Microtextures and crystal chemistry of pigeonite in the ureilites ALHA77257, RKPA80239, Y‐791538, and ALHA81101

Abstract— The microtextures of pigeonite in four ureilites, Allan Hills (ALH) 77257, Reckling Peak (RKP) A80239, Yamato (Y‐) 791538, and Allan Hills A81101, chosen to span a range of composition and shock level, were investigated by transmission electron microscopy (TEM); two of the samples were also investigated by single crystal X‐ray diffraction to determine Fe²⁺‐Mg cation site partitioning. The low‐shock and compositionally homogeneous pigeonites in ALHA77257 and RKPA80329 (Wo 6.4 for both, mg 86.3 and 84.3 respectively) display irregularly spaced, shock‐induced stacking faults oriented parallel to (100), and large antiphase domains (50–100 nm). Antiphase domains have no preferential orientation. No evidence of exsolution was observed. The low‐shock Y‐791538 pigeonite is homogeneous and has higher Ca and mg (Wo 9.4, mg 91.2). TEM investigation showed spinodal decomposition, indicative of incipient exsolution; small antiphase domains were observed (～5 nm). Single crystal refinement yielded R_4s? = 5.71%, with Fe²⁺‐Mg partitioning coefficient k_d = 0.077(8) and T_c = 658(35) °C. ALHA81101 has compositionally heterogeneous pyroxenes, with large local variations in Wo and mg (Wo = 4–13, mg = 86–68). No compositional gradients from core to rim of grains were observed, and the heterogeneity is interpreted as related to cation migration during shock. In one relatively Ca‐rich region (Wo～12), TEM analysis showed augite‐pigeonite exsolution lamellae, with spacing 145(20) nm. Results for ALHA77257, RKPA80239, and Y‐791538 support a model of rapid cooling following breakup of the ureilite parent body. The presence of exsolution lamellae in ALHA81101 can be related to a local shock‐induced Ca enrichment and provides no constraint on the late cooling history.     

The luminosity oscillation of X-ray bursters and recurrent novae

Thermo-mechanical oscillations of a radiating spherically-symmetric shell containing a fermion gas (i.e., oscillation where only mechanical, thermodynamical, and eventually radiation phenomena are taken into account) are studied. With a reasonable choice of the three relevant parameters all other observational data are similar to the ones of X-ray bursters and recurrent novae.Therefore, thermo-mechanical oscillations could play an important role in the oscillation spectrum of these astronomical objects.     

华北板块北缘东段陆缘活动带构造岩片划分及变质变形特征

1∶25万和龙市幅、汪清县幅等九幅区域地质调查成果显示,华北板块北缘东段残存着数条元古代-古生代不同时期的构造岩片,这些构造岩片均经历了强烈的变形改造及变质作用叠加,记录了增生型造山带在不同演化阶段热-动力学条件。吉林东部华北板块北缘陆缘活动带东段内元古代-古生代构造地层单位的确定,对探讨吉黑地区的大地构造演化具有重要意义。     

A new calibration of Wesselink's correlation for the determination of stellar radii

By means of a new homogeneous set of data from 34 double-lined detached systems, we have recalibrated the colour-surface brightness correlation in the interval –0.3(B-V)_o0.95. A comparison is made with Wesselink's calibration. We find that Wesselink's method can provide a good estimate of the stellar radii.     

鄂尔多斯盆地奥陶系马家沟组溶斑形成机理

鄂尔多斯盆地中部气田奥陶系马家沟组属蒸发边缘海相地层,其风化壳是中部气田的主要产气层段。该层中广泛发育毫米级、厘米级的溶斑,这些溶斑的产状、大小、成分以及溶孔内的充填物十分复杂,有的具多期充填,充填物为石膏、石英、方解石、白云石、高岭石、黄铁矿等多种矿物。溶斑中下半部残留的岩石经溶蚀后的白云石晶粒形成的渗流砂示底构造十分明显。研究表明,溶斑的形成不仅具有适宜的岩相古地理环境和其复杂的生成演化史,而且与原始沉积以及不同地史阶段的岩溶作用相关。     

