CO<Subscript>2</Subscript> Flux Measurements over the Sea Surface by Eddy Correlation and Aerodynamic Techniques

The measurements of the vertical transport of CO₂ were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO₂ fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO₂ fluxes during sea breeze conditions: −0.001 to −0.08 mg m⁻²s⁻¹ with the mean of −0.05 mg m⁻²s⁻¹. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO₂ flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO₂ concentration difference of the order of 0.1 ppmv on the research vessels or the buoys.     

Protracted Active Surge Phase in the High Arctic (Svalbard): Dynamic Development and Morphological Impact

Glacial surges in Svalbard are protracted and characterized by individual dynamic evolution, in contrast to many other areas, which calls for a subdivision of the classic two‐phased surge cycle. A dominating part of the ice masses seem to have a surge potential and this represents a considerable challenge for palaeoclimatic studies. Glaciological and geological models therefore need to be coupled. The issue is discussed with Fridtjovbreen glacier as an example. This ice mass is one of few glaciers studied throughout a surge cycle. It was active for 12 years (1991–2002) and represents the most protracted surge documented. The maximum advance rate was 4.2 m day^?1, its maximum extent was reached after seven years, its run‐out distance was 4 km, and the relocated ice filled 5 km² of the fjord. Intense subglacial thrusting occurred during various stages, including part of the ice‐front retreat, as shown by sub‐bottom profiling data from 2002. A six‐stage model is presented and processes are discussed with emphasis on the ice‐front retreat with transition to the quiescent phase. Although the surge mechanism itself is unrelated to climate, climatic conditions obviously play a major role in the course of a surge. During the surge, the ice mass made a dramatic impression in the landscape, but 10 years after the maximum extent, there is little onshore evidence of the event.     

Experimental study on prevention of acid mine drainage by silica coating of pyrite waste rocks with amorphous silica solution

Acid mine drainage (AMD) is a widespread environmental problem associated with working and abandoned mining operations. It results from the microbial oxidation of pyrite in the presence of water and air, affording an acidic solution that contains toxic metal ions. Pyrite microencapsulation, utilizing silica coating, is a novel approach for controlling AMD that has been shown to be very effective in controlling pyrite oxidation. The roles of the solution pH and silica concentration in the formation mechanism for the AMD-preventing coating were investigated. A silica coating can be formed from silica solution at pH 7, at which the amount of Fe eluted from pyrite into the solution is small. No coating was formed at other pH values, and the amounts of eluted Fe were larger than at pH 7, especially at pH 11. The silica coating forms from 2,500 to 5,000 mg/L silica solutions, but not from 0 or 1,000 mg/L silica solutions. The coating formation rate was slower in the 2,500 mg/L silica solution than in the 5,000 mg/L silica solution. The formation of silica coating on pyrite surfaces depends on three main steps: formation of Fe(OH)₃ on the surface of pyrite, reaction between Fe(OH)₃ and silicate in the solution on the pyrite surface, and growth of the silica layer on the first layer of silica. The best pH condition to enable these steps was around 7, and the silica coating formation rate can be controlled by the concentration of silica.     

Strain and tilt changes measured during a water injection experiment at the Nojima Fault zone, Japan

Abstract In order to make geophysical and geological investigations of the Nojima Fault on Awaji Island, Japan, three boreholes measuring 1800 m, 800 m and 500 m deep were drilled into the fault zone. The fault is one of the seismic source faults of the 1995 Hyogo-ken Nanbu earthquake of M 7.2. A new multicomponent borehole instrument was installed at the bottom of the 800 m borehole and continuous observations of crustal strain and tilt have been made using this instrument since May 1996. A high-pressure water injection experiment within the 1800 m borehole was done in February and March 1997 to study the geophysical response, behavior, permeability, and other aspects of the fault zone. The injection site was located approximately 140 m horizontally and 800 m vertically from the instrument. Associated with the water injection, contraction of approximately 0.7 × 10⁻⁷ str (almost parallel to the fault) and tilt of approximately 1 × 10^-7 rad in the sense of upheaval toward the injection site were observed. In addition to these controlled experiments, the strainmeter and tiltmeter also recorded daily variations. We interpret strain and tilt changes to be related to groundwater discharge and increased ultra-micro seismicity induced by the injected water.     

