Composition and origin of organic matter in surface sediments of Lake Sarbsko: A highly eutrophic and shallow coastal lake (northern Poland)

We present an organic geochemical study of surface sediments of Lake Sarbsko, a shallow coastal lake on the middle Polish Baltic coast. The aim was to provide evidence concerning the origin of the organic matter (OM) and its compositional diversity in surface deposits of this very productive, highly dynamic water body. The content and composition of the OM in the bottom sediments were investigated at 11 sampling stations throughout the lake basin. OM sources were assigned on the basis of bulk indicators [total organic carbon (TOC), total nitrogen (TN), δ¹³C_TOC and δ¹⁵N and extractable OM yield], biomarker composition of extractable OM and compound-specific C isotope signatures. The source characterization of autochthonous compounds was verified via phytoplankton analysis. The distribution of gaseous hydrocarbons in the sediments, as well as temporal changes in lake water pH, the concentration of DIC (dissolved inorganic carbon) and δ¹³C_DIC were used to trace OM decomposition.The sedimentary OM is composed mainly of well preserved phytoplankton compounds and shows minor spatial variability in composition. However, the presence of CH₄ and CO₂ in the bottom deposits provides evidence for microbial degradation of sedimentary OM. The transformation of organic compounds in surface, bottom and pore waters via oxidative processes influences carbonate equilibrium in the lake and seasonally favours precipitation or dissolution of CaCO₃.The data enhance our understanding of the relationships between the composition of sedimentary OM and environmental conditions within coastal ecosystems and shed light on the reliability of OM proxies for environmental reconstruction of coastal lakes.     

Multi‐Criteria Analysis for Optimization of Sodium Chromate Production from Chromic Waste

The proposal of application of multi‐criteria analysis and technological quality method for optimization of technological processes on the case study of sodium chromate production variants from waste was presented. The research on the use of chromic waste for the production of sodium chromate made it possible to determine the optimal process parameters. Technological quality method was used to define the value of criterions for multi‐criteria analysis while multi‐criteria analysis allowed determining the impact of criterions weights for ranking variants of technological process. Both methods in a complex way evaluate the degree of modernization of technologies, describing them qualitatively within the area of environmental, technical, and the economic effects of the proposed technological variants. Based on the proposed evaluating criteria both methods yield comparable results. The most advantageous alternatives provided realization of the sodium chromate production process with the use of in‐process recycling of chromic mud, off‐site recycling of chromic tannery waste and on‐site recycling of waste from the old chromic heaps.     

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

Characteristics of airborne bacteria and fungi in some Polish wastewater treatment plants

The aim of this study was to characterize both the viable airborne bacteria and fungi collected in different types of wastewater treatment plants in Poland. Bacterial and fungal aerosols in five different wastewater treatment plants in Poland were studied, including the pioneering antibiotic resistance testing of airborne bacteria. Concentration level was measured using the six-stage Andersen impactor. After incubation, bioaerosol particles captured on nutrient media on Petri dishes were quantitatively evaluated and qualitatively identified. It was found that the concentration levels of both airborne bacteria and fungi ranged from 10² to 10³ colony-forming units/m³, in all stages of the wastewater treatment plants. The patterns of size distributions of airborne bacteria and fungi were very similar, showing dominant peaks typically in the size range between 3.3 and 4.7 μm. The majority fraction of small bacterial and fungal particles (less than 4.7 μm) in the studied areas indicates that the bioaerosol is relatively fresh, and mostly of local origin. The Gram-positive cocci and nonsporing Gram-positive rods were the dominating forms in the studied wastewater treatment plants environment. The existing differences in the concentration levels between sampling sites enabled identification of the main bioaerosol sources. The highest concentration of bacterial aerosol appeared in sections, where activated sludge post-processing and mechanical purifying are conducted. The most frequently occurring species in the sampled bacterial aerosol were Gram-positive cocci and nonsporing Gram-positive rods. Multi-antibiotic resistance testing showed that among the isolated airborne bacteria, the most antibiotic-resistant features were present among Bacillus species (especially Bacillus mycoides).     

