The δ13C–δ18O variations in marble in the Hida Belt,Japan

Marble has a great potential to understand a history of various geological events occurring during tectonic processes. In order to decode metamorphic–metasomatic records on C–O isotope compositions of marble at mid-crustal conditions, we conducted a C–O–Sr isotope study on upper amphibolite-facies marbles and a carbonate–silicate rock from the Hida Belt, which was once a part of the crustal basement of the East Asian continental margin. Carbon and oxygen isotope analyses of calcite from marbles (Kamioka area) and a carbonate–silicate rock (Wadagawa area) show a large variation of δ¹³C [VPDB] and δ¹⁸O [VSMOW] values (from −4.4 to +4.2 ‰ and +1.6 to +20.8 ‰, respectively). The low δ¹³C values of calcites from the carbonate–silicate rock (from −4.4 to −2.9 ‰) can be explained by decarbonation (CO₂ releasing) reactions; carbon–oxygen isotope modeling suggests that a decrease of δ¹³C strongly depends on the amount of silicate reacting with carbonates. The occurrence of metamorphic clinopyroxene in marbles indicates that all samples have been affected by decarbonation reactions. All δ¹⁸O values of calcites are remarkably lower than the marine-carbonate values. The large δ¹⁸O variation can be explained by the isotope exchange via interactions between marble, external fluids, and/or silicates. Remarkably low δ¹⁸O values of marbles that are lower than mantle value (~+5 ‰) suggest the interaction with meteoric water at a later stage. Sr isotope ratios (⁸⁷Sr/⁸⁶Sr = 0.707255–0.708220) might be close to their protolith values. One zircon associated with wollastonite in a marble thin-section yields a U–Pb age of 222 ± 3 Ma, which represents the timing of the recrystallization of marble, triggered by H₂O-rich fluid infiltration at a relatively high-temperature condition. Our isotope study implies that the upper amphibolite-facies condition, like the Hida Belt, might be appropriate to cause decarbonation reactions which can modify original isotope compositions of marble if carbonates react with silicates.     

长江干流主要营养盐含量的变化特征——1998~1999年日中合作调查结果分析

根据1998年和1999年秋季在长江干流从重庆至长江口进行的纵向采样和分析,对长江干流的各态氮、磷含量的沿江变化进行研究。从整体上了解长江干流的水质变化特性,特别是营养盐含量的分布状况。研究结果表明,长江干流的SS浓度很高,介于50~400 mg/l。TN、TP浓度分别在70~110 滋mol/L、2~25 滋mol/L之间,前者以NO3-N为主,后者以PTP为主,PO4-P含量仅占TP的10%~20%。DIN/PO4-P的比值在70~160之间,远高于浮游植物生长P限制值,表明长江口及临近海域中P可能是生物生命活动的主要限制因素。葛洲坝水库对SS、TP、TN、NH4-N、BOD、COD等水质有一定的净化作用。长江水体在通过各大城市以及两大湖泊时,BOD、NH4-N负荷的增加迅速,特别是通过重庆、武汉、南京、上海及洞庭湖和鄱阳湖之后尤为明显。N、P含量的上升与人口增长、生活污水排放量及流域内化肥施用量增加有关。洞庭湖和鄱阳湖水系以及周围的面源负荷,对长江流域的营养盐变动有很大的影响。     

Development of a 2-km resolution ocean model covering the coastal seas around Japan for operational application

Ocean Dynamics - In order to expand the coastal ocean monitoring and forecasting system of the Japan Meteorological Agency from the Seto Inland Sea to the entire coastal seas of Japan, a 2-km...     

Discovery of an ice cave in the Yatude Valley, Langhovde, Dronning Maud Land, East Antarctica

A circular hole was discovered on the downstream side of a glacier dam in the Yatude Valley, Langhovde, East Antarctica, during the 2005–2006 austral summer. The opening of this hole is the first opportunity enabling us to observe the interior of the dam. The opening led to a large cave in the dam, raising the possibility of meltwater drainage through the dam. The Yatude Valley is an approximately U-shaped fluvial valley. The valley floor has been incised to form a box-shaped inner valley that contains fluvial terraces and large boulders upon the valley floor. The origin of these features can be explained by a large amount of running water; however, we consider it unlikely that a regular current has flowed through this site for a long period. Instead, it is more likely that large quantities of lake water have been periodically discharged due to collapse of the glacier dam or spilling out through a tunnel channel within the cave. The discovered hole and the ice cave are key features in understanding the historical development of the Yatude Valley in relation to the melting history of the Antarctic ice sheet.     

Interdiffusion of Mg–Fe in olivine at 1,400–1,600 °C and 1 atm total pressure

The interdiffusion coefficient of Mg–Fe in olivine (D _Mg–Fe) was obtained at 1,400–1,600 °C at the atmospheric pressure with the oxygen fugacity of 10^?3.5–10^?2 Pa using a diffusion couple technique. The D _Mg–Fe shows the anisotropy (largest along the [001] direction and smallest along the [100] direction), and its activation energy (280–320 kJ/mol) is ~80–120 kJ/mol higher than that estimated at lower temperatures. The D _Mg–Fe at temperatures of >1,400 °C can be explained by the cation-vacancy chemistry determined both by the Fe³⁺/Fe²⁺ equilibrium and by the intrinsic point defect formation with the formation enthalpy of 220–270 kJ/mol depending on the thermodynamical model for the Fe³⁺/Fe²⁺ equilibrium in olivine. The formation enthalpy of 220–270 kJ/mol for the point defect (cation vacancy) in olivine is consistent with that estimated from the Mg self-diffusion in Fe-free forsterite. The increase in the activation energy of D _Mg–Fe at >1,400 °C is thus interpreted as the result of the transition of diffusion mechanism from the transition metal extrinsic domain to the intrinsic domain at the atmospheric pressure.     

