The even-odd systematics inR-process nuclide abundances

We report and discuss solar systemN _R abundances for nuclidesA>70, obtained as differences between measured solar system abundances and calculatedS-process contributions. The abundance peak atA163 in the rare Earth element region reveals properties which are similar to those of theR-process peaks corresponding to magic neutron numbersN=82 andN=126. We observe that systematic differences in theN _R abundances of even-A and odd-A nuclides are restricted to specific mass regions. We discuss possible interpretations and conclude that these differences are most probably related to the properties of nuclear species during _– to the stability valley.... A genesis of the elements such as is sketched out would not be confined to our little Solar System, but would probably follow the same general sequence of events in every center of energy now visible as a Star. Sir William Crookes (1886)Paper dedicated to Professor Hannes Alfvén on the occasion of his 80th birthday, 30 May 1988.     

Response of earth and venus ionospheres to corotating solar wind stream of 3 July 1979

Corotating solar wind streams emanating from stable coronal structures provide an unique opportunity to compare the response of planetary ionospheres to the energy conveyed in the streams. For recurrent solar conditions the signal propagating outward along spiral paths in interplanetary space can at times exhibit rather similar content at quite different downstream locations in the ecliptic plane. Using solar wind measurements from plasma detectors on ISEE-3, Pioneer Venus Orbiter (PVO) and Helios-A, as well as in-situ ion composition measurements from Bennett Ion Mass Spectrometers on the Atmosphere Explorer-E and PVO spacecraft, corotating stream interactions are examined at Earth and Venus. During May–July 1979 a sequence of distinct, recurrent coronal regions developed at the Sun. Analysis of these regions and the associated solar wind characteristics indicates a corrresponding sequence of corotating streams, identifiable over wide distances. The time series of solar wind velocity variations observed at Earth, Venus, and the Helios-A positions during June–July attests to intervals of corotating stream propagation. The characteristics of the stream which passed Earth on July 3, are observed at Helios-A and at Venus (PVO) about 8 days later, consistent with the spiral path propagation delay times between the locations in the ecliptic plane. On July 3, Earth and Venus have a wide azimuthal separation of about 142 . Although the planetary environments are distinctly different, pronounced and somewhat analagous ionospheric responses to the stream passage are observed at both Earth and Venus. The response to the intercepted stream is consistent with independent investigations which have shown that the variability of the solar wind momentum flux is an important factor in the solar wind-ionosphere interaction at both planets.     

Propagation of MHD body and surface waves in magnetically structured regions of the solar atmosphere

The fact that magnetically structured regions exist in the solar atmosphere has been known for a number of years. It has been suggested that different kinds of magnetohydrodynamic (MHD) waves can be efficiently damped in these regions and that the dissipated wave energy may be responsible for the observed enhancement in radiative losses. From a theoretical point of view, an important task would be to investigate the propagation and dissipation of MHD waves in these highly structured regions of the solar atmosphere. In this paper, we study the behavior of MHD body and surface waves in a medium with either a single or double (slab) magnetic interface by use of a nonlinear, two-dimensional, time-dependent, ideal MHD numerical model constructed on the basis of a Lagrangean grid and semi-implicit scheme. The processes of wave confinement and wave energy leakage are discussed in detail. It is shown that the obtained results depend strongly on the type of perturbations imposed on the interface or slab and on the plasma parameter, . The relevance of the obtained results to the heating problem of the upper parts of the solar atmosphere is also discussed.     

Polar coronal plumes

Polar coronal plumes are modeled using concentrations of magnetic flux at 1.01R , and assuming the field is current-free, or a potential field. Identifying the density enhancement of plumes with magnetic flux concentration produces good agreement between 1.01R and 1.10R , for model conditions of a large background magnetic field and a plume separation of 50 000 to 70 000 km at the base. Beyond 1.10R , both plumes and the potential field diverge very nearly as r ².Also Department of Astrogeophysics, University of Colorado, Boulder, Colo. 80309, U.S.A. Presently visiting Stanford University Institute for Plasma Research, Via Crespi, Stanford, Calif. 94303, U.S.A.     

