Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Ultra-Deep Optical Spectroscopy with PMAS. Using the Nod-and-Shuffle Technique

PMAS, the Potsdam Multi-Aperture Spectrophotometer, is a new integral field spectrograph in the optical, which is optimized for good transmission and high image quality from 350 nm to 1 μm. We present our plan to implement a CCD charge-shuffle mode to allow for beam switching with a very high degree of sky subtraction accuracy for faint object 3-D spectroscopy. This revised version was published online in July 2006 with corrections to the Cover Date.     

Deformation styles as a key for interpreting glacial depositional environments

Lithostratigraphical and lithofacies approaches used to interpret glacial sediments often ignore deformation structures that can provide the key to environment of formation. We propose a classification of deformation styles based on the geometry of structures rather than inferred environment of formation. Five styles are recognised: pure shear (P), simple shear (S), compressional (C), vertical (V) and undeformed (U). These dictate the first letter of the codes; the remaining letters conveying the evidence. This information can be used to reconstruct palaeostress fields and to infer physical properties of sediments when they deformed. Individual structures are not diagnostic of particular environments but the suite of structures, their relative scale, stratigraphical relationships, and orientation relative to palaeoslopes and to palaeoice‐flow directions can be used to infer the environment in which they formed. This scheme is applied at five sites in west Wales. The typical succession is interpreted as subglacial sediments overlain by meltout tills, flow tills and sediment flows. Paraglacial redistribution of glacial sediments is widespread. Large‐scale compressional deformation is restricted to sites where glaciers readvanced. Large‐scale vertical deformation occurs where water was locally ponded near the ice margin. There is no evidence for glaciomarine conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

Flare stars and solar bursts: High resolution in time and frequency

Coronal loops on the Sun and nearby stars are investigated using observations at 20 cm wavelength with high resolution in time and frequency. Observations of the dwarf M star AD Leonis with high time resolution using the Arecibo Observatory have resulted in the discovery of a quasi-periodic train of circularly polarized spikes with a mean periodicity of 32 ± 5 ms and a total duration of 150 ms. The individual spikes had rise times of 5 ms, leading to an upper limit to the linear size L 1.5 × 10⁸ cm for the spike emitter. This size is only 0.005 of the estimated radius of AD Leonis. Provided that the emitter is symmetric, it has a brightness temperature of T _B 10¹⁶ K, suggesting a coherent burst mechanism such as an electron-cyclotron maser. Coronal oscillations might modulate the maser output, producing the quasi-periodic spikes. Observations at closely spaced wavelengths, or high frequency resolution, using the Very Large Array have revealed narrow-band structure (v/v 0.01) in solar bursts and in the slowly-varying radiation of the dwarf M star YZ Canis Minoris. The narrow-band emission cannot be explained by continuum emission processes, but it might be attributed to electron-cyclotron maser radiation. Maser action at the second or first harmonic of the gyrofrequency implies magnetic field strengths of 250 and 500 G, respectively. Thus, observations with high resolution in time and frequency suggest coherent processes in the coronae of the Sun and dwarf M stars. The scientific potential of these discoveries may be best fulfilled by the construction of a solar-stellar synthesis radiotelescope.Proceedings of the Workshop on Radio Continua during Solar flares, held at Duino (Trieste), Italy, 27–31 May, 1985.     

高效液相色谱-等离子体质谱技术在溴元素形态分析中的应用

溴是一种在自然水体中都含有的元素,通常以B r-的形式存在。目前最常用的水净化方式就是向水中通入臭氧以杀灭细菌;而臭氧分解的副产物即为B r-转换成的B rO3-,这是一种公认的致癌物质。本实验室曾使用阴离子交换高效液相色谱(HPLC)与等离子体质谱(ICP-MS)联用分析B rO3-和B r-,方法虽能有效地将这两种溴形态分离,但分析每个样品需8 m in。本文试图建立新的方法缩短分析时间,并验证该方法应用于实际水样分析时测定其他含溴化合物的能力。1实验部分1.1高效液相色谱分析条件表1列出了等度淋洗和梯度淋洗两种模式下HPLC的分析条件,完成形态的分离。等度淋洗和梯度淋洗在分析中显示出不同     

Evaluation of approaches to calculate debris-flow parameters for hazard assessment

Many different runout prediction methods can be applied to estimate the mobility of future debris flows during hazard assessment. The present article reviews the empirical, analytical, simple flow routing and numerical techniques. All these techniques were applied to back-calculate a debris flow, which occurred in 1982 at La Guingueta catchment, in the Eastern Pyrenees. A sensitivity analysis of input parameters was carried out, while special attention was paid to the influence of rheological parameters. We used the Voellmy fluid rheology for our analytical and numerical modelling, since this flow resistance law coincided best with field observations. The simulation results indicated that the “basal” friction coefficients rather affect the runout distance, while the “turbulence” terms mainly influence flow velocity. A comparison of the velocity computed on the fan showed that the analytical model calculated values similar to the numerical ones. The values of our rheological parameters calibrated at La Guingueta agree with data back-calculated for other debris flows. Empirical relationships represent another method to estimate total runout distance. The results confirmed that they contain an important uncertainty and they are strictly valid only for the conditions, which were the basis for their development. With regards to the simple flow routing algorithm, this methods could satisfactorily simulate the total area affected by the 1982 debris flow, but it was not able to directly calculate total runout distance and velocity. Finally, a suggestion on how different runout prediction methods can be applied to generate debris-flow hazard maps is presented. Taking into account the definition of hazard and intensity, the best choice would be to divide the resulting hazard maps into two types: “final hazard maps” and “preliminary hazard maps”. Only the use of numerical models provided final hazard maps, because they could incorporate different event magnitudes and they supplied output-values for intensity calculation. In contrast, empirical relationships and flow routing algorithms, or a combination of both, could be applied to create preliminary hazard maps. The present study only focussed on runout prediction methods. Other necessary tasks to complete the hazard assessment can be looked up in the “Guidelines for landslide susceptibility, hazard and risk zoning” included in this Special Issue.     

Phytoreduction and volatilization of mercury by ascorbate in Arabidopsis thaliana, European beech and Norway spruce

Mercury vapor (Hg⁰) emission from plants contributes to the atmospheric Hg cycle. Young barley (Hordeum vulgare L.) plants grown on a hydroponic cultivation medium containing Hg(II) have previously been shown to increase their Hg⁰ emission significantly by reduction of Hg(II) with endogenous ascorbic acid. Regarding the potential contribution to the Hg cycle from the vast forest-covered areas, it was important to investigate this mechanism in trees. The increase in Hg⁰ emission from young European beech plants cultivated on a HgCl₂ medium exceeded that from controls by ca. tenfold and was proportional to the Hg(II) concentration. From these experiments, a flux of 12.8 μg Hg⁰/h/m² was estimated at an exposure of the roots to 20 μM Hg(II). Mercury vapor release from homogenates of Norway spruce needles exceeded that from European beech leaves by a factor of 2.3–4, i.e. in proportion to the reported AA concentrations; the reduction was maximal at alkaline pH which is typical for AA. The 8.4-fold difference in Hg⁰ release between homogenates from wild-type Arabidopsis thaliana and from its AA-deficient mutant vtc 1-1 also paralleled the reported difference in AA levels of both species. It is concluded that the phytoreduction and vaporization of Hg by AA is an important mechanism as much for Hg detoxification in trees as for Hg emission to the atmosphere. The efficiency of this process seems to result from the optimal coordination of transfer and biochemical transformation of mercuric ions and Hg vapor. There is no evidence for a relevant difference in the mechanisms of biogenic Hg(II) reduction between grass plants and trees.