Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

Atlas of Japan (East) Sea hydrographic properties in summer, 1999

Hydrographic properties from CTD and discrete bottle sample profiles covering the Japan (East) Sea in summer, 1999, are presented in vertical sections, maps at standard depths, maps on isopycnal surfaces, and as property–property distributions. This data set covers most of the Sea with the exception of the western boundary region and northern Tatar Strait, and includes nutrients, pH, alkalinity, and chlorofluorocarbons, as well as the usual temperature, salinity, and oxygen observations.     

The Ms = 6.2, June 15, 1995 Aigion earthquake (Greece): evidence for low angle normal faulting in the Corinth rift

We present the results of a multidisciplinary study of the M_s = 6.2, 1995, June 15, Aigion earthquake (Gulf of Corinth, Greece). In order to constrain the rupture geometry, we used all available data from seismology (local, regional and teleseismic records of the mainshock and of aftershocks), geodesy (GPS and SAR interferometry), and tectonics. Part of these data were obtained during a postseismic field study consisting of the surveying of 24 GPS points, the temporary installation of 20 digital seismometers, and a detailed field investigation for surface fault break. The Aigion fault was the only fault onland which showed detectable breaks (< 4 cm). We relocated the mainshock hypocenter at 10 km in depth, 38 ° 21.7 N, 22 ° 12.0 E, about 15 km NNE to the damaged city of Aigion. The modeling of teleseismic P and SH waves provides a seismic moment M_o = 3.4 10¹⁸ N.m, a well constrained focal mechanism (strike 277 °, dip 33 °, rake – 77°), at a centroidal depth of 7.2 km, consistent with the NEIC and the revised Harvard determinations. It thus involved almost pure normal faulting in agreement with the tectonics of the Gulf. The horizontal GPS displacements corrected for the opening of the gulf (1.5 cm/year) show a well-resolved 7 cm northward motion above the hypocenter, which eliminates the possibility of a steep, south-dipping fault plane. Fitting the S-wave polarization at SERG, 10 km from the epicenter, with a 33° northward dipping plane implies a hypocentral depth greater than 10 km. The north dipping fault plane provides a poor fit to the GPS data at the southern points when a homogeneous elastic half-space is considered: the best fit geodetic model is obtained for a fault shallower by 2 km, assuming the same dip. We show with a two-dimensional model that this depth difference is probably due to the distorting effect of the shallow, low-rigidity sediments of the gulf and of its edges. The best-fit fault model, with dimensions 9 km E–W and 15 km along dip, and a 0.87 m uniform slip, fits InSAR data covering the time of the earthquake. The fault is located about 10 km east-northeast to the Aigion fault, whose surface breaks thus appears as secondary features. The rupture lasted 4 to 5 s, propagating southward and upward on a fault probably outcropping offshore, near the southern edge of the gulf. In the shallowest 4 km, the slip – if any – has not exceeded about 30 cm. This geometry implies a large directivity effect in Aigion, in agreement with the accelerogram aig which shows a short duration (2 s) and a large amplitude (0.5 g) of the direct S acceleration. This unusual low-angle normal faulting may have been favoured by a low-friction, high pore pressure fault zone, or by a rotation of the stress directions due to the possible dip towards the south of the brittle-ductile transition zone. This fault cannot be responsible for the long term topography of the rift, which is controlled by larger normal faults with larger dip angles, implying either a seldom, or a more recently started activity of such low angle faults in the central part of the rift.     

EN photographic Perseids

Many Perseid meteors were photographed in the Czech part of the European Fireball Network during the activity of the new strong and sharp maximum on August 12, 1993. Basic data on many of them were evaluated and radiants, atmospheric trajectories and some orbital elements are presented here and compared with atmospheric and orbital data of regular Perseids, which were photographed outside the new activity in 1993 and preceding years. No substantial difference between these two groups of Perseid meteors was found.     

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.     

Isotope Evidences of the Paleozoic Stage of Epigenetic Transformation of Vendian Sediments of the Russian Platform

The Rb–Sr characteristics of whole-rock samples of Upper Vendian clayey rocks recovered by Gavrilov-Yam boreholes are studied. The Rb–Sr age versus sampling depth relationship has been revealed. Three sample assemblages are identified. The errorchron relationship of samples in the first interval (1760–2400 m) fits the age of 390 ± 40 Ma corresponding to the initial Hercynian history characterized by the transformation of platformal sediments. The other two assemblages (2410–2525 and 2528–2560 m) make up isochrons with slopes corresponding to 590 ± 50 and 690 ± 10 Ma, respectively. Their geochronological meaning is unclear.     

Optimal Model for Geoid Determination from Airborne Gravity

Two different approaches for transformation of airborne gravity disturbances, derived from gravity observations at low-elevation flying platforms, into geoidal undulations are formulated, tested and discussed in this contribution. Their mathematical models are based on Green's integral equations. They are in these two approaches defined at two different levels and also applied in a mutually reversed order. While one of these approaches corresponds to the classical method commonly applied in processing of ground gravity data, the other approach represents a new method for processing of gravity data in geoid determination that is unique to airborne gravimetry. Although theoretically equivalent in the continuous sense, both approaches are tested numerically for possible numerical advantages, especially due to the inverse of discretized Fredholm's integral equation of the first kind applied on different data. High-frequency synthetic gravity data burdened by the 2-mGal random noise, that are expected from current airborne gravity systems, are used for numerical testing. The results show that both approaches can deliver for the given data a comparable cm-level accuracy of the geoidal undulations. The new approach has, however, significantly higher computational efficiency. It would be thus recommended for real life geoid computations. Additional errors related to regularization of gravity data and the geoid, and to accuracy of the reference field, that would further deteriorate the quality of estimated geoidal undulations, are not considered in this study.     

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.