Effect of hydrostatic pressure on the lattice parameters of Fe2SiO4 olivine up to 70 kbar

The pressure dependence of the three lattice parameters and unit cell volume of fayalite (Fe₂SiO₄ olivine) was determined by X-ray diffraction under hydrostatic pressures up to 70 kbar. In order to eliminate stress inhomogeneity within a composite material consisting of a specimen mixed with an internal-pressure standard, a liquid (1 : 1 mixture of ethanol and methanol) was used as a pressure-transmitting medium. The isothermal bulk modulus calculated on the basis of the second-order Birch-Murnaghan equation of state gives the values K₀ = 1.19 ± 0.10 Mbar and K₀′ = 7 ± 4, and if we assume K₀′ = 5: K₀ = 1.24 ± 0.02 Mbar. Three axes of fayalite were found to be compressible in the following order, b >c >a. Comparisons with the results obtained under non-hydrostatic compression are made.     

Perceptual models of uncertainty for socio-hydrological systems: a flood risk change example

ABSTRACT

Characterizing, understanding and better estimating uncertainties are key concerns for drawing robust conclusions when analyzing changing socio-hydrological systems. Here we suggest developing a perceptual model of uncertainty that is complementary to the perceptual model of the socio-hydrological system and we provide an example application to flood risk change analysis. Such a perceptual model aims to make all relevant uncertainty sources – and different perceptions thereof – explicit in a structured way. It is a first step to assessing uncertainty in system outcomes that can help to prioritize research efforts and to structure dialogue and communication about uncertainty in interdisciplinary work.     

Eigen oscillation of a fluid sphere and source mechanism of harmonic volcanic tremor

The eigen oscillation of a fluid sphere embedded in an infinite elastic medium is analyzed to understand the source mechanism of volcanic tremor that vibrates nearly monotonically and attenuates slowly. The dimensionless eigen frequencies of the sinusoidal oscillation are calculated in a complex form with the attenuation factor in its imaginary part for various combinations of the three parameters: the contrasts of P-wave velocity, density and rigidity between the fluid and the country rock. Eigen oscillations consist of a high attenuation mode with a rapidly decaying pulsive wave at a low frequency and infinite number of regular modes with slowly decaying vibrations. For regular modes, the frequency of oscillation obtained from the real part of an eigen value is distributed in approximately regular intervals while the attenuation factor from the imaginary part is almost constant independent of the mode. Each eigen frequency of regular and high attenuation modes is degenerated with two independent eigen functions describing different distributions of displacement, velocity and stress. The theory is applied to harmonic volcanic tremor observed at Kusatsu-Shirane Volcano, central Japan. Observed spectral peaks of the tremor are explained by the eigen frequencies and attenuation factors of several lowest regular modes if the spherical fluid oscillator has a radius of dozens of meters and a P-wave velocity of about several hundred meters per second.     

Small inflation sources producing seismic and infrasonic pulses during the 2000 eruptions of Miyake-jima, Japan

