The impact of planning on pedestrian movement: contrasting pedestrian movement models in pre-modern and modern neighborhoods in Israel

Most pedestrian movement volume models were constructed for urban areas that developed on the basis of pre-modern planning. In this paper, we confront neighborhoods that were built upon modern planning doctrines, combining the functional hierarchy of streets with the neighborhood unit concept, with neighborhoods that developed from pre-modem non-hierarchical street-based planning. We use space syntax analysis to investigate how their street network’s structural attributes interact with pedestrian movement distribution. The investigation was conducted in 14 neighborhoods from 4 cities in Israel by examining the correlation of observed pedestrian volume with models using different axial- and segment-based topological, angular, and metric syntactic attributes across different radii (scales). The results indicate that the street network and the distribution of pedestrian movement interact differently in the two neighborhood types. In pre-modern neighborhoods: (i) there is significantly more walking; (ii) the street network’s syntactic attributes tend to be much more consistent in their correlation with pedestrian volume across all scales; (iii) the correlation of pedestrian volume with these attributes and with commerce is relatively high; and (iv) pedestrian movement distribution is more predictable. We relate these differences to the absence of a self-organized circular causality between street network structure, commerce, and movement in modern planned neighborhoods.     

Land–sea carbon and nutrient fluxes and coastal ocean CO2 exchange and acidification: Past,present, and future

Epochs of changing atmospheric CO₂ and seawater CO₂–carbonic acid system chemistry and acidification have occurred during the Phanerozoic at various time scales. On the longer geologic time scale, as sea level rose and fell and continental free board decreased and increased, respectively, the riverine fluxes of Ca, Mg, DIC, and total alkalinity to the coastal ocean varied and helped regulate the C chemistry of seawater, but nevertheless there were major epochs of ocean acidification (OA). On the shorter glacial–interglacial time scale from the Last Glacial Maximum (LGM) to late preindustrial time, riverine fluxes of DIC, total alkalinity, and N and P nutrients increased and along with rising sea level, atmospheric PCO₂ and temperature led, among other changes, to a slightly deceasing pH of coastal and open ocean waters, and to increasing net ecosystem calcification and decreasing net heterotrophy in coastal ocean waters. From late preindustrial time to the present and projected into the 21st century, human activities, such as fossil fuel and land-use emissions of CO₂ to the atmosphere, increasing application of N and P nutrient subsidies and combustion N to the landscape, and sewage discharges of C, N, P have led, and will continue to lead, to significant modifications of coastal ocean waters. The changes include a rapid decline in pH and carbonate saturation state (modern problem of ocean acidification), a shift toward dissolution of carbonate substrates exceeding production, potentially leading to the “demise” of the coral reefs, reversal of the direction of the sea-to-air flux of CO₂ and enhanced biological production and burial of organic C, a small sink of anthropogenic CO₂, accompanied by a continuous trend toward increasing autotrophy in coastal waters.     

Global Nitrogen Cycle: Pre-Anthropocene Mass and Isotope Fluxes and the Effects of Human Perturbations

We present a nitrogen cycle model for pre-industrial times based on an extensive literature database. The model consists of 18 reservoirs in the domains of the atmosphere, land, and ocean. The biotic reservoirs on land and in the ocean (N-fixing plants, non-N-fixing plants, and marine biota) interact with atmospheric N₂ and dissolved inorganic nitrogen (DIN, consisting of N₂, NO₃ ^?, and NH₄ ⁺) in the ocean and soil waters. Marine DIN is taken up by marine biota and transformed from ocean particulate organic matter to dissolved organic nitrogen and the ocean sediment. The atmosphere, the largest nitrogen reservoir, supplies N₂ to the system by N fixation, deposition, and dissolution, and these input fluxes are balanced by denitrification and volatilization back to the atmosphere. The land and ocean domains are linked by river transport, which carries both dissolved and particulate nitrogen to the oceanic coastal zone. The isotope–mass balances of the N reservoirs are calculated from the isotopic composition of the reservoirs and the fractionation factors accompanying the fluxes between the reservoirs based on reported values from different natural conditions. The model sensitivity was tested for different biouptake rates and was run with various human perturbations, including fertilization, nitrous oxide emissions, population-related sewage disposal, land-use changes, and temperature-dependent rate kinetics. The new N mass–isotope cycle model provides the basis for assessment of the impact of artificial fertilization between 1700 and 2050. The perturbation experiments in this study suggest that land-use change is the key factor altering the N mass cycle since industrialization.     

