Late Hercynian–Mesozoic thinning in the Alboran domain: metamorphic data from the northern Rif, Morocco

In the Alboran domain, two crustal-thickening late-orogenic extension cycles are superposed. The importance of the late Alpine thinning of the Alpujarride-Sebtide crustal section on top of the Beni Bousera peridotites is discussed here in metamorphic petrological terms. The Alpine metamorphism operated first under a HP–LT gradient, and reached the eclogite facies in the Permian–Triassic phyllites, before retrogression under a high geothermal gradient. A contrasting, higher temperature metamorphism characterizes the pre-Permian section, reaching the HP-granulite facies at the bottom of the crustal section. By reference to the western European setting, the granulites relate to the Hercynian orogeny, as supported by the isotopic ages of the enclosed, armoured monazite crystals. Thus, thinning of an overthickened crust might have occurred there during the late Hercynian extension and Tethyan opening, before being reactivated during the late Oligocene.     

Reliability based risk index for the design of reinforced earth structures

The design methods currently used for earth reinforcement are mostly based on deterministic properties of both the soil and the construction materials used. Nowadays, however, the general trend is designing at a specific degree of reliability. This is even more true where the raw data such as soil properties exhibit significant variation. Deterministic solutions, in this case, may not suffice. Therefore, this paper will attempt to use probabilistic formulations thereby modifying the existing design procedure of reinforced earth retaining walls to account for uncertainties and variabilities. Through a first order Taylor's series expansion about the mean, the mean and variance of the strip reinforcing components, namely width and length, are derived in terms of the variations in the soil properties. Design charts that enable estimation of both mean and variance are developed to avoid extensive partial differentiation involved in the computations. Using appropriate probability distributions along with the mean and variance, the final design outputs are determined for a selected failure probability by introducing what is refered to as 'risk index'. The results indicate that the risk index increases with an increase in the coefficient of variations and a decrease in failure probability. Furthermore, it is shown that in some cases, depending on the variabilities of the soil properties, the classical design technique produced a relatively high failure probability. This revised version was published online in July 2006 with corrections to the Cover Date.     

Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.     

Post‐Variscan exhumation of the Central Anti‐Atlas (Morocco) constrained by zircon and apatite fission‐track thermochronology

The origin of the Anti‐Atlas relief is one of the currently debated issues of Moroccan geology. To constrain the post‐Variscan evolution of the Central Anti‐Atlas, we collected nine samples from the Precambrian basement of the Bou Azzer‐El Graara inlier for zircon and apatite fission‐track thermochronology. Zircon ages cluster between 340 ± 20 and 306 ± 20 Ma, whereas apatite ages range from 171 ± 7 Ma to 133 ± 5 Ma. Zircon ages reflect the thermal effect of the Variscan orogeny (tectonic thickening of the ca. 7 km‐thick Paleozoic series), likely enhanced by fluid advection. Apatite ages record a complex Mesozoic–Cenozoic exhumation history. Track length modelling yields evidence that, (i) the Precambrian basement was still buried at ca. 5 km depth by Permian times, (ii) the Central Anti‐Atlas was subjected to (erosional) exhumation during the Triassic‐Early Cretaceous, then buried beneath ca. 1.5 km‐thick Cretaceous‐Paleogene deposits, (iii) final exhumation took place during the Neogene, contemporaneously with that of the High Atlas.     

Contribution of remote sensing and GIS to analysis of the risk of flooding in the Zat basin (High Atlas-Morocco)

Natural Hazards - Despite the controversy regarding their use, school buildings are often assigned as emergency evacuation shelters, temporary accommodation and aid distribution hubs following...     

Metal-enriched nanoparticles and black carbon: A perspective from the Brazil railway system air pollution

Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public transport. This study measured, for the first time in Brazil, nanoparticles (NPs) and black carbon (BC) on two ground-level platforms and inside trains of the Metropolitan Area of Porto Alegre (MAPA). An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy techniques. The results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger densities. Also, internal and external sources of pollution at the stations were identified. The predominance of NPs enriched with metals that increase oxidative stress like Cd, Fe, Pb, Cr, Zn, Ni, V, Hg, Sn, and Ba both on the platforms and inside trains, including Fe-minerals as hematite and magnetite, represents a critical risk to the health of passengers and employees of the system. This interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols.     

Probabilistic earthquake risk assessment using CAPRA: application to the city of Barcelona, Spain

The risk evaluation model CAPRA (Comprehensive Approach to Probabilistic Risk Assessment) is a techno-scientific methodology and information platform, composed of tools for evaluating and communicating risk at various territorial levels. The model allows evaluating losses on exposed elements using probabilistic metrics, such as the loss exceedance curve, the expected annual loss and the probable maximum loss, useful for multi-hazard risk analyses. In this article, the process of probabilistic seismic risk analysis is described, explaining the main features of the CAPRA modules of hazard, vulnerability and risk estimation applied to the city of Barcelona, Spain. In addition, according to the physical risk results and the information on the socioeconomic indicators of the city, this article presents the holistic evaluation of seismic risk, which is a valuable result to facilitate the integrated risk management by the different stakeholders involved in risk reduction decision making.     

Prediction of Engineering Properties of Basalt Rock in Jordan Using Ultrasonic Pulse Velocity Test

Basalt is an extrusive igneous rock derived from Lava and spread over different localities in Jordan. It can be used in industrial applications, and as construction materials. Before using basalt, it is essential to determine its dry density, porosity, uniaxial compressive strength, and Brazilian tensile strength. The testing procedure and sample preparation used to determine the engineering properties are time-consuming and need expertise. Hence, the ultrasonic pulse velocity (UPV) test, a quick and non-destructive evaluation method, was used to determine the engineering properties. Empirical relationships for determination of dry density, porosity, uniaxial compressive strength, Brazilian tensile strength, and tangent modulus of elasticity were deduced. Good correlation coefficients (R²?=?0.832–0.929) were obtained between UPV and dry density, porosity, uniaxial compressive strength, Brazilian tensile strength and modulus of elasticity. These correlations were limited to intact basalt with UPV?≥?4000 m/s.     

Atomic structures and energies of grain boundaries in Mg2SiO4 forsterite from atomistic modeling

Grain boundaries influence many physical and chemical properties of crystalline materials. Here, we perform molecular dynamics simulations to study the structure of a series of [100] symmetric tilt grain boundaries in Mg₂SiO₄ forsterite. The present results show that grain boundary energies depend significantly on misorientation angle. For small misorientation angles (up to 22°), grain boundary structures consist of an array of partial edge dislocations with Burgers vector $\frac{1}{2}[001]$ associated with stacking faults and their energies can be readily fit with a model which adds the Peach-Koehler equation to the Read-Shockley dislocation model for grain boundaries. The core radius of partial dislocations and the spacing between the partials derived from grain boundary energies show that the transition from low- to high-angle grain boundaries occurs for a misorientation angle between 22° and 32°. For high misorientation angles (32.1° and 60.8°), the cores of dislocations overlap and form repeated structural units. Finally, we use a low energy atomic configuration obtained by molecular dynamics for the misorientation of 12.18° as input to simulate a high-resolution transmission electron microscopy (HRTEM) image. The simulated image is in good agreement with an observed HRTEM image, which indicates the power of the present approach to predict realistic atomic structures of grain boundaries in complex silicates.