During the 2000 activity of Miyake-jima volcano, Japan, we detected long period seismic signals with initial pulse widths of 1-2 s, accompanied by infrasonic pulses with almost the same pulse widths. The seismic signals were observed from 13 July 2000, a day before the second summit eruption. The occurrences of the seismic signals were intermittent with a gradual increase in their magnitudes and numbers building toward a significant explosive eruption on 18 August. After the eruption, the seismic and infrasonic events ceased. The results of a waveform inversion show that the initial motions were excited by an isotropic inflation source beneath the south edge of the caldera at a depth of 1.4 km. On the other hand, the sources of the infrasonic pulses were located in the summit caldera area. The times at which the infrasonic pulses were emitted at the surface were delayed by about 3 s from the origin times of the seismic events. It is suggested that small isotropic inflations excited seismic waves in the crust and simultaneously caused acoustic waves that traveled in the conduit and produced infrasonic pulses at the crater bottom. Considering the observed time differences and gas temperatures emitted from the vent, the conduit should have been filled with vapor mixed with SO₂ gas and volcanic ash. The change of the time differences between the seismic and infrasonic signals suggests that the seismic source became shallower within half a day before the August 18 explosive eruption. We interpret the source process as a fragmentation process of magma in which gas bubbles burst and quickly released part of the pressure that had been sustained by the tensional strength of magma.     

The use of microstructures for discriminating turbiditic and hemipelagic muds and mudstones

The microstructures of turbiditic and hemipelagic muds and mudstones were investigated using a scanning electron microscope to determine whether there are microstructural features that can differentiate turbiditic from hemipelagic sedimentary processes. Both types of muddy deposits are, in general, characterized by randomly‐oriented clay particles. However, turbiditic muds and mudstones also characteristically contain aggregates of ‘edge‐to‐face’ contacts between clay particles with long‐axis lengths of up to 30 μm. Based on observations of the clay fabric of the experimentally‐formed muds settled from previously agitated muddy fluids, these types of aggregates, hereafter referred to as ‘aggregates of clay particles’, are interpreted as having been formed by the collision of component flocs in turbulent fluids. Furthermore, some aggregates of clay particles have ‘face‐to‐face’ contacts between clay particles; this is similar to face‐to‐face aggregates characteristically developed in fluid‐mud deposits that are commonly recognized only in turbiditic mudstones, indicating the possibility of a final stage of deposition under highly‐dense conditions, such as temporary fluid muds. In conjunction with earlier proposed lithofacies‐based and ichnofacies‐based criteria, aggregates of clay particles should be useful for the differentiation of turbiditic and hemipelagic muddy deposits, particularly with limited volumes of non‐oriented samples from deep‐water successions.     

Indonesian rainfall variability during Western North Pacific and Australian monsoon phase related to convectively coupled equatorial waves

The Indonesian archipelago which has over 15,000 islands, lies in the tropics between Asia and Australia. This eventually alters the rainfall variability over the region, which was influenced by the Asian-Australian monsoon and controlled by intraseasonal variabilities such as convectively coupled equatorial waves (CCEW), i.e., Kelvin, n?=?1 equatorial Rossby (ER), mixed Rossby gravity (MRG), and n?=?1 Westward inertio gravity (WIG), including the Madden–Julian Oscillation (MJO). This study examines a 15-year 3B42 data for trapping CCEW and MJO in the region of Indonesia during both active and extreme Western North Pacific (WNP) and Australian (AU) monsoon phases, which are then compared with 30-year rainfall anomalies among 38 synoptic stations over Indonesia. The space–time spectral analysis is employed to filter each wave including the MJO in the equator, then proceeding with the empirical orthogonal function (EOF) method to seek each wave peak which then coincides with WNP and AU monsoon peaks over Indonesia. It is concluded that an extreme monsoon classification has proven to control rainfall activity related to the CCEW and MJO at 60.66% during December through February (DJF)-WNP for only the significant wave perturbation value. Meanwhile, the CCEW and MJO significantly increase/decrease precipitation at Day 0 for about 37.88% from the total of Day 1st to Day end. Although the contribution of the CCEW and MJO does not profoundly influence rainfall activity during monsoon phase over Indonesia, they still modulate weather condition for more than 50%. On the other hand, a complex topography with a number of land–sea complexities is capable of influencing the rainfall variability in the region as a negative relationship is associated with the CCEW and MJO either during DJF-WNP or July through August (JAS)-AU monsoon phase.