Characterization of dissolved organic matter across the Subtropical Convergence off the South Island,New Zealand

Dissolved organic matter (DOM) was investigated along a gradient across the Subtropical Convergence (STC) off the South Island, New Zealand. Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS), excitation emission matrix fluorescence (EEM) spectroscopy, and molecular lignin analysis techniques were used to study this DOM. The analysis revealed a group of compounds found only in the coastal DOM samples, which were also characterized by an elevated terrestrial DOM fluorescence pattern and elevated lignin content if compared to the offshore samples. This group exhibited a high degree of carbon unsaturation, as evident from high double bond equivalence minus oxygen values (DBE-O > 9) and maximum fluorescence intensity. Sulfur-containing molecular formulae for summer DOM samples were much more abundant across the entire transect of the STC compared to winter and exhibited distinctly different hydrogen:carbon and oxygen:carbon elemental ratios, suggesting a possible correlation between biological activity and sulfur compounds. The molecular formulae common to all STC samples were compared with those calculated for DOM extracted from freshwater collected from a stream discharging into Doubtful Sound (West Coast, New Zealand). ESI-FT-ICR-MS measurements undertaken in negative electrospray ionization (ESI?) mode indicated that 30% of the molecular formulae were present in both types of DOM, while in positive ESI mode (ESI+) over 90% of the formulae were present in all samples. Hence, a significant portion of the molecular formulae assigned to the solid-phase extractable DOM pool (SPE-DOM) appear to be identical in oceanic and freshwater samples.     

Chlorinated hydrocarbons in fish-eating birds wintering in the Gdańsk Bay, 1981–82 and 1982–83

Seventy-four samples of adipose fat of 10 species of fisheating birds commonly wintering in Gdańsk Bay and one of little auk, a rare species in this area, have been analysed for residues of HCB, ΣBHC, ΣDDT and PCBs. Auks (guillemot, black guillemot and razorbill), which probably stay a whole year in the Baltic area, contained in their fat twice the level of PCBs as mergansers, and 5–6 times as much as in divers and grebes—birds which stay in the sea mainly after the breeding season. ΣDDT levels were somewhat higher but comparable in auks and grebes, and lower in mergansers and divers. ΣBHC and HCB levels were 3–4 times and 5–10 times higher, respectively, in auks than in birds from other families studied. When comparing residue levels found in adipose fat of birds taken during the wintering seasons of 1981–1982 and 1982–1983 with those taken in 1975–1976 or 1980–1981, an initially rapid, but in recent years a rather slow decline in ΣDDT level is detectable for grebes, mergansers and divers, and in the case of PCBs the residue levels fell slightly. In auks, the ΣDDT residue level fell by half, but remains rather stable in recent years, while there are only minor fluctuations in the residue level of PCBs.     

Chlorinated hydrocarbons in fish-eating birds wintering in the Gdańsk Bay,Baltic Sea, 1980–1981

Further samples of the chlorinated hydrocarbon content in adipose tissue of fish-eating birds wintering in the South Baltic show high concentrations of PCB compared with ΣDDT, HCB, alpha- and gamma-BHC. The great crested grebe presently examined had approximately four times higher PCB/ΣDDT ratios than specimens taken during 1975–1976.     

Some observations of bipolar flashes during summer thunderstorms near Warsaw

Lightning discharges monitored by the SAFIR network system in Poland have been additionally identified over the 100×100 km area near Warsaw by single-point independent recordings of electric field and Maxwell current rapid changes. The data collected in summer thunderstorm days of 2002 showed some untypical properties of the lightning discharges which are rarely observed. Especially remarkable was a number of ground multi-stroke flashes with the return strokes (RS) which transported to the earth charges of opposite signs. Bipolar flashes (BF) of this kind were mostly involved in the events in which the nearby intracloud (ic) and cloud-to-ground (c-g) discharges were very closely associated in time. Events of such a close collocation of two different types of lightning discharges, previously called the complex lightning discharge events (CLDE), were quite often observed during summer thunderstorms in Poland. The events of this kind, i.e. 8 flashes, identified by the SAFIR detection system as BF’s present the multiple stroke flashes of the mean horizontal separation distance between striking points of particular RS equal to (2.8 ± 2.1) km and of the mean time interval between strokes of (46.8 ± 74.4) ms. The time separation between the observed BF and the adjacent ic flashes was from 0.1 to 335 ms, and horizontal separation distance between them ranged from 1.8 to 14.5 km. The multiplicity of the recorded BF’s ranged from 2 to 4 strokes. Four of these BF’s followed the ic discharge, but the other three preceded the ic and one was alone with no close ic.     

