Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

极地冰钻关键技术研究进展

极地冰钻技术是获取冰芯,研究冰盖-冰架-海洋相互作用,以及获取极地冰下基岩与冰下水环境样品,开展冰下环境探测的重要手段。目前极地冰钻技术的难点与前沿主要包括深冰芯钻探、冰架热水钻、冰下基岩钻和冰下水环境采样与观测技术。本文针对以上4个极地冰钻关键技术,对国内外相关技术的研究进展与项目开展情况进行了总结与梳理。综合来看,虽然我国开展极地钻探技术研究起步较晚,但随着我国极地战略不断推进,我国的极地冰钻关键技术与装备的研究正持续向着赶超极地钻探强国方向迈进,这必将为我国的极地科学研究提供强有力的技术支撑。     

Spherical integral transforms of second-order gravitational tensor components onto third-order gravitational tensor components

New spherical integral formulas between components of the second- and third-order gravitational tensors are formulated in this article. First, we review the nomenclature and basic properties of the second- and third-order gravitational tensors. Initial points of mathematical derivations, i.e., the second- and third-order differential operators defined in the spherical local North-oriented reference frame and the analytical solutions of the gradiometric boundary-value problem, are also summarized. Secondly, we apply the third-order differential operators to the analytical solutions of the gradiometric boundary-value problem which gives 30 new integral formulas transforming (1) vertical-vertical, (2) vertical-horizontal and (3) horizontal-horizontal second-order gravitational tensor components onto their third-order counterparts. Using spherical polar coordinates related sub-integral kernels can efficiently be decomposed into azimuthal and isotropic parts. Both spectral and closed forms of the isotropic kernels are provided and their limits are investigated. Thirdly, numerical experiments are performed to test the consistency of the new integral transforms and to investigate properties of the sub-integral kernels. The new mathematical apparatus is valid for any harmonic potential field and may be exploited, e.g., when gravitational/magnetic second- and third-order tensor components become available in the future. The new integral formulas also extend the well-known Meissl diagram and enrich the theoretical apparatus of geodesy.     

Hydrologic impacts of climate change on the Nile River Basin: implications of the 2007 IPCC scenarios

We assess the potential impacts of climate change on the hydrology and water resources of the Nile River basin using a macroscale hydrology model. Model inputs are bias corrected and spatially downscaled 21st Century simulations from 11 General Circulation Models (GCMs) and two global emissions scenarios (A2 and B1) archived from the 2007 IPCC Fourth Assessment Report (AR4). While all GCMs agree with respect to the direction of 21st Century temperature changes, there is considerable variability in the magnitude, direction, and seasonality of projected precipitation changes. Our simulations show that, averaged over all 11 GCMs, the Nile River is expected to experience increase in streamflow early in the study period (2010–2039), due to generally increased precipitation. Streamflow is expected to decline during mid- (2040–2069) and late (2070–2099) century as a result of both precipitation declines and increased evaporative demand. The predicted multimodel average streamflow at High Aswan Dam (HAD) as a percentage of historical (1950–1999) annual average are 111 (114), 92 (93) and 84 (87) for A2 (B1) global emissions scenarios. Implications of these streamflow changes on the water resources of the Nile River basin were analyzed by quantifying the annual hydropower production and irrigation water release at HAD. The long-term HAD release for irrigation increases early in the century to 106 (109)% of historical, and then decreases to 87 (89) and 86 (84)% of historical in Periods II and III, respectively, for the A2 (B1) global emissions scenarios. Egypt’s hydropower production from HAD will be above the mean annual average historical value of about 10,000 GWH for the early part of 21st century, and thereafter will generally follow the streamflow trend, however with large variability among GCMs. Agricultural water supplies will be negatively impacted, especially in the second half of the century.     