The effect of dissolved barium on biogeochemical processes at cold seeps

A numerical model was applied to investigate and quantify the biogeochemical processes fueled by the expulsion of barium and methane-rich fluids in the sediments of a giant cold-seep area in the Derugin Basin (Sea of Okhotsk). Geochemical profiles of dissolved Ba²⁺, Sr²⁺, Ca²⁺, SO₄²⁻, HS⁻, DIC, I⁻ and of calcium carbonate (CaCO₃) were fitted numerically to constrain the transport processes and the kinetics of biogeochemical reactions. The model results indicate that the anaerobic oxidation of methane (AOM) is the major process proceeding at a depth-integrated rate of 4.9 μmol cm⁻² a⁻¹, followed by calcium carbonate and strontian barite precipitation/dissolution processes having a total depth-integrated rate of 2.1 μmol cm⁻² a⁻¹. At the low seepage rate prevailing at our study site (0.14 cm a⁻¹) all of the rising barium is consumed by precipitation of barite in the sedimentary column and no benthic barium flux is produced. Numerical experiments were run to investigate the response of this diagenetic environment to variations of hydrological and biogeochemical conditions. Our results show that relatively low rates of fluid flow (<∼5 cm a⁻¹) promote the dispersed precipitation of up to 26 wt% of barite and calcium carbonate throughout the uppermost few meters of the sedimentary column. Distinct and persistent events (several hundreds of years long) of more vigorous fluid flow (from 20-110 cm a⁻¹), instead, result in the formation of barite-carbonate crusts near the sediment surface. Competition between barium and methane for sulfate controls the mineralogy of these sediment precipitates such that at low dissolved methane/barium ratios (<4-11) barite precipitation dominates, while at higher methane/barium ratios sulfate availability is limited by AOM and calcium carbonate prevails. When seepage rates exceed 110 cm a⁻¹, barite precipitation occurs at the seafloor and is so rapid that barite chimneys form in the water column. In the Derugin Basin, spectacular barite constructions up to 20 m high, which cover an area of roughly 22 km² and contain in excess of 5 million tons of barite, are built through this process. In these conditions, our model calculates a flux of barium to the water column of at least 20 μmol cm⁻² a⁻¹. We estimate that a minimum of 0.44 × 10⁶ mol a⁻¹ are added to the bottom waters of the Derugin Basin by cold seep processes, likely affecting the barium cycle in the Sea of Okhotsk.     

南海东北部海底沉积物波的形态、粒度特征及物源、成因分析

在南海东北部广泛发育沉积物波。通过高分辨率多波束数据、地震剖面以及重力柱状样,对沉积物波的形态特征、粒度特征、物源以及形成机制进行了分析。研究表明大致以台湾浅滩南海底峡谷为界,北侧为近北东向展布,南侧为近南北向展布。对其分布规律、地貌和形态特征及重力柱状样粒度分析表明这些沉积物波为浊流成因。沉积物波的发育与新生代晚期研究区的构造活动密切相关,自距今6.5 Ma以来台湾造山运动使台湾岛强烈抬升剥蚀,这些剥蚀物为研究区提供了大量的陆源物质,而在南海东北部陆坡区大量发育的峡谷-冲沟系统为陆缘物质向下陆坡的输送提供了良好的通道。研究区西侧的东沙隆起长期处于抬升剥蚀状态,这种抬升剥蚀也为研究区沉积物波的发育提供了部分物源。随着坡度的减缓,浊流沉积物开始堆积,在台湾浅滩南海底峡谷的北侧形成了展布方向与冲沟垂直的沉积物波,而在南侧由于台湾浅滩南海底峡谷发生转向,浊流从水道中漫溢出来,沉积物堆积下来,形成了与原先水道近于垂直的近南北向的沉积物波。     

Mg---NH4 exchange on humic acid: A radiotracer technique for conditional exchange constants in a seawater medium