煤层上覆地层含水不均匀性电法探测的可能性

煤田上覆岩层中含水直接对煤层的开采构成威胁，本文先从理论上阐述了电阻率勘探可以探测煤层上覆地层含水不均匀性的可能性，然后用简单的断层型薄层含水模型的CSAMT正演模拟结果展示出：地下900m深处，尽管只有20m厚的的含水岩层，但在电阻率剖面上该薄层的反映具有非常明显的特征，从理论上和数值模拟实例说明，一定深度内一定厚度的薄层含水性的电阻率法探测是可能的。     

A calderas field at the Marifil Formation, new volcanogenic interpretation, Norpatagonian Massif, Argentina

Major volcanogenic structures within the Marifil Formation allowed to determine the location of a claderas field that spreads along 400 kilometers. This field has at least three large calderas with diameters near to 100 kilometers, recognizable by regional distribution of associated dikes and rhyolite lava flows present at the caldera border that separates a monotonous ignimbritic plateau from a depressed (150 meters) inner volcanic collapsed caldera. The Marifil ignimbritic plateau cover more than 50,000 square kilometers with thicknesses that reach 800 meters. Associated with these plateau ignimbrites there is an important fluorite mineralization.     

Design of backfilled thin-seam coal pillars using earth pressure theory

In underground coal mining any increase in coal recovery rate is dependent on a decrease in pillar size. Backfilling is one way of reducing the required size of pillars and hence the volume of coal left underground. Therefore any comparisons made between a self-supported mine layout and backfill supported mine layout are based directly on pillar design. The most effective way to examine the effect of backfill on pillar support, and subsequently the rate of recovery, would be to incorporate the mechanisms of backfill support directly into the current design procedure for coal pillars. This paper presents a review of the mechanics of backfill support, a method of estimating the magnitude of that support based on earth pressure theory, and an example that incorporates backfill support into current coal pillar design.     

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

Argon isotope fractionation induced by stepwise heating

Noble gas isotopes are widely used to elucidate the history of the rocks in which they have been trapped, either from distinct reservoirs or by accumulation following radioactive decay. To extract noble gases from their host rocks, stepwise heating is the most commonly used technique to deconvolve isotopically different components, e.g., atmospheric, in situ radiogenic, or excess radiogenic from mantle or crustal reservoirs. The accurate determination of the isotopic composition of these different components is of crucial importance, e.g., for ages obtained by ⁴⁰Ar-³⁹Ar stepheating plateaus. However, diffusion theory-based model calculations predict that the stepwise thermal extraction process from mineral phases induces isotope fractionation and, hence, adulterates the original composition. Such effects are largely unconsidered, as they are small and a compelling experimental observation is lacking. We report the first unequivocal evidence for significant mass fractionation of argon isotopes during thermal extraction, observed on shungite, a carbon-rich Precambrian sedimentary rock. The degree of fractionation, as monitored by ³⁸Ar/³⁶Ar and ⁴⁰Ar/³⁶Ar ratios, very well agrees with theoretical predictions assuming an inverse square root dependence of diffusion coefficient and atomic mass, resulting in easier extraction of lighter isotopes. Hence, subatmospheric ⁴⁰Ar/³⁶Ar ratios obtained for argon extracted at low temperatures may not represent paleoatmospheric argon. Shungite argon resembles modern atmospheric composition, but constraints on the timing of trapping appear difficult to obtain, as shungites are multicomponent systems.In ⁴⁰Ar-³⁹Ar stepwise heating, the isotope fractionation effect could cause systematic underestimations of plateau ages, between 0.15 and 0.4% depending on age, or considerably higher if samples contain appreciable atmospheric Ar. The magnitude of this effect is similar to the presently achieved uncertainties of this increasingly precise dating technique. Our results also indicate the importance of thermally activated diffusion as a possible fractionation mechanism, e.g., for hydrothermal gas exhalations, or for carbonaceous carrier phases such as “Q” in meteorites that have been suggested as carriers of highly fractionated noble gas residues from the early solar nebula.