极地深部冰层取心钻探孔壁水压致裂研究

为了维护极地深部冰层取心钻探工作中钻孔的稳定,避免孔内事故的发生,冰层孔壁的水压致裂问题是亟待解决的重要科学问题之一。本文在深入分析国内外冰层钻探资料的基础上,结合冰盖动力学相关理论,计算得出了钻孔所在区域冰层的密度、温度及内部应力随深度的变化规律。在此基础上,结合油气资源勘探水力压裂技术与冰层钻进钻井液等相关理论,建立了合理的孔壁压差计算方法,深入探讨了适用于深部冰层钻探孔壁水压致裂机理。研制了冰层钻孔水压致裂模拟实验装置,可分析研究不同围压条件下冰样的脆性变形机理。结合我国Dome A深冰心钻探工程实际,提出钻孔可能发生水压致裂的深度区域及孔壁所需的起始裂纹长度判定,以期为后续的安全高效冰层钻进提供重要的理论依据。     

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.     

The first record of “spelaeoid” bears in Arctic Siberia

For a long time, “spelaeoid” (cave-bear-like) bears, Ursus (Spelearctos) spp., were believed to be almost purely European animals. Their geographic range has recently been extended to the east, in southern Siberia, Transbaikalia, Kirghizia, Mongolia and Korea. Two unexpected new findings, presented here in detail, significantly change existing views on the distribution of cave bears; both were found in North-Eastern Siberia, far beyond the Arctic Circle, more than 1500 km to the north-east of the previously accepted range.One of the fossils is a mandible, found near the town of Cherskiy at 68.73°N, 161.38°E. The analysis of local geology and accompanying mammal fossils suggests that it comes from the Olyorian Fauna (Early to early Middle Pleistocene). Morphologically, the Cherskiy mandible is closest to Ursus savini, a small middle Pleistocene cave bear from the British Cromer Forest-bed Formation, but differs in having a slightly more advanced dentition, and thus it is described as a new subspecies Ursus savini nordostensis. Another newly recognized fossil of the “spelaeoid” bear is an astragalus found at the Oskhordokh site at 67.54°N, 135.67°E, on a large gravel bar on the right bank of the Adycha River. This specimen is attributed to Ursus cf. deningeri.The paper also presents an interesting example of the interaction between classical and “molecular” palaeontology.The new finds significantly change existing ideas on the ecology and evolution of cave bears, some of the most remarkable members of the extinct Pleistocene megafauna.     

Paleontological records indicate the occurrence of open woodlands in a dry inland climate at the present-day Arctic coast in western Beringia during the Last Interglacial

Permafrost records, accessible at outcrops along the coast of Oyogos Yar at the Dmitry Laptev Strait, NE-Siberia, provide unique insights into the environmental history of Western Beringia during the Last Interglacial. The remains of terrestrial and freshwater organisms, including plants, coleopterans, chironomids, cladocerans, ostracods and molluscs, have been preserved in the frozen deposits of a shallow paleo-lake and indicate a boreal climate at the present-day arctic mainland coast during the Last Interglacial. Terrestrial beetle and plant remains suggest the former existence of open forest-tundra with larch (Larix dahurica), tree alder (Alnus incana), birch and alder shrubs (Duschekia fruticosa, Betula fruticosa, Betula divaricata, Betula nana), interspersed with patches of steppe and meadows. Consequently, the tree line was shifted to at least 270 km north of its current position. Aquatic organisms, such as chironomids, cladocerans, ostracods, molluscs and hydrophytes, indicate the formation of a shallow lake as the result of thermokarst processes. Steppe plants and beetles suggest low net precipitation. Littoral pioneer plants and chironomids indicate intense lake level fluctuations due to high evaporation. Many of the organisms are thermophilous, indicating a mean air temperature of the warmest month that was greater than 13 °C, which is above the minimum requirements for tree growth. These temperatures are in contrast to the modern values of less than 4 °C in the study area. The terrestrial and freshwater organism remains were found at a coastal exposure that was only 3.5 m above sea level and in a position where they should have been under sea during the Last Interglacial when the global sea level was 6–10 m higher than the current levels. The results suggest that during the last warm stage, the site was inland, and its modern coastal situation is the result of tectonic subsidence.     

Ziminaite,Fe3+VO4, a new howardevansite-group mineral from the Bezymyannyi volcano,Kamchatka, Russia

Mineralogy and Petrology - The new mineral ziminaite, ideally Fe3+VO4, was found in fumarole sublimates at the Bezymyannyi volcano, Kamchatka, Russia. Ziminaite occurs as lamellar, tabular or...