A radiotracer technique, employing ²⁷Mg, is used to determine the Mg released by ammonium exchange on undis-solved humic acid in a seawater medium. This new method allows for the measurement of exchangeable Mg on the solid phase surface, which eliminates the problem caused by the high-Mg background in the seawater matrix. The precision calculated from the counting statistics is better than ±2%; the reproducibility among repeated counts ranged from ±1% to ±3%. The higher sensitivity of the method allows for monitoring the Mg---NH₄ exchange at concentrations as low as 30 mM NH₄. This is a major improvement relative to the data obtained with the analytical methods used so far, which allow detection of exchangeable Mg only at NH₄ concentrations higher than 1 M. The lower experimental concentrations are more in accordance with the natural ammonium levels found in anoxic marine sediments. For the undissolved humic acid used in this experiment, the amount of exchangeable Mg in apparent equilibrium with an ammonium-free seawater matrix was found to be 96.6 ± 0.4 meq/100g. The Mg---NH₄ exchange on humic acid in seawater comes to a steady-state value in < 18 min. The conditional equilibrium constant obtained for this reaction, K_cond = 0.039 ± 0.001 M⁻¹. The technique can be expanded to other geochemical solid phases in seawater and it can be modified to study the behavior of the major cations by using ²⁴Na, ⁴²K and ⁴⁹Ca.     

The Multiple Sources and Patterns of Methane inNorth Sea Waters

The methane concentration in the atmosphere andsurface water was surveyed along 58° N acrossthe North Sea. In addition, the vertical methanedistribution in the water column was determined at sixstations along the transect. The methane contents ofthe surface water as well as in the water column wereextremely inhomogeneous. Input by freshwater fromriver discharge and injection of methane from thesediment were both observed. The survey continued fromthe western side of the North Sea to the Elbe Riverestuary. The Elbe River appears to have low methaneconcentrations compared to other European rivers, itsaverage input into the North Sea is estimated to be70 nmol s-1 of methane. Near 58° N,1°40' E, an abandoned drill site releases about 25 % ofthe North Sea's emission of methane to the atmosphere.The advective methane transport induced by watercirculation was assessed for May 16, 1994, using a 3-DNorth Sea circulation model. For the period of thissurvey, the North Sea's source strength foratmospheric methane is estimated using in situwind velocities. In comparison to the advectivetransport by the water circulation, the gas flux tothe atmosphere appears to be the dominant sink ofNorth Sea methane. This flux is estimated to bebetween 1500 · 106 mol a-1 and 3100 ·106mol a-1, depending on the relationbetween wind speed and gas transfer velocity.     

Interaction of organic compounds with calcium carbonate—III. Amino acid composition of sorbed layers

Nitrogenous organic compounds in sorbed surface layers and in calcified organic matter associated with calcium carbonate sediment particles consist of 40–50% amino acids, 2% amino sugars and 25% ammonia. In grain size classes > 20 μm these compounds are mainly contained in the calcified protein of carbonate secreting organisms but with smaller grain sizes—and consequently increased specific surface area—they are contained in sorbed layers at the mineral surface. The composition of the sorbed layer is characterized by a predominance of neutral amino acids, a relative enrichment of basic and weakly polar amino acids, and a deficiency of acidic amino acids in comparison with the proteinaceous matter of calcifying organisms. The respective abundances for sorbed and calcified matter are: 505 and 380 Res./ of neutral amino acids, 262 and 450 Res./1000 of acidic amino acids, 92 and 51 Res./l000 of basic amino acids, and 141 and 129 Res./1000 of weakly polar amino acids.The composition of the sorbed layer appears to be the result of sorption of proteinaceous matter from solution since it reflects the free and peptide-bound amino acid composition of seawater. The characteristic amino acid assemblage could also be the result of preferential decomposition of protein and subsequent enrichment of neutral and basic amino acids; however, sorption from solution appears more likely since the total amount of amino acids sorbed to calcium carbonate (0.58 mg m ^?2) corresponds closely to the amount of protein known to cover one m² of aqueous substrate in monolayer arrangement. Sorption from solution is further supported by the low arginine/ornithine ratios in both the sorbed layer and the natural dissolved organic matter. This process might lead to a characteristic amino acid spectrum in fine grained calcareous sediments that reflects the composition of the dissolved organic matter in seawater rather than that of the carbonate secreting proteinaceous matter.