Metals in eggs and hatchlings of Dermochelys coriacea (testudines) in Espírito Santo,Brazil and their relation to hatching and emergence success

Certain concentration of metal may influence survival in embryonic stages, reducing the birthrate and hatching emergence. This study aimed to evaluate concentration of metal in eggs and hatchlings of Dermochelys coriacea and correlate metal concentrations in eggs with hatching and emergence success. The samples were collected at Biological Reserve Station, ES, Brazil. At the nests' opening, unhatched eggs and stillborn hatchlings were collected to survey the successful hatching and emergence of D. coriacea. The eggs shell, egg content, and dead hatchlings metal concentrations were compared to hatching and emergence success. A positive correlation was found between the concentration of copper (Cu) in the hatchlings and the success of the emergence (r² = .28, p < .05), and a moderate positive correlation between the concentrations of iron (Fe) and barium (Ba; r² = .44, p < .05) and success hatching. The concentrations of metals in eggs and hatchlings of D. coriacea in the Espírito Santo are below the levels that could be considered harmful to the species. In summary, there is a positive correlation between metals levels and hatching and emergence success.     

Hydrochemistry of the Lake Magadi basin,Kenya

New and more complete compositional data are presented for a large number of water samples from the Lake Magadi area, Kenya. These water samples range from dilute inflow (<0.1 g/kg dissolved solids) to very concentrated brines (>300 g/kg dissolved solids). Five distinct hydrologic stages can be recognized in the evolution of the water compositions: dilute streamflow, dilute ground water, saline ground water (or hot spring reservoir), saturated brines, and residual brines. Based on the assumption that chloride is conserved in the waters during evaporative concentration, these stages are related to each other by the concentration factors of about 1:28:870:7600:16,800.Dilute streamflow is represented by perennial streams entering the Rift Valley from the west. All but one (Ewaso Ngiro) of these streams disappear in the alluvium and do not reach the valley floor. Dilute ground water was collected from shallow pits and wells dug into lake sediments and alluvial channels. Saline ground water is roughly equivalent to the hot springs reservoir postulated by Eugster (1970) and is represented by the hottest of the major springs. Saturated brines represent surficial lake brines just at the point of saturation with respect to trona (Na₂CO₃.NaHCO₃.2H₂O), while residual brines are essentially interstitial to the evaporite deposit and have been subjected to a complex history of precipitation and re-solution.The new data confirm the basic hydrologic model presented by Eugster (1970) which has now been refined, particularly with respect to the early stages of evaporative concentration. Budget calculations show that only bromide is conserved as completely as chloride. Sodium follows chloride closely until trona precipitation, whereas silica and sulfate are largely lost during the very first concentration' step (dilute streamflow-dilute ground water). A large fraction of potassium and all calcium plus magnesium are removed during the first two concentration steps (dilute streamflow-dilute ground water-saline ground water). Carbonate and bicarbonate are the dominant anions, and mechanisms by which they are extracted from the solution include precipitation of alkali and alkaline-earth carbonates, and degassing, as well as precipitation and re-solution of efflorescent crusts. Much sulfate is apparently lost from solution by sorption as well as subsurface reduction.Seasonal runoff, principally from the valley floor north of Lake Magadi, is considered to be the principal recharge to the Magadi ground water system. Evaporative concentration is the overall process responsible for the chemical evolution of the brines. This includes not only simple evaporation, but also mineral precipitation as films and cements in the unsaturated zone, re-solution, and reprecipitation of efflorescent crusts, with consequent recycling of salts. In fact, a large fraction of the solutes are acquired through dissolution of efflorescent crusts.Data were obtained for borehole brines from as deep as 297 m. They show the existence of two distinct brine bodies below the present lake, one shallow, coexistent with bedded salts, and highly concentrated (260 g/kg average dissolved solids), and the other deeper in lacustrine sediments or fractured lavas, and only half as concentrated.     

