Methane-derived authigenic carbonates from active hydrocarbon seeps of the St. Lawrence Estuary,Canada

Nearly 2000 pockmarks with diameters ranging from a few tens of meters up to 700 m are present on the seafloor of the St. Lawrence Estuary in eastern Canada. Coring of some pockmarks resulted in the recovery of various-sized and shaped carbonate concretions in a predominantly silty mud matrix. Petrographic and geochemical data on four authigenic carbonate concretions are reported as well as data from shell material in the unconsolidated sediment. Video observations and echo-sounder images indicate that the sampled pockmarks are actively gas venting. The video images show significant look-alike microbial mats in areas where gas is venting. The carbonate concretions are primarily made up of carbonate cements with varying percentage of shell fragments, micrite particles and fine-grained clastics. Orthorhombic crystal morphology and diagenetic fabrics including isopachous layers and botryoids characterize the aragonite cement. Oxygen isotopes ratios for the cement crusts do not record any thermal anomaly at the site of precipitation with δ¹⁸O_VPDB ratios (+3‰) in equilibrium with cold (5 °C) deep marine waters, whereas significant negative δ¹³C_VPDB ratios (−9.9 to −33.5‰) for cement and shell material within concretions indicate that the carbonates largely derive from the microbial oxidation of methane. The δ¹³C_VPDB ratios of aragonite shells (−2.7 to −5.6‰) taken from unconsolidated sediments at some distance from the concretions/vents show variable dilution of HCO₃⁻ with negative δ¹³C_VPDB ratios derived from microbial oxidation of methane with isotopically normal (0‰) marine bicarbonate. These results are in agreement with other lines of evidence suggesting that pockmarks formed through the recent and still active release of gas from a reservoir within the Paleozoic sedimentary succession.     

Deep seismic reflection and refraction profiling along the Aquitaine shelf (Bay of Biscay)

Summary. The 300 km ECORS - Bay of Biscay profile was carried out along the Aquitaine shelf and comprised a complete set of experiments including zero-offset and 7.5 km constant offset vertical seismic reflection and six expanding spread profiles. Large offset recordings were fundamental for the definition of the layered lower crust and the Moho, while ESPs provided decisive complementary information for the geological interpretation. These data show a strong variation in crustal thickness from about 20 km beneath the rifted Parentis basin, a failed arm of the oceanic Bay of Biscay, up to 35 km to the north below the Armorican shelf, in the Hercynian domain, and to the south below the Cantabria shelf, in the vicinity of the Pyrenean deformation front. The results have important implications for the behaviour of the crust during the formation of rifted sedimentary basins and during continental collision.     

Thick sections of layered ultramafic cumulates in the Oman ophiolite revealed by an airborne hyperspectral survey: Petrogenesis and relationship to mantle diapirism

Using the HyMap instrument, we have acquired visible and near infrared hyperspectral data over the Maqsad area of the Oman ophiolite (~ 15 × 60 km). This survey allowed us to identify and map the distribution of clinopyroxene-rich cumulates (inter-layered clinopyroxenites and wehrlites) whose occurrence was previously undocumented in this area. The cumulates reach several hundred meters in thickness and crop out at distances exceeding 15 km on both sides of the Maqsad former spreading centre. They occur either in mantle harzburgites, as km-sized layered intrusions surrounded by fields of pegmatitic dykes consisting of orthopyroxene-rich pyroxenite and gabbronorites, or at the base of the crustal section where they are conformably overlain by cumulate gabbros. These ultramafic cumulates crystallized from silica- and Mg-rich melts derived from a refractory mantle source (e.g. high Cr#, low [Al₂O₃], low [TiO₂]). These melts are close to high-Ca boninites, although, strictly speaking, not perfect equivalents of present-day, supra-subduction zone, boninites. Chemical stratigraphy reveals cycles of replenishment, mixing and fractional crystallization from primitive (high Mg#) melts, typical of open magma chambers and migration of inter-cumulus melts. The TiO₂ content of clinopyroxene is always low (≤ 0.2 wt.%) but quite variable compared to the associated pegmatites that are all derived from a source ultra-depleted in high field strength elements (HFSE). This variability is not caused by fractional crystallization alone, and is best explained by hybridization between the ultra-depleted melts (parent melts of the pegmatites) and the less depleted mid-ocean ridge basalts (MORB) parent of the dunitic–troctolitic–gabbroic cumulates making up the crustal section above the Maqsad diapir.We propose that, following a period of magma-starved spreading, the Maqsad mantle diapir, impregnated with tholeiitic melts of MORB affinity, reached shallow depths beneath the ocean ridge. This diapir induced melting of the formerly accreted and hydrothermally altered lithosphere. At this stage, these boninitic-like lithospheric melts crystallized as pegmatitic dykes. As the diapir continued to rise, the amount of MORB reaching shallow depths increased, together with the surrounding temperature, leading to the formation of magma chambers where the crystallization of layered cumulates became possible. These cumulates remained rich in pyroxene and devoid of plagioclase as long as the contribution of MORB-derived melts was moderate relative to the lithospheric-derived melts. As the contribution of MORB to the refilling of the magma chamber increased, gabbroic cumulates started to crystallize.     

Identification of a new outflow channel on Mars in Syrtis Major Planum using HRSC/MEx data

Syrtis Major Planum is a volcanic plain dominated by lava flows. High resolution stereo camera (HRSC) images of the northern Syrtis Major region display erosional features such as grooves, teardrop-shaped islands and valleys. These landforms are characteristics of outflow channels seen on Mars, therefore implying that a flood event took place in this region. The flow of 100 km long and a few kilometer wide followed the local slopes in most locations. Maximum flood discharges estimated from images and topography vary from about 0.3×10⁶ to 8×10⁶ m³/s, and therefore are in the range of terrestrial mega-floods in the Scablands or Lake Bonneville. In North Syrtis Major, the relationships with surrounding lava flows and the timing of the flood coeval to Syrtis Major volcanic activity suggest that it could be related to the subsurface water discharge mobilized by the volcanic activity. The proximity of Noachian age basement rocks 20 km away from the flood and below lava flows might have played a role in its formation and water presence.     