Rates of dissolution of aluminosilicates in seawater

Dissolution of eight clay minerals, four zeolites, and quartz in seawater has been monitored for81/2 years. For most of the minerals, dissolution can be described as a first-order reaction in which dissolved silica approaches from undersaturation steady concentration values with time. Characteristic reaction rate constants (k₁) are of the order of 10^?7 sec^?1. One of the zeolites, clinoptilolite, shows a different dissolution behavior: SiO₂ concentration in solution reaches a high value within one year, followed by a decline to a lower value, suggestive of precipitation of another silicate phase (possibly sepiolite).A mathematical solution is given for a kinetic equation combining the parabolic-rate and first-order rate processes. It is shown that in a wide range of silicate dissolution reactions taking place over long periods of time, the presence of the parabolic-rate dissolution processes cannot be detected, thereby making its inclusion in the kinetic equations unnecessary. The experimental rates of dissolution are comparable to the SiO₂^? dissolution rates in oceanic sediments near the sediment/water interface. But deeper in the sediment, the calculated dissolution rates are significantly lower than the near-interface and experimental values.     

Century-scale nitrogen and phosphorus controls of the carbon cycle

In recent decades, humans have become a very important force in the Earth system, demonstrating that emissions (gaseous, liquid, and solid) are the cause of many of our environmental issues. These emissions are responsible for major global reorganizations of the biogeochemical cycles. The oceans are now a net sink of atmospheric CO₂, whereas in their preindustrial state they were a source; the trophic state of the coastal oceans is progressively moving toward increased heterotrophy; and the terrestrial realm is now vacillating between trophic states, whereas in preindustrial times it was autotrophic. In this paper, we present model calculations that underscore the role of human-induced perturbations in changing Earth's climate, specifically the role of anthropogenic nitrogen and phosphorus in controlling processes in the global carbon cycle since the year 1850 with projections to the year 2035. Our studies show that since the late 1940's emissions of nitrogen and phosphorus have been sequestered in the terrestrial living phytomass and groundwater. This nutrient-enhanced fertilization of terrestrial biota, coupled with rising atmospheric CO₂ and global temperature, has induced a sink of anthropogenic CO₂ that roughly balances the emission of CO₂ owing to land use change. In the year 2000, for example, the model-calculated terrestrial biotic sink was 1730 Mtons C/year, while the emission of CO₂ from changes in land use was 1820 Mtons C/year, a net flux of 90 Mtons C/year emitted to the atmosphere. In the global aquatic environment, enhanced terrestrial inputs of biotically reactive phosphorus (about 8.5 Mtons P/year) and inorganic nitrogen (about 54 Mtons N/year), have induced increased new production and burial of organic carbon in marine sediments, which is a small sink of anthropogenic CO₂. It is predicted that the response of the global land reservoirs of C, N, and P to sustained anthropogenic perturbations will be maintained in the same direction of change over the range of projected scenarios of global population increase and temperature change for the next 35 years. The magnitude of change is significantly larger when the global temperature increase is maximum, especially with respect to the processes of remobilization of the biotically important nutrients nitrogen and phosphorus.     

The THESEUS space mission: science goals,requirements and mission concept

Experimental Astronomy - THESEUS, one of the two space mission concepts being studied by ESA as candidates for next M5 mission within its Comsic Vision programme, aims at fully exploiting Gamma-Ray...     

Human perturbations on the global biogeochemical cycles of coupled Si–C and responses of terrestrial processes and the coastal ocean

We present a model of the global biogeochemical cycle of silicon (Si) that emphasizes its linkages to the carbon cycle and temperature. The Si cycle is a crucial part of global nutrient biogeochemistry regulating long-term atmospheric CO₂ concentrations due to silicate mineral weathering reactions involving the uptake of atmospheric CO₂ and production of riverine dissolved silica, cations and bicarbonate. In addition and importantly, the Si cycle is strongly coupled to the other nutrient cycles of N, P, and Fe; hence siliceous organisms represent a significant fraction of global primary productivity and biomass. Human perturbations involving land-use changes, burning of fossil fuel, and inorganic N and P fertilization have greatly altered the terrestrial Si cycle, changing the river discharge of Si and consequently impacting marine primary productivity primarily in coastal ocean waters.