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1.
This paper outlines the structure of the institutions involved in scientific and technological development in France. It points to new trends in French marine policy, and gives details of the country's offshore petroleum technology and nodule mining. 相似文献
2.
The conditional acid dissociation constants (pKa′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pKa′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln−1):The estimated accuracy of pH measurements using these calculated pKa′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities. 相似文献
3.
A generalized database of global palaeomagnetic data from 3719 lava flows and thin dykes of age 0–5 Ma has been constructed for use with a relational database management system. The database includes all data whose virtual geomagnetic poles (VGP) lie within 45 of the spin axis and can be used for studies of palaeosecular variation and for geomagnetic field modelling. Because many of these data were collected and processed more than 15–20 years ago, each result has been characterized according to the demagnetization procedures carried out. Analysis of these data in terms of the latitude variation of the angular dispersion of VGPs (palaeosecular variation from lavas) strongly suggests that careful data selection is required and that many of the older studies may need to be redone using more modern methods. Differences between the angular dispersions for separate normal- and reverse-polarity data sets confirm that many older studies have not been adequately cleaned magnetically. Therefore, the use of the database for geomagnetic field modelling should be carried out with some caution. Using a VGP cut-off angle that varies with latitude, the best data set consists of 2636 results that show a smooth increase of VGP angular dispersion with latitude. Model G for palaeosecular variation, which is based on modelling of the antisymmetric (dipole) and symmetric (quadrupole) dynamo families, provides a good fit to these results. 相似文献
4.
Alexander N. Gorr Luke A. McGuire Ann M. Youberg Rebecca Beers Tao Liu 《地球表面变化过程与地形》2024,49(2):622-641
Burned slopes are susceptible to runoff-generated debris flows in the years following wildfire due to reductions in vegetation cover and soil infiltration capacity. Debris flows can pose serious threats to downstream communities, so quantifying variations in flow properties along debris-flow runout paths is needed to improve both conceptual and quantitative models of debris-flow behaviour to help anticipate and mitigate the risk associated with these events. Changes in flow properties along the runout paths of the runoff-generated debris flows that follow fire may be particularly dramatic, since they initiate when a water-dominated flow rapidly entrains sediment and later transition back to a water-dominated flow once they reach greater drainage areas and lower slopes. Here, we study the properties of a debris flow that initiated 1 month following the 2022 Pipeline Fire in northern Arizona, USA. We categorized flow type into two classes, granular debris flow and muddy debris flow, along the 7-km runout path and examined how flow properties varied between the phases. Changes in channel gradient and confinement likely facilitated the transition between the flow phases, which were characterized by significant differences in maximum clast size, but similar clay content and fine fractions. We also found that the volume and runout distance of the debris flow were 28 and six times greater, respectively, than that of a debris flow that initiated in the same watershed following a fire 12 years earlier. We attribute these differences to the combined effects of two high-severity fires, suggesting that consideration of recent fire history could improve post-fire debris-flow hazard assessments. Results of this study provide quantitative constraints on changes in post-fire debris-flow properties along a runout path. Data collected in this study add to a small number of debris-flow inundation datasets that can be used to test runout models in post-fire settings. 相似文献
5.
Significance of shallow core transects for reef models and sea‐level curves,Heron Reef,Great Barrier Reef
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Gregory E. Webb Luke D. Nothdurft Jian‐Xin Zhao Bradley Opdyke Gilbert Price 《Sedimentology》2016,63(6):1396-1424
A sequence of shallow reef cores from Heron Reef, Great Barrier Reef, provides new insights into Holocene reef growth models. Isochron analysis of a leeward core transect suggests that the north‐western end of Heron Reef reached current sea‐level by ca 6·5 kyr bp and then prograded leeward at a rate of ca 19·6 m/kyr between 5·1 kyr and 4·1 kyr bp (pre‐1950) to the present reef margin. A single short core on the opposing margin of the reef is consistent with greater and more recent progradation there. Further to the east, one windward core reached modern sea‐level by ca 6·3 kyr bp , suggesting near ‘keep‐up’ behaviour at that location, but the opposing leeward margin behind the lagoon reached sea‐level much more recently. Hence, Heron Reef exhibited significantly different reef growth behaviour on different parts of the same margin. Mean reef accretion rates calculated from within 20 m of one another in the leeward core transect varied between ca 2·9 m and 4·7 m/kyr depending on relative position in the prograding wedge. These cores serve as a warning regarding the use of isolated cores to inform reef growth rates because apparent aggradation at any given location on a reef varies depending on its location relative to a prograding margin. Only transects of closely spaced cores can document reef behaviour adequately so as to inform reef growth models and sea‐level curves. The cores also emphasize potential problems in U‐series dates for corals within a shallow (ca 1·5 m) zone beneath the reef flat. Apparent age inversions restricted to that active diagenetic zone may reflect remobilization and concentration of Th in irregularly distributed microbialites or biofilms that were missed during sample vetting. Importantly, the Th‐containing contaminant causes ages to appear too old, rather than too young, as would be expected from younger cement. 相似文献
6.
Luke Daly Phil A. Bland Svetlana Tessalina David W. Saxey Steven M. Reddy Denis Fougerouse William D.A. Rickard Lucy V. Forman Alexandre La Fontaine Julie M. Cairney Simon P. Ringer Bruce F. Schaefer Daniel Schwander 《Geostandards and Geoanalytical Research》2018,42(3):279-299
Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm3). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS 187Os/189Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM 187Os/189Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles. 相似文献
7.