Crustal laminations in deep seismic profiles in France and neighbouring areas

Summary. Remarkable crustal features appear on the ECORS profiles carried out in northern France and the Bay of Biscay as well as on the SWAT profiles shot in the western Channel and the Celtic Sea. The most striking one is the occurrence of flat laminations in the lower crust. Dipping events and laminations are also present in the upper and lower crust, especially in the SWAT profiles. They can readily be related to tectonic events, Variscan in age, some of them identified in the field. The flat laminations in the lower crust are at first interpreted as resulting from delamination, shearing, magmatism and metamorphism at the crust-mantle transition during the Variscan orogeny. This interpretation raises some difficulty concerning the space and time correlation of the laminations with the Variscan orogeny. They seem to have been emplaced after the Permian-Triassic infilling of the Plymouth Bay basin and before the early Cretaceous opening of the Bay of Biscay. An early to middle Jurassic age is suggested, a period when large cratonic basins were formed without noticeable extension. Heat flow increase and magmatism are proposed as a second hypothesis for the formation of the lower crust laminations. Choosing between orogenic and non-orogenic causes of these laminations will require further deep seismic profiles together with good velocity determination.     

Contribution à la connaissance des romanéchites et des cryptomélanes — coronadites — hollandites. Traits essentiels et paragenèses

Chemical, thermal, X Ray analysis, and microscopic observation of romanechites, cryptomelanes, and coronadites indicate some specific features for each of these oxide.Structural calculation shows a theoretical ratio Ba/H₂O close to 12 for romanechite, slightly different for samples from cuirass. In the group cryptomelane, coronadite, hollandite the ratio: (Ba, K, Pb)/H₂O equals generaly 11, exceptionnally 12 under supergene conditions.Thermogravimetric curves indicate some weight loss starting at low temperature for romanechite and cryptomelane and higher temperature for coronadite and hollandite.Optical properties of these oxides seem to be more influenced by the evolution of the ore complex than by their own chemical particularities.The microscopic anisotropy is higher for romanechite and coronadite than for cryptomelane.Romanechite, cryptomelane, and coronadite present a great stability under surface conditions, where these oxides generally replace pyrolusite.     

Linking a linear pockmark train with a buried Palaeozoic structure: a case study from the St. Lawrence Estuary

The 15-km-long Matane pockmark train belongs to a series of NNE-striking alignments of pockmarks mapped on the seafloor of the St. Lawrence Estuary. It includes 109 pockmarks that show a complete transition from well-defined, relatively deep (up to 8.6 m), crater-like depressions to subtle, partly buried morphological features, suggesting that pockmarks have formed at different periods along the whole alignment and that the location of fluid release has changed through time. On seismic profiles, pockmarks are characterized by vertical seismic chimneys that root in the (fractured?) hinge zone of an open anticline within the autochthonous Palaeozoic rocks of the St. Lawrence Platform. In absence of a geochemical characterization of expelled gas, the relationship between the Matane pockmark train and the anticline in a domain characterized by mature source rocks is the strongest evidence for the genetic link between pockmarks and the release of gas from an active hydrocarbon system or a reservoir located in the Palaeozoic succession.

Askival: An altered feldspathic cumulate sample in Gale crater

Askival is a light-toned, coarsely crystalline float rock, which was identified near the base of Vera Rubin Ridge in Gale crater. We have studied Askival, principally with the ChemCam instrument but also using APXS compositional data and MAHLI images. Askival and an earlier identified sample, Bindi, represent two rare examples of feldspathic cumulate float rocks in Gale crater with >65% relict plagioclase. Bindi appears unaltered whereas Askival shows textural and compositional signatures of silicification, along with alkali remobilization and hydration. Askival likely experienced multiple stages of alteration, occurring first through acidic hydrolysis of metal cations, followed by deposition of silica and possible phyllosilicates at low T and neutral-alkaline pH. Through laser-induced breakdown spectroscopy compositional analyses and normative calculations, we suggest that an assemblage of Fe-Mg silicates including amphibole and pyroxene, Fe phases, and possibly Mg-rich phyllosilicate are present. Thermodynamic modeling of the more pristine Bindi composition predicts that amphibole and feldspar are stable within an upper crustal setting. This is consistent with the presence of amphibole in the parent igneous rocks of Askival and suggests that the paucity of amphiboles in other known Martian samples reflects the lack of representative samples of the Martian crust rather than their absence on Mars.     

Use of non-linear filtering for the regional–residual separation of potential field data

Regional–residual separation is essential in gravity and magnetic data interpretation and a variety of techniques have been proposed. Graphical determination of the regional allows geological information to be taken into account. Upward continuation can be used to obtain the regional field either empirically or using some hypothesis about the geology. In some cases, a matched filter can be designed and used to separate deep and shallow sources. Simple low pass filtering has also been used but without much success. Here we propose to use a non-linear filter approach to remove gravity and magnetic anomalies smaller than a given width. This technique attempts to mimic the graphical separation method. The results from synthetic models are presented as well as the results from a case study in eastern Canada and compared to regional gravity and magnetic anomalies obtained by other techniques. Contrary to the regional fields obtained by upward continuation, non-linear filtering does not have any physical meaning. However, its main advantage is that it gives a regional component of the gravity or magnetic field similar to the one obtained from a graphical separation.