An approach to adaptation to climate changes in Poland

Adopted by COP 10 (Dec 1/CP.10) and approved by the MOP1, the Buenos Aires programme of adaptation and response measures opens doors to intensify preparations for expected climate change. By this decision the COP, requested the SBSTA to develop a structured 5-year programme of work of the SBSTA on the scientific, technical and socio-economic aspects of impacts of, and vulnerability and adaptation to, climate change. Consequently, the COP, by its decision 2/CP.11, adopted the “Five-year programme of work of the Subsidiary Body for Scientific and Technological Advice on impacts, vulnerability and adaptation to climate change” Finally during COP12 this programme was approved as “Nairobi Work Programme on impacts, vulnerability and adaptation to climate change”. This programme has fundamental significance not only for developing countries, but also for industrialized nations in which some sectors of the or social life are particularly vulnerable to climate change, specifically, inter alia EIT countries and new EU Member States. Further development of this adaptation programme economy should contain steps that provide optimum economic and social effectiveness, risk management, identification of vulnerable sectors and gaps in knowledge, preparation of a list of policy options, including an analysis of cost effectiveness, selection of the most effective policies, and a preparedness implementation plan. In Poland the preliminary adaptation programme covered agriculture, water management, and coastal zone management. For the time being, gaps in knowledge and preparedness measures have been identified. An estimation of possible impact on these areas was based on chosen GCMs, and sea level rise IPCC scenarios. In conclusion, it was stated that the results achieved should be seen as a first step forward and a more comprehensive study is necessary to update the results and cover other sectors of the economy, such as health protection, spatial planning, ecosystems and forestry, and to develop specific guidelines and recommendations for policy-makers.     

Deciphering late Devonian–early Carboniferous P–T–t path of mylonitized garnet-mica schists from Prins Karls Forland,Svalbard

Quartz-in-garnet inclusion barometry integrated with trace element thermometry and calculated phase relations is applied to mylonitized schists of the Pinkie unit cropping out on the island of Prins Karls Forland, western part of the Svalbard Archipelago. This approach combines conventional and novel techniques and allows deciphering of the pressure–temperature (P–T) evolution of mylonitic rocks, for which the P–T conditions could not have been easily deciphered using traditional methods. The results obtained suggest that rocks of the Pinkie unit were metamorphosed under amphibolite facies conditions at 8–10 kbar and 560–630°C and mylonitized at ~500 to 550°C and 9–11 kbar. The P–T results are coupled with in-situ Th–U-total Pb monazite dating, which records amphibolite facies metamorphism at c. 359–355 Ma. This is the very first evidence of late Devonian–early Carboniferous metamorphism in Svalbard and it implies that the Ellesmerian Orogeny on Svalbard was associated with metamorphism up to amphibolite facies conditions. Thus, it can be concluded that the Ellesmerian collision between the Franklinian margin of Laurentia and Pearya and Svalbard caused not only commonly accepted brittle deformation and weak greenschist facies metamorphism, but also a burial and deformation of rock complexes at much greater depths at elevated temperatures.     

An Attempt of the Treatment of Underground Water in an Integrated Multifunctional Plant

By means of an integrated multifunctional experimental pilot plant there were tested several process variants for the treatment of carbonic-acid-aggressive and manganese-enriched model water. Deacidification and oxidation of iron- and manganese-constituents are effected by gas exchange with atmospheric oxygen. The hydrated-oxide particles formed are held back by two layers of foamed polyurethane and a sand bed lying uppermost. The process of neutralization and oxidation as well as flocculation is accelerated by the use of chalk, lime or soda. The effectiveness of the process technology investigated is illustrated by a table of results of small-scale experiments with model waters prepared from drinking water.     

Methods of Searching for Planets Around Pulsars

Earth, Moon, and Planets -     

Determination of 3D Trajectories of Knots in Solar Prominences Using MSDP Data

In this paper we present a new method of restoration of the true three-dimensional (3D) trajectories of prominence knots using ground-based observations taken with a single telescope that is equipped with a Multi-Channel Subtractive Double Pass imaging spectrograph. Our method allows us to evaluate the true 3D trajectories of the prominence knots without any assumptions concerning the shape of the trajectories or the dynamics of the motion. The reconstructed trajectories of several knots observed in three prominences are presented.