply required for heaters in the sonde and cable is as follows: (i) 4.8 kW (sonde) plus 0 W (cable) to penetrate to 300 m depth over 10 days into temperate glacier ice for which the temperature is 0 °C at all depths and to maintain a water layer along 300 m of cable; (ii) 10 kW (sonde) plus 19–32 kW (cable) to penetrate to 1000 m depth over 1 month into cold glacier ice for which the temperature is −25 °C at the surface and 0 °C at 1000 m depth and to maintain a water layer along 1000 m of cable; and (iii) 19 kW (sonde) plus 140–235 kW (cable) to penetrate to 3000 m depth over 2 months into an ice sheet for which the temperature is −55 °C at the surface and 0 °C at 3000 m depth and to maintain a water layer along 3000 m of cable. The thermal supply required for the cable is strongly affected by the thickness of the water layer, cable diameter, and the horizontal distance from the ice wall at which the ice temperature was maintained at its initial temperature. A large thermal supply is required to heat 3000 m of cable in an ice sheet (scenario (iii) above), but penetration into glacier ice (scenarios (i) and (ii) above) could be realistic with the use of a currently employed generator.     

Initial behavior of granite in response to injection of CO2-saturated fluid

To understand the initial reactions of granite in a CO₂-saturated hydrothermal system, experiments were conducted using a batch-type autoclave over a temperature range of 100–350 °C at up to 250 bar and numerical computations of phase equilibria based on the experimental results were carried out. The experiments showed that the dissolution of granite and the deposition of secondary minerals were encouraged by the addition of CO₂. Solution chemistry and examination of the granite’s surface texture suggested that its initial dissolution is characterized by the release of Na and Ca (from the dissolution of plagioclase) and that initial precipitation occurs by deposition of some secondary minerals on to plagioclase and/or biotite in the CO₂-saturated system. However, the effect of CO₂ was small at 350 °C owing to the low activity of H₂CO₃. According to EDX analysis and numerical phase equilibrium calculations, the secondary minerals formed might be kaolinite, muscovite, smectite and calcite. That is, the granite as a whole might have the potential to take-up dissolved CO₂. The results suggest that the alteration of granite under CO₂-saturated hydrothermal conditions has the potential to capture CO₂ when it is injected at moderate temperatures (150–250 °C) into granite-hosted rock masses.     

Factors Controlling the Fractionation and Seasonal Mobility Variations of Ga and In in Systems Impacted by Acidic Thermal Waters: Effects of Thermodynamics and Bacterial Activity

This work assessed both the fractionation and the seasonal mobility variations of Ga and In in systems impacted by acidic thermal waters. This was accomplished by performing thermodynamic calculations using the PHREEQC algorithm and by assessing the activity of acidophilic iron-oxidizing bacteria. The pH of the Kusatsu thermal waters in Gunma Prefecture, central Japan, is rapidly increased following the addition of a lime suspension. After an abrupt pH increase, under which conditions free ions of Ga and In and their complexes with Cl^? and SO₄^2? exist only in negligible quantities, the majority of dissolved Ga and In is removed by sorption onto suspended hydrous ferric oxides (HFOs). These HFOs are then transported to an artificial lake without significant sedimentation along the river. Subsequently, the suspended HFOs settle out and are added to sediments without significant fractionation between Ga and In. The Tamagawa thermal waters in Akita Prefecture, northeast Japan, are also treated with lime. However, complete neutralization requires mixing with some tributary streams, leading to a gradual downstream increase in pH. Dissolved Ga is, in general, sorbed by HFOs in upstream areas, leading to wide dispersal of Ga across the entire watershed. In comparison, In is transported to the lake inlet predominantly as a Cl^? complex species without significant removal along the river, with the majority being precipitated in an artificial lake, where Cl^? concentrations are too low to form stable complex species with In, and thus, dissolved In is sorbed by HFOs. As a result, In is effectively concentrated within downstream lakebed sediments, whereas Ga is dispersed along the river. Seasonal variations in Ga mobility within the Tamagawa field between snowmelt and low-flow seasons are primarily controlled by pH, because hydrolysis reactions of these metals, which are related to sorption reactions, tend to occur in the upstream regions in the snowmelt season. However, under warmer conditions, HFO formation preferably occurs due to the activity of acidophilic iron-oxidizing bacteria. Thus, under similar pH variations, dissolved Ga is more effectively removed by HFOs during warmer seasons. On the contrary, because HFOs are abundantly formed in low-flow season, even under colder conditions, before In hydrolysis reaction starts to occur, In mobility is less affected by water temperature and then bacterial activity.