Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.     

Rapid ground deformation corresponding to a mining-induced seismic event followed by a massive collapse

Natural Hazards - On 17 April 2015, the Wujek/?l?sk underground coal mine in Poland was struck by a strong induced tremor of magnitude M4.0. The event was followed by a massive rock burst...     

Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.     

Socioenvironmental issues of river bed material extraction in the Himalayan piedmont (India)

The present study focuses on the Balason river running through the Himalayan piedmont zone (near Siliguri, India). The objective of the study is an assessment of the environmental effects of river bed material extraction by humans and the dependence of indigenous people on the river and its ecosystem services. The analysis is based on results of field work consisting of geodetic measurements of the river channel and interviews among the local community from the Nimtijot village. Historical hydrological data were also used for the study. The results of the investigation show that the Balason river is heavily affected by excessive exploitation of river bed material during dry season and the replenishment of extracted material in a monsoon season is not always sufficient. It leads to channel deepening. The local community working in the river heavily depends for its livelihood on continuing this activity. A decreasing amount of bed material to be extracted may lead to degradation of the strong relationship between the local community and their natural environment (river).     

A mixing-length model for predicting vertical velocity distribution in flows through emergent vegetation

Abstract

The vertical profiles of streamwise velocities are computed on flood plains vegetated with trees. The calculations were made based on a newly developed one-dimensional model, taking into account the relevant forces acting on the volumetric element surrounding the considered vegetation elements. A modified mixing length concept was used in the model. An important by-product of the model is the method for evaluating the friction velocities, and consequently bed shear stresses, in a vegetated channel. The model results were compared with the relevant experimental results obtained in a laboratory flume in which flood plains were covered by simulated vegetation.     

Galactic Dynamo and Spiral Arms - 3D MHD Simulations

In the present project we investigate the evolution of a three-dimensional (3D), large-scale galactic magnetic field under the influence of gas flows in spiral arms and in the presence of dynamo action. Our principal goal is to check how the dynamical evolution of gaseous spiral arms affects the global magnetic field structure and to what extent our models could explain the observed spiral patterns of polarization B-vectors in nearby galaxies. A two-step scheme is used: the N-body simulations of a two-component, self-gravitating disk provide the time-dependent velocity fields which are then used as the input to solve the mean-field dynamo equations. We found that the magnetic field is directly influenced by large-scale non-axisymmetric density wave flows yielding the magnetic field locally well-aligned with gaseous spiral arms in a manner similar to that discussed already by Otmianowska-Mazur et al. 1997. However, an additional field amplification, introduced by a non-zero -term in the dynamo equations, is required to cause a systematic increase of magnetic energy density against the diffusive losses. Our simulated magnetic fields are also used to construct the models of a high-frequency (Faraday rotation-free) polarized radio emission accounting for effects of projection and limited resolution, thus suitable for direct comparisons with observations.     

Pure cross-anisotropy for geotechnical elastic potentials

The pure cross-anisotropy is understood as a special scaling of strain (or stress). The scaled tensor is used as an argument in the elastic stiffness (or compliance). Such anisotropy can be overlaid on the top of any elastic stiffness, in particular on one obtained from an elastic potential with its own stress-induced anisotropy. This superposition does not violate the Second Law. The method can be also applied to other functions like plastic potentials or yield surfaces, wherever some cross-anisotropy is desired. The pure cross-anisotropy is described by the sedimentation vector and at most two constants. Scaling with more than two purely anisotropic constants is shown impossible. The formulation was compared with experiments and alternative approaches. Static and dynamic calibration of the pure anisotropy is also discussed. Graphic representation of stiffness with the popular response envelopes requires some enhancement for anisotropy. Several examples are presented. All derivations and examples were accomplished using the algebra program Mathematica.