Numerical simulation of Pacific water intrusions into Otsuchi Bay,northeast of Japan,with a nested-grid OGCM

A numerical simulation of Otsuchi Bay located on the northeast coast of the Honshu, the largest island of Japan, is conducted, using an ocean general circulation model (OGCM) with a nested-grid system in order to illustrate seasonal variability of the circulation in the bay. Through a year, an anticlockwise circulation is dominant in the bay, as observational studies have implied, although it is modified in the bay-mouth-half of the bay in winter. In addition, there is an intense outflow at the surface layer during spring to autumn, influenced by river water discharge. Intrusion of the Pacific water into the bay is influened by mean circulations, but it is also influenced by baroclinic tides from spring to autumn. Pacific water intrusions affected by baroclinic tides may have an impact on the environment in Otsuchi Bay.     

http://dx.doi.org/10.1016/j.gsf.2016.06.013

The Archean continental crusts account for ca.20% of the present volume,but the thermal history of the Earths' mantle suggests much more continental crusts were formed in the early Archean.Because the Archean continental crust underwent severe metamorphism,it is important to avoid influence by the later thermal events.We carried out a comprehensive geochronological work of Cathodoluminescence(CL) observation and U-Pb dating of zircons from orthogneisses and supracrustal rocks over the Saglek Block to obtain their protolith ages.The zircons were classified into three domains of core,mantle and rims,and the cores were further classified into three groups of inherited,altered and zoned cores based on the zonation on the CL images.We estimated the protolith ages from Pb-Pb ages of the zoned-cores of zircons with low U contents.We made a detailed sketch of a small outcrop in St.John's Harbour South(SJHS) area,and classified the orthogneisses and mafic enclaves into seven generations based on the geologic occurrence.The first and second generations comprise mafic rocks and lack magmatic zircons.We conducted CL imaging and U-Pb dating of zircons from the third,sixth and seventh generation of the orthogneisses to estimate the protolith ages at 3902 L 25,3892 ± 33 and 3897 ± 33 Ma for each,supporting the presence of the over 3.9 Ca Iqaluk Gneiss.The geological occurrence that the mafic rocks occur as enclaves within the 3.9 Ga Iqaluk Gneiss indicates that they are the oldest supracrustal rocks in the world.Our geochronological and geological studies show the Uivak Gneiss is quite varied in lithology and age from 3.6 to 3.9 Ga,and tentatively classified into six groups based on their ages.The oldest Uivak Gneiss components including the Iqaluk Gneiss are present around the SJHS area,and the orthogneisses become young as it is away.The lines of evidence of overprinting of younger granitoid on older granitoid in small outcrops and geological-map scale as well as presence of inherited zircons even in the oldest suite suggests that crustal reworking played an important role on erasing the ancient crusts.     

Curation protocol of Phobos sample returned by Martian Moons eXploration

Japan Aerospace Exploration Agency's Martian Moons eXploration (MMX) mission will launch a spacecraft in 2024 to return samples from Phobos in 2029. Curatorial work for the returned Phobos samples is critical for the sample allocation without degrading the sample integrity and subsequent sample analysis that will provide new constraints on the origin of Phobos and the evolution of the circum-Mars environment. The Sample Analysis Working Team of the MMX is designing the sample curation protocol. The curation protocol consists of three phases: (1) quick analysis (extraction and mass spectrometry for gases), (2) pre-basic characterization (bulk-scale observation), and (3) basic characterization (grain-by-grain observation and allocation of the sample aliquots). Nondestructive analyses within the clean chamber (e.g., visible and near-infrared spectral imaging) and outside the chamber (e.g., gas mass spectrometry) are incorporated into the curation flow in coordination with the MMX mission instrument teams for ground-truthing the remote-sensing data sets. The MMX curation/sample analysis flow enables the seamless integration between the sample and remote-sensing data sets to maximize the scientific value of the collected Phobos samples.     

Anisotropy of Mg isotopic fractionation during evaporation and Mg self-diffusion of forsterite in vacuum

Evaporation of solid materials under low-pressure conditions could play important roles in chemical and isotopic fractionations in the early solar system. We have studied anisotropy of isotopic fractionation of ²⁶Mg and ²⁵Mg during kinetic evaporation of forsterite (Mg₂SiO₄), which is potentially a powerful tool to understand thermal histories of crystals in the early solar system. Ion-microprobe depth profiling revealed that the Mg isotopic zoning profiles of forsterite evaporated at 1500-1700 °C are notably differing along the a-, b-, and c-axes, which can be attributed to anisotropy in self-diffusion coefficient of Mg (D) and an isotopic fractionation factor for evaporation of Mg (α). The D and α were obtained from zoning profiles by applying the diffusion-controlled isotopic fractionation model of Wang et al. [1999. Evaporation of single crystal forsterite: Evaporation kinetics, magnesium isotope fractionation, and implications of mass-dependent isotopic fractionation of a diffusion-controlled reservoir. Geochim. Cosmochim. Acta 63(6), 953-966.].The D is largest and smallest along the a- and c-axes, respectively. The activation energy of 560-670 kJ/mol indicates that Mg diffusion at 1500-1700 °C occurred in the intrinsic diffusion regime.The α seems to be larger along the a- or c-axes than along the b-axis. The α along the a- or c-axes show weak temperature dependence. The α along all the crystallographic orientations is closer to unity than that expected from the kinetic theory of gases. These lines of evidence suggest that surface processes such as breaking of bonds and surface diffusion are responsible for the isotopic fractionation.