Nutrient budgets and trophic state in a hypersaline coastal lagoon: Lagoa de Araruama, Brazil

Lagoa de Araruama in the state of Rio de Janeiro, Brazil, is a hypersaline lagoon with salinity varying spatially from 45 to 56. We collected water samples during monthly cruises throughout the lagoon, and along the streams feeding the system, from April 1991 to March 1992. Nutrients and other water quality parameters exhibited great spatial and temporal variations. Mass balance calculations indicate large amounts of anthropogenic nutrient inputs. The data indicate that the lagoon currently is oligotrophic but is in a state of transition to become a mesotrophic system. Molar dissolved inorganic nitrogen:dissolved inorganic phosphorus (DIN/DIP) varied between 2.2:1 and 659:1 with a volume-weighted average of 22:1. The high DIN/DIP ratio contrasts with that found in nearby lagoons, suggesting that phytoplankton primary production is limited by phosphorus in Lagoa de Araruama. The major loss of DIP is apparently driven by biological assimilation and diagenic reactions in the sediments. Calculations indicate that the lagoon is slightly net autotrophic at +0.9 mol C m⁻² yr⁻¹. This suggests that the biomass of the primary producers is restricted by phosphorus availability. Phosphorus retention in the sediment and the hypersaline state of the lagoon prevent changes in autotrophic communities and the formation of eutrophic conditions.     

Estimating Buoyancy Heat Flux Using the Surface Renewal Technique over Four Amazonian Forest Sites in Brazil

The surface renewal (SR) method was applied for the first time to measurements of air temperature over four Amazonian forest sites and different seasons in order to obtain estimates of buoyancy heat flux. The required calibration of this method against eddy covariance resulted in a value for a specific parameter that is close to the range reported in other studies, contributing to the generalization of the SR method to different kinds of canopies. The comparison with fluxes obtained using the eddy covariance technique revealed a good match between the two methods for different sites, heights and seasons. Sites with high levels of non-stationarity in the signals of temperature and wind speed presented higher scatter in the regression with fluxes from eddy covariance. For a particular site with previously reported influence of low-frequency motions, the regression was only satisfactory, i.e., slope parameter close to unity and small offset, when oscillations with periods longer than $\approx $ ≈ 13 min were filtered out. The SR method has a great potential due to the simplicity of the instrumentation required. However, care should be taken when measuring under the influence of mesoscale motions, which can lead to high levels of non-stationarity, compromising the fundamental concepts of the SR theory.     

Evaluation of methods of spatial interpolation for monthly rainfall data over the state of Rio de Janeiro,Brazil

Five deterministic methods of spatial interpolation of monthly rainfall were compared over the state of Rio de Janeiro, southeast Brazil. The methods were the inverse distance weight (IDW), nearest neighbor (NRN), triangulation with linear interpolation (TLI), natural neighbor (NN), and spline tension (SPT). A set of 110 weather stations was used to test the methods. The selection of stations had two criteria: time series longer than 20 years and period of data from 1960 to 2009. The methods were evaluated using cross-validation, linear regression between values observed and interpolated, root mean square error (RMSE), coefficient of determination (r ²), coefficient of variation (CV, %), and the Willmott index of agreement (d). The results from different methods are influenced by the meteorological systems and their seasonality, as well as by the interaction with the topography. The methods presented higher precision (r ²) and accuracy (d, RMSE) during the summer and transition to autumn, in comparison with the winter or spring months. The SPT had the highest precision and accuracy in relation to other methods, in addition to having a good representation of the spatial patterns expected for rainfall over the complex terrain of the state and its high spatial variability.     

An analysis of carrier phase differential kinematic GPS positioning using DynaPos

A series of activities have been carried out at the University of New Brunswick in an effort to evaluate advances in long-range marine kinematic differential positioning. These activities involved processing and analysis of GPS carrier phase kinematic data sets. Some of the data was collected by UNB and some was provided by The XYZs of GPS Inc. Data were collected using Trimble 5700 and Ashtech Z-12 receivers. The data sets were processed using the software DynaPos provided by the The XYZs of GPS Inc. The best results obtained in our analysis indicate an agreement of 5 cm RMS for the horizontal component and 12 cm RMS for the vertical component between two ionospheric-delay free solutions, in baselines varying from 40 to 100 km.     

Inertial and hydrodynamic inertial loads on floating units

The analysis of the dynamic behavior of floating units usually employs a coordinate system with origin in the unit's center of gravity, which significantly simplifies the global mass matrix. Hydrodynamic coefficients are then computed considering the same coordinate system. However, to analyze other conditions of mass distribution and maintain the simplicity of a global mass matrix, it is necessary to determine again the hydrodynamic coefficients, thereby reducing the efficiency of the entire process. Another important point is that the geometries frequently used in floating units are such that the cross-terms of an added mass are relatively unimportant when compared with the main terms, and it is, therefore, common to use only some of them to analyze the unit's dynamic behavior. Recently, however, in the search for production systems suitable for water depths greater than 3000 m, other geometries have been considered in technical and economic feasibility studies. It is possible that for these new geometries all terms of the added mass matrix must be included in the analysis. This paper presents the full development used to determine the complete global mass matrix, the inertial and hydrodynamic inertial loads that make use of the added mass matrices considering any coordinate system and the six degrees of freedom, including all cross-terms.     

Study of bi-orthogonal modes in magnetic butterflies

We present a bi-orthogonal decomposition of the temporal and latitudinal distribution of solar magnetic fields from synoptic magnetograms. Results are compared with a similar decomposition of the distribution of sunspots since 1874. We show that the butterfly diagrams can be interpreted as the result of approximately constant amplitudes and phases of two oscillations with periods close to 22 years. A clear periodicity of 7 years can also be identified in the most energetic modes of both spatio-temporal series. These results can be used to obtain relevant information concerning the physics of the solar dynamo.     

Laboratory studies on the sputtering contribution to the sodium atmospheres of Mercury and the Moon

To ascertain the importance of sputtering by solar wind ions on the formation of a sodium exosphere around Mercury and the Moon, we have irradiated with 4 keV He ions, the Na bearing tectosilicates: albite, labradorite, and anorthoclase, as well as adsorbed Na layers deposited on albite and on olivine (a neosilicate that does not contain Na). Sodium at the surface and near surface (<40 Å) was quantified with X-ray photoelectron spectroscopy before and after each irradiation to determine the depletion cross section. We measured a cross section for sputtering of Na adsorbed on mineral surfaces, σ_s ≈ 1 × 10^?15 cm² atom^?1. In addition, mass spectrometric analyses of the sputtered flux show that a large fraction of the Na is sputtered as ions rather than as neutral atoms. These results have strong implications for modeling the sodium population within the mercurian and the lunar exospheres.