Influence of dissolved organic carbon on photochemically mediated cycling of hydrogen peroxide in rainwater

The influence of sunlight and dissolved organic carbon (DOC) on the photochemically mediated cycling of hydrogen peroxide (H₂O₂) was investigated in rainwater samples collected in Wilmington, North Carolina USA. Upon exposure to simulated sunlight 14 of 19 authentic rainwater samples exhibited significant decreases in H₂O₂. The concentration of hydrogen peroxide did not change significantly in organic-free synthetic rainwater spiked with H₂O₂ in the light or in dark controls suggesting that the loss was not due to direct photolysis or dark mediated reactions. There was a significant correlation between pseudo-first order rate constants of H₂O₂ decay and initial H₂O₂ concentrations. There was also a significant correlation between the rate constant and the abundance of DOC suggesting that rainwater organic carbon plays an important role during photolytic decay either via direct reaction or indirectly through production of peroxide reactive species or scavenging of peroxide generating radicals. Several rain samples exhibited an initial increase in H₂O₂ during the first 2 h of irradiation. These increases were generally small and most likely do not represent a significant input of peroxide in precipitation. The photo-induced destruction of H₂O₂ is important because it may partly explain the late afternoon decrease of peroxide concentrations observed in earlier field studies and the substantial under saturation (<10%) of this oxidant in rainwater compared with gas phase concentrations.     

A radio survey of supersoft, persistent and transient X-ray sources in the Magellanic Clouds

We present a radio survey of X-ray sources in the Large and Small Magellanic Clouds with the Australia Telescope Compact Array at 6.3 and 3.5 cm. Specifically, we have observed the fields of five LMC and two SMC supersoft X-ray sources, the X-ray binaries LMC X-1, X-2, X-3 and X-4, the X-ray transient Nova SMC 1992, and the soft gamma-ray repeater SGR 0525-66. None of the targets are detected as point sources at their catalogued positions. In particular, the proposed supersoft jet source RXJ 0513-69 is not detected, placing constraints on its radio luminosity compared to Galactic jet sources. Limits on emission from the black hole candidate systems LMC X-1 and X-3 are consistent with the radio behaviour of persistent Galactic black hole X-ray binaries, and a previous possible radio detection of LMC X-1 is found to be almost certainly a result of nearby field sources. The SNR N49 in the field of SGR 0525-66 is mapped at higher resolution than it has been previously, but there is still no evidence for any enhanced emission or disruption of the SNR at the location of the X-ray source.     

The identification of the optical/IR counterpart to the ROSAT SMC X-ray transient RX J0117.6−7330

We report observations which identify the optical/IR counterpart to the ROSAT X-ray transient RX J0117.6−7330. The counterpart is suggested to be a B1–B2 star (luminosity class III–V) showing an IR excess and strong Balmer emission lines. The distance derived from reddening and systemic velocity measurements is consistent with the distance derived from X-ray measurements and puts the source in the Small Magellanic Cloud (SMC).