Studies of the pedogenic iron oxyhydroxides in suites of latest Holocene to middle Pleistocene soils formed on fluvial deposits of the transverse ranges, southern California, indicate that the content and composition of iron oxyhydroxide change in a systematic manner. Analysis of total secondary free iron oxides (dithionite extractable, Fe2O3d) and ferrihydrite (oxalate extractable, Fe2O3o) shows that (1) a single-logarithmic model (Y = a + b log X) or double logarithmic model (log Y = a + b log X), where Y is the total mass of pedogenic Fe oxides (g/cm2-soil column) and X is soil age, describes the rate of increase in Fe2O3d with time; (2) the Fe2O3d content correlates linearly with soil reddening and clay content; (3) the ratio, which indicates the degree of Fe oxide crystallinity, is moderately high to very high (0.22–0.58) in middle Holocene to latest Pleistocene soils and progressively decreases to less than 0.10 in older soils; (4) the value of the ratio also appears to be infuenced by climate; and (5) temporal changes in Fe oxide content and mineralogy are accompanied by related, systematic changes in clay mineralogy and organic matter content. These relationships are attributed to a soil environment that must initially favor ferrihydrite precipitation and/or organic matter-Fe complexation. Subsequent transformation to hematite causes increasingly intense reddening and a concomitant decrease in the ratio. The results demonstrate that iron oxide analysis is useful for numerical age studies of noncalcic soils and shows potential as an indicator of paleoclimates. 相似文献
8.
Analyses of cloud condensation nuclei (CCN) number concentrations (cm− 3) measured at the Mace Head Atmospheric Research Station, near Carna, County Galway, Ireland, using a DH Associates Model M1 static thermal diffusion cloud chamber over the period from March 1994 to September 2002 are presented in this work. Air masses are defined as being ‘marine’ if they originate from a wind direction of 180–300° and ‘continental’ air masses are defined as originating from a wind direction of 45–135°. Air masses without such filtering were classified as ‘undefined’ air masses. Air masses were found to be dominated by marine sector air, re-affirming Mace Head as a baseline atmospheric research station. CCN levels for specific air masses at Mace Head were found to be comparable with earlier studies both at Mace Head and elsewhere. Monthly averaged clean marine (wind direction of 180–300° and black carbon absorption coefficient < 1.425 Mm− 1) CCN and marine CCN varied between 15–247 cm− 3 and 54–670 cm− 3, respectively. As expected, significant increases in number concentration were found in continentally sourced CCN over that of marine CCN and were found to follow a log-normal distribution significantly tighter than that of clean marine air masses. No significant trend was found for CCN over the 9-year period. While polluted continental air masses showed a slight increase in CCN concentrations over the winter months, most likely due to increased fuel usage and a lower mixed boundary layer, the dominance of marine sector air arriving at Mace Head, which generally consists of background CCN concentrations, reduced seasonal differences for polluted air. Marine air showed a distinct seasonal pattern, with elevated values occurring over the spring and summer seasons. This is thought to be due to enhanced biogenic aerosol production as a result of phytoplankton bloom activity in the North Atlantic. 相似文献
9.
This paper examines constraints and enabling factors towards ‘integration’ as they are perceived by actors involved in an ongoing strategy development process. The paper examines stakeholder perspectives on current progress in coastal flood risk management in London and the Thames Estuary. The case-study suggests that important steps have been taken towards an integrated and adaptive strategy development process, particularly through the development of informal stakeholder networks. However, constraints in enabling learning within the strategy development process mean that practical pathways of integration in such a large, global-scale city remain challenging to identify and perhaps even more so to implement. 相似文献
10.
From 378 Hubble Space Telescope WFPC2 images obtained between 1996-2004, we have measured the detailed nature of azimuthal brightness variations in Saturn's rings. The extensive geometric coverage, high spatial resolution (), and photometric precision of the UBVRI images have enabled us to determine the dependence of the asymmetry amplitude and longitude of minimum brightness on orbital radius, ring elevation, wavelength, solar phase angle, and solar longitude. We explore a suite of dynamical models of self-gravity wakes for two particle size distributions: a single size and a power law distribution spanning a decade in particle radius. From these N-body simulations, we calculate the resultant wake-driven brightness asymmetry for any given illumination and viewing geometry. The models reproduce many of the observed properties of the asymmetry, including the shape and location of the brightness minimum and the trends with ring elevation and solar longitude. They also account for the “tilt effect” in the A and B rings: the change in mean ring brightness with effective ring opening angle, |Beff|. The predicted asymmetry depends sensitively on dynamical ring particle properties such as the coefficient of restitution and internal mass density, and relatively weakly on photometric parameters such as albedo and scattering phase function. The asymmetry is strongest in the A ring, reaching a maximum amplitude A∼25% near a=128,000 km. Here, the observations are well-matched by an internal particle density near 450 kg m−3 and a narrow particle size distribution. The B ring shows significant asymmetry (∼5%) in regions of relatively low optical depth (τ∼0.7). In the middle and outer B ring, where τ?1, the asymmetry is much weaker (∼1%), and in the C ring, A<0.5%. The asymmetry diminishes near opposition and at shorter wavelengths, where the albedo of the ring particles is lower and multiple-scattering effects are diminished. The asymmetry amplitude varies strongly with ring elevation angle, reaching a peak near |Beff|=10° in the A ring and at |Beff|=15-20° in the B ring. These trends provide an estimate of the thickness of the self-gravity wakes responsible for the asymmetry. Local radial variations in the amplitude of the asymmetry within both the A and B rings are probably caused by regional differences in the particle size distribution. 相似文献