Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

Fe57 Mossbauer spectroscopy of the Leoville meteorite

The Mossbauer spectra has been measured for the Leoville meteorite. Experimental results identify it as a type III carbonaceous meteorite. The spectrum shows the principle iron components to be olivine, magnetite, metallic iron, troilite and phyllosilicate material.     

Proximity of galactic civilizations

Approximate expressions are derived for the number of civilizations within a few tens of light years of each other since intelligent life first evolved in the Galaxy. The number is proportional to the square of the usual selectivity factors and to the first power of the longevity. Arguments are presented for expecting intelligent life in certain multiple star systems, and the number of coexistent civilizations in such systems is estimated.     

Rapid orbit determination of LEO satellites using IGS clock and ephemeris products

Different types of GPS clock and orbit data provided by the International GPS Service (IGS) have been used to assess the accuracy of rapid orbit determination for satellites in low Earth orbit (LEO) using spaceborne GPS measurements. To avoid the need for reference measurements from ground-based reference receivers, the analysis is based on an undifferenced processing of GPS code and carrier-phase measurements. Special attention is therefore given to the quality of GPS clock data that directly affects the resulting orbit determination accuracy. Interpolation of clock data from the available 15 min grid points is identified as a limiting factor in the use of IGS ultra-rapid ephemerides. Despite this restriction, a 10-cm orbit determination accuracy can be obtained with these products data as demonstrated for the GRACE-B spacecraft during selected data arcs between 2002 and 2004. This performance may be compared with a 5-cm orbit determination accuracy achievable with IGS rapid and final products using 5 min clock samples. For improved accuracy, high-rate (30 s) clock solutions are recommended that are presently only available from individual IGS centers. Likewise, a reduced latency and more frequent updates of IGS ultra-rapid ephemerides are desirable to meet the requirements of upcoming satellite missions for near real-time and precise orbit determination.     

High-T, low-P metamorphism in the Palaeoproterozoic Halls Creek Orogen, northern Australia: the middle crustal response to a mantle-related transient thermal pulse

High‐T, low‐P metamorphic rocks of the Palaeoproterozoic central Halls Creek Orogen in northern Australia are characterised by low radiogenic heat production, high upper crustal thermal gradients (locally exceeding 40 °C km^?1) sustained for over 30 Myr, and a large number of layered mafic‐ultramafic intrusions with mantle‐related geochemical signatures. In order to account for this combination of geological and thermal characteristics, we model the middle crustal response to a transient mantle‐related heat pulse resulting from a temporary reduction in the thickness of the mantle lithosphere. This mechanism has the potential to raise mid‐crustal temperatures by 150–400 °C within 10–20 Myr following initiation of the mantle temperature anomaly, via conductive dissipation through the crust. The magnitude and timing of maximum temperatures attained depend strongly on the proximity, duration and lateral extent of the thermal anomaly in the mantle lithosphere, and decrease sharply in response to anomalies that are seated deeper than 50–60 km, maintained for <5 Myr in duration and/or have half‐widths <100 km. Maximum temperatures are also intimately linked to the thermal properties of the model crust, primarily due to their influence on the steady‐state (background) thermal gradient. The amplitudes of temperature increases in the crust are principally a function of depth, and are broadly independent of crustal thermal parameters. Mid‐crustal felsic and mafic plutonism is a predictable consequence of perturbed thermal regimes in the mantle and the lowermost crust, and the advection of voluminous magmas has the potential to raise temperatures in the middle crust very quickly. Although pluton‐related thermal signatures significantly dissipate within <10 Myr (even for very large, high‐temperature intrusive bodies), the interaction of pluton‐ and mantle‐related thermal effects has the potential to maintain host rock temperatures in excess of 400–450 °C for up to 30 Myr in some parts of the mid‐crust. The numerical models presented here support the notion that transient mantle‐related heat sources have the capacity to contribute significantly to the thermal budget of metamorphism in high‐T, low‐P metamorphic belts, especially in those characterised by low surface heat flow, very high peak metamorphic geothermal gradients and abundant mafic intrusions.     

Leucoxene fish as a micro-kinematic indicator

Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis.     

Effective elastic properties of randomly fractured soils: 3D numerical experiments

This paper is concerned with numerical tests of several rock physical relationships. The focus is on effective velocities and scattering attenuation in 3D fractured media. We apply the so‐called rotated staggered finite‐difference grid (RSG) technique for numerical experiments. Using this modified grid, it is possible to simulate the propagation of elastic waves in a 3D medium containing cracks, pores or free surfaces without applying explicit boundary conditions and without averaging the elastic moduli. We simulate the propagation of plane waves through a set of randomly cracked 3D media. In these numerical experiments we vary the number and the distribution of cracks. The synthetic results are compared with several (most popular) theories predicting the effective elastic properties of fractured materials. We find that, for randomly distributed and randomly orientated non‐intersecting thin penny‐shaped dry cracks, the numerical simulations of P‐ and S‐wave velocities are in good agreement with the predictions of the self‐consistent approximation. We observe similar results for fluid‐filled cracks. The standard Gassmann equation cannot be applied to our 3D fractured media, although we have very low porosity in our models. This is explained by the absence of a connected porosity. There is only a slight difference in effective velocities between the cases of intersecting and non‐intersecting cracks. This can be clearly demonstrated up to a crack density that is close to the connectivity percolation threshold. For crack densities beyond this threshold, we observe that the differential effective‐medium (DEM) theory gives the best fit with numerical results for intersecting cracks. Additionally, it is shown that the scattering attenuation coefficient (of the mean field) predicted by the classical Hudson approach is in excellent agreement with our numerical results.     

The lower marine to lower freshwater Molasse transition in the northern Alpine foreland basin (Oligocene; central Switzerland–south Germany): age and geodynamic implications

The Wilhelmine Alpe section near Immenstadt (Allgäu, south Germany), which represents one of the best continuously exposed outcrops within the northern Alpine foreland basin, has been analyzed for magnetostratigraphic and palynostratigraphic signals. The section comprises the marine-to-terrestrial transition from Lower Marine (UMM) to Lower Freshwater Molasse (USM) sediments. Based on the correlation of the local magnetic pattern with the geomagnetic polarity timescale (GPTS) and palynostratigraphic data, an age of about 31 Ma is suggested for the UMM–USM transition in the Wilhelmine Alpe section. A comparison with coeval magnetostratigraphic sections from central and eastern Switzerland indicates that the regression of the UMM sea along the southern margin of the Molasse basin occurred strongly heterochronously between 31.5 and 30 Ma. The heterochroneity is attributed to the deposition of fan-delta and alluvial fan sediments which document that the overall marine conditions during the UMM were accompanied by strong clastic input derived from the rising Alps. This clastic contribution had a much stronger influence on the depositional pattern than previously thought.