The Monahans chondrite and halite: Argon‐39/argon‐40 age,solar gases,cosmic‐ray exposure ages,and parent body regolith neutron flux and thickness

Abstract— The Monahans H‐chondrite is a regolith breccia containing light and dark phases and the first reported presence of small grains of halite. We made detailed noble gas analyses of each of these phases. The ³⁹Ar‐⁴⁰Ar age of Monahans light is 4.533 ± 0.006 Ma. Monahans dark and halite samples show greater amounts of diffusive loss of ⁴⁰Ar and the maximum ages are 4.50 and 4.33 Ga, respectively. Monahans dark phase contains significant concentrations of He, Ne and Ar implanted by the solar wind when this material was extant in a parent body regolith. Monahans light contains no solar gases. From the cosmogenic ³He, ²¹Ne, and ³⁸Ar in Monahans light we calculate a probable cosmic‐ray, space exposure age of 6.0 ± 0.5 Ma. Monahans dark contains twice as much cosmogenic ²¹Ne and ³⁸Ar as does the light and indicates early near‐surface exposure of 13–18 Ma in a H‐chondrite regolith. The existence of fragile halite grains in H‐chondrites suggests that this regolith irradiation occurred very early. Large concentrations of ³⁶Ar in the halite were produced during regolith exposure by neutron capture on ³⁵Cl, followed by decay to ³⁶Ar. The thermal neutron fluence seen by the halite was (2–4) × 10¹⁴ n/cm². The thermal neutron flux during regolith exposure was ～0.4‐0.7 n/cm²/s. The Monahans neutron fluence is more than an order of magnitude less than that acquired during space exposure of several large meteorites and of lunar soils, but the neutron flux is lower by a factor of ≤5. Comparison of the ³⁶Ar_n/²¹Ne_cos ratio in Monahans halite and silicate with the theoretically calculated ratio as a function of shielding depth in an H‐chondrite regolith suggests that irradiation of Monahans dark occurred under low shielding in a regolith that may have been relatively shallow. Late addition of halite to the regolith can be ruled out. However, irradiation of halite and silicate for different times at different depths in an extensive regolith cannot be excluded.     

The expansive nondecelerative universe

(a) Hubble's discovery of the expansion of the Universe makes it possible to choose unambiguously from the models described by Friedmann's equations of universe dynamics. (b) From the present temperature of the cosmic microwave background radiation, the specific entropy in the matter era and the model properties of the expansive nondecelerative universe, we can determine the present parameters of our Universe with deviations smaller than 2.2%.     

A note on the problem of choosing a model of the Universe,IV

The Friedmannian model of the Universe with ultra-relativistic equation of statep=–1/3 withk=0 is nondecelerative, i.e., it expands with the constant velocityv=c during the whole expanding phase of evolution of the Universe. The ultrastable nondecelerative model is the only model of the Universe which fulfills all conditions resulting from the quantum-mechanical and relativistic analysis of the Universe.     

Interpretation of a special fine structure in type-IV solar radio bursts

A special fine structure (slowly drifting chains of narrowband fiber bursts), firstly observed during the solar type-IV radio burst on April 24, 1985, is interpreted as the radio signature of whistler waves periodically excited by a switch-on/switch-off process of a loss-cone instability in a localized wave packet of the fast magnetoacoustic mode.     

Paleogeothermal gradient in the boskovice furrow

Summary A coalification data set from the first seam of the Rosice-Oslavany coal district in the Boskovice furrow was used to estimate the temperature gradient prevailing within the furrow during Autunian sedimentation. An appreciable scatter of the data reflects the complicated history of the sedimentary region. The northern part of the district displays a higher degree of coalification. The results of the evaluation suggest that the region ceased to subside in the upper Autunian, and that the extent of the post-Autunian erosion does not exceed 500 metres. This version of the burial history, which is consistent with geological data, yields a temperature paleogradient of 76 mK/m for the northern part and of 72 mK/m for the southern part of the district. The gradients estimated are higher than those prevailing during the Carboniferous sedimentation in the Central Bohemian Basin (45 – 53 mK/m), lower than values found for the Ostrava Formation in the Upper Silesian Basin during its Namurian A sedimentation (about 95 mK/m), but comparable with values evaluated for the Karviná Formation of the same basin deposited during the Namurian B - C and Westphalian A (60 – 77 mK/m).Dedicated to the Memory of Professor Karel P     

Sunspot indices characterizing the 11-year cycle as a whole and their relationship to the analogous indices of geomagnetic activity

Summary Sunspot indices characterizing the 11-year cycle as a whole were determined on the basis of Wolf's sunspot numbers and their total area as well as on the basis of the primary physically indices of the spot-generating activity of the Sun.Their interrelationship is shown and their relationship to the indices of geomagnetic activity aa and C_i is examined. It is shown that under high solar activity a certain saturation of the Earth's magnetosphere occurs and that the variations of geomagnetic activity correlate with the variations of the global sunspot indices (Wolf number and total area) but correlate but slightly with the primary physically sunspot indices.

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Semi-analytical solutions of a contaminant transport equation with nonlinear sorption in 1D

A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed).     

Stable Cu and Zn isotope ratios as tracers of sources and transport of Cu and Zn in contaminated soil

Copper and Zn metals are produced in large quantities for different applications. During Cu production, large amounts of Cu and Zn can be released to the environment. Therefore, the surroundings of Cu smelters are frequently metal-polluted. We determined Cu and Zn concentrations and Cu and Zn stable isotope ratios (δ⁶⁵Cu, δ⁶⁶Zn) in three soils at distances of 1.1, 3.8, and 5.3 km from a Slovak Cu smelter and in smelter wastes (slag, sludge, ash) to trace sources and transport of Cu and Zn in soils. Stable isotope ratios were measured by multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) in total digests. Soils were heavily contaminated with concentrations up to 8087 μg g⁻¹ Cu and 2084 μg g⁻¹ Zn in the organic horizons. The δ⁶⁵Cu values varied little (−0.12‰ to 0.36‰) in soils and most wastes and therefore no source identification was possible. In soils, Cu became isotopically lighter with increasing depth down to 0.4 m, likely because of equilibrium reactions between dissolved and adsorbed Cu species during transport of smelter-derived Cu through the soil. The δ⁶⁶Zn_IRMM values were isotopically lighter in ash (−0.41‰) and organic horizons (−0.85‰ to −0.47‰) than in bedrock (−0.28‰) and slag (0.18‰) likely mainly because of kinetic fractionation during evaporation and thus allowed for separation of smelter-Zn from native Zn in soil. In particular in the organic horizons large variations in δ⁶⁶Zn values occur, probably caused by biogeochemical fractionation in the soil-plant system. In the mineral horizons, Zn isotopes showed only minor shifts to heavier δ⁶⁶Zn values with depth mainly because of the mixing of smelter-derived Zn and native Zn in the soils. In contrast to Cu, Zn isotope fractionation between dissolved and adsorbed species was probably only a minor driver in producing the observed variations in δ⁶⁶Zn values. Our results demonstrate that metal stable isotope ratios may serve as tracer of sources, vertical dislocation, and biogeochemical behavior in contaminated soil.