Magnetostratigraphic correlation of the Oxfordian–Kimmeridgian boundary

A magnetic polarity pattern for Boreal and Sub-Boreal ammonite zones of the Upper Oxfordian to Lower Kimmeridgian was established and confirmed in four British sections, including the proposed Global Boundary Stratotype Section and Point (GSSP) on the Isle of Skye (Scotland) to define the base of the international Kimmeridgian Stage. A coeval pattern for Sub-Mediterranean ammonite zones was compiled from seven sections in Poland, one German section and multi-section composites from France and Spain. The mean paleopole for the European Craton (excluding Spain) at the Oxfordian–Kimmeridgian boundary is 74.2°N, 181.3°E (Α₉₅ = 3.8°). The common magnetic polarity scale enables inter-correlation of ammonite subzones among these three faunal provinces and to the marine magnetic-anomaly M-Sequence. The proposed GSSP at the base of the Pictonia baylei Zone is near the base of an extended interval dominated by reversed polarity, which is interpreted to be Chron M26r. This GSSP level projects to the lower to middle part of the Epipeltoceras bimammatum Subzone, which is the middle subzone of this E. bimammatum Zone in the Sub-Mediterranean standard zonation. In contrast, the traditional placement of the Oxfordian–Kimmeridgian boundary in that Sub-Mediterranean standard zonation (base of Sutneria platynota Zone) is at the base of Chron M25r, or nearly 1 million years younger.     

A late Pleistocene and Holocene mineral magnetic record from sediments of Lake Aibi,Dzungarian Basin,NW China

We studied mineral magnetic properties of a 6-m-long, late Pleistocene through Holocene sediment sequence from Lake Aibi in Dzungaria (Zunggary, Junggar), northern Xinjiang, China. Results were used to infer environmental changes and are compared with previously studied cores from Lake Manas. Both water bodies occupy the deepest parts of the Dzungarian Basin and are remnants of large Holocene lakes. During the Late Pleistocene, the magnetic mineralogy in both lakes was dominated by detrital, iron oxide minerals. Oxic conditions, which dominated during sedimentation and early diagenesis, persisted over the Pleistocene–Holocene transition. Later, during the middle Holocene, lake bottom conditions enabled authigenic formation of iron sulphide minerals such as pyrite (FeS₂) in Lake Aibi, and pyrite and greigite (Fe₃S₄) in Lake Manas. This iron sulphide mineralogy suggests increased biological activity in stagnant, anoxic bottom waters. Anoxic bottom conditions started about 9.8 cal kyr BP in Lake Manas and at about 7.2 cal kyr BP in Lake Aibi. A short dry event recorded in Lake Manas between 6.8 and 5.2 cal kyr BP is not clearly observed in Lake Aibi. In the late Holocene, i.e. the last 2.8 cal kyr, sediments of both lakes are again characterised by iron oxides, suggesting well-mixed, shallow water bodies. For this recent period, it seems that the detrital material in the two lakes had a common origin. Magnetic properties of sediments in Lakes Aibi and Manas show broadly similar environmental evolution during the late Pleistocene and Holocene. Nevertheless, despite the close proximity of the two lakes (~200 km) in the same basin, they display some different magnetic properties and record environmental changes at different times.     

Winter severity and snowiness and their multiannual variability in the Karkonosze Mountains and Jizera Mountains

This paper analyses winter severity and snow conditions in the Karkonosze Mountains and Jizera Mountains and examines their long-term trends. The analysis used modified comprehensive winter snowiness (WSW) and winter severity (WOW) indices as defined by Paczos (1982). An attempt was also made to determine the relationship between the WSW and WOW indices. Measurement data were obtained from eight stations operated by the Institute of Meteorology and Water Management – National Research Institute (IMGW–PIB), from eight stations operated by the Czech Hydrological and Meteorological Institute (CHMI) and also from the Meteorological Observatory of the University of Wroc?aw (UWr) on Mount Szrenica. Essentially, the study covered the period from 1961 to 2015. In some cases, however, the period analysed was shorter due to the limited availability of data, which was conditioned, inter alia, by the period of operation of the station in question, and its type.Viewed on a macroscale, snow conditions in the Karkonosze Mountains and Jizera Mountains (in similar altitude zones) are clearly more favourable on southern slopes than on northern ones. In the study area, negative trends have been observed with respect to both the WSW and WOW indices—winters have become less snowy and warmer. The correlation between the WOW and WSW indices is positive. At stations with northern macroexposure, WOW and WSW show greater correlation than at ones with southern macroexposure. This relationship is the weakest for stations that are situated in the upper ranges (Mount ?nie?ka and Mount Szrenica).     

From slots to tubes: The influence of dimensionality on fracture dissolution models

We briefly review the models of fracture dissolution process, discussing the experimental and numerical evidence showing that this phenomenon is inherently two-dimensional and hence cannot be accurately described by one-dimensional models. The physical reason for this incompatibility is that a dissolution front in a single rock fracture is potentially unstable to small variations in local permeability, leading to spontaneous formation of dissolution channels in the rock. This leads to a dramatic increase of fissure opening rates, which must be taken into account not only in the estimation of karstification times but also in the assessment of ground subsidence, dam collapse or toxic seepage risks.