Monitoring permeable paver runoff with an open-innovation geospatial sensor network

Sensor networks are an essential tool for environmental scientists. As scientists and engineers are beginning to utilize these new methods and devices in their fieldwork, they need to be actively involved in the future of sensor-networking development. Continued sensor network innovation is important for improved standardization, affordability, and interoperability. This article uses a storm water case study to outline an end-to-end open-innovation sensor network. Open innovation by scientists, engineers, and entities is the collaborative process of creating value for this project in permeable paver runoff data and advances within sensor networking. This article focuses on the technical implementation of the near–real-time location and temporally aware sensor network. Data are streamed in near–real-time with subliter precision to the cloud using common off-the-shelf routers. The sensors use Maxim's 1-wire? protocol, and the unique digital serial numbers confirm the data. The data retrieved compare residence times within the permeable paver catchment basins and the control basin. Sensor network advances are made by bridging the gap between sensor protocols and communication systems. These advances enable the development of open-source representational state transfer web services. Our successful implementation serves as an example for others to study and expand upon for a variety of monitoring solutions.     

Detection of CO and Ethane in Comet 21P/Giacobini-Zinner: Evidence for Variable Chemistry in the Outer Solar Nebula

Ethane and carbon monoxide were detected in a short-period comet of probable Kuiper Belt origin. Ethane is substantially less abundant compared with Hyakutake and Hale-Bopp, two comets from the giant-planet region of the solar nebula, suggesting a heliocentric gradient in ethane in precometary ices. It is argued that processing by X-rays from the young Sun may be responsible.     

Great Salt Lake,and precursors,Utah: The last 30,000 years

Sediment cores up to 6.5 m in length from the South Arm of Great Salt Lake, Utah, have been correlated. Radiocarbon ages and volcanic tephra layers indicate a record of greater than 30,000 years. A variety of approaches have been employed to collect data used in stratigraphic correlation and lake elevation interpretation; these include acoustic stratigraphy, sedimentologic analyses, mineralogy, geochemistry (major element, C, O and S isotopes, and organics), paleontology and pollen.The results indicate that prior to 32,000 year B.P. an ephemeral saline lake-playa system was present in the basin. The perennial lake, which has occupied the basin since this time, rose in a series of three major steps; the freshest water conditions and presumably highest altitude was reached at about 17,000 year B.P. The lake remained fresh for a brief period, followed by a rapid increase in salinity and sharp lowering in elevation to levels below that of the present Great Salt Lake. The lake remained at low elevations, and divided at times into a north and south Basin, until about 8,000 year B.P. Since that time, with the exception of two short rises to about 1290 m, the lake level has remained near the present elevation of 1280 m.     

Detection of the 2165 inverse centimeter (4.619 micron) XCN band in the spectrum of L1551 IRS 5

We report the detection of a broad absorption band at 2165 cm-1 (4.619 microns) in the spectrum of L1551 IRS 5. New laboratory results over the 2200-2100 cm-1 wavenumber interval (4.55-4.76 microns), performed with realistic interstellar ice analogs, suggest that this feature is due to a CN-containing compound. We will refer to this compound as XCN. We also confirm the presence of frozen CO (both in nonpolar and polar matrices) through absorption bands at 2140 cm-1 (4.67 microns) and 2135 cm-1 (4.68 microns). The relative abundance of solid-state CO to frozen H2O is approximately 0.13 while the abundance of XCN seems comparable to that of frozen CO.     

Geochemistry of Great Salt Lake,Utah I: Hydrochemistry since 1850

The hydrochemistry of Great Salt Lake, Utah, has been defined for the historic period, 1850 through 1982, from published data combined with new observations. The water balance depends largely on river inflow, atmospheric precipitation onto the lake surface and evaporation. Input of the major solutes can best be accounted for by mixing dilute calcium-bicarbonate type river waters with NaCl-dominated hydrothermal springs.Prior to 1930, lake concentrations fluctuated inversely with lake volume in response to small climatic variations. Since then, salt precipitation and dissolution have significantly modified lake brine compositions and have led to density stratification and the formation of brine pockets of differing composition. Brine mixing has become an important component of brine evolution. We have used calculated evaporation curves with mineral precipitation and dissolution to clarify these processes.Pore fluids represent important storage for solutes. Solute profiles can be modeled by simple one-dimensional diffusion calculations. Short-term historic variations in lake composition affect shallow pore fluids in the upper 2 metres of sediment.