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1.
Pyruvate kinase (PK) activity measurements are used to assess the role of carbohydrates in global feeding of mesozooplankton communities inhabiting an estuary plume. As a consequence of a remarkably low freshwater discharge rate, the sea surface layers of the area under estuarine influence showed a very moderate salinity fall and a nearly total depletion in nitrates, whereas higher levels of these nutrients were found in deeper, more saline, layers. Small-scale PK activity variations in mesozooplankton appear to be closely correlated to nitrate integration values within the water column. The results were analysed in comparison with literature reports. The study produced a coherent overall interpretation, which strongly supports the reliability of this new biochemical tool in detecting assimilation of trace carbohydrates in the diet of mesozooplankton.  相似文献   
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In order to assess in fish the maternal transfer of alkylphenolic compounds to the progeny, the identification and quantification of the labelled compounds present in oocytes and embryos was conducted after dietary exposure of mature female mosquitofish to 14C-4n-nonylphenol during vitellogenesis and embryogenesis respectively. Radioactivity found in bile and liver extracts accounted for 0.9-0.6 and 0.2-0.1% of ingested radioactivity for females exposed during vitellogenesis and embryogenesis respectively. The amount of extractable radioactivity present in oocytes and embryos was 0.19 and 0.07% of the ingested dose respectively. The radio-HPLC profiles obtained from bile, liver, oocyte and embryo extracts were similar. They showed the presence of 4n-NP-glucuronide as the major metabolite and traces of unchanged 4n-NP. The other metabolites corresponded to 8-hydroxynonylphenol, 9-(4-hydroxyphenyl)-nonanoic acid and para-hydroxybenzoic acid which is the final product of the alkyl chain oxidation. Our results indicate that exposure of ovoviviparous female fish to 4-NP during vitellogenesis and embryogenesis leads to the contamination of the progeny by 4-NP and its metabolites.  相似文献   
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This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.  相似文献   
5.
We present a general stratigraphic synthesis for the Upper Rhine Graben (URG) and the Swiss Molasse Basin (SMB) from Eocene to Pliocene times. The stratigraphic data were compiled both from literature and from research carried out by the authors during the past 6 years ; an index of the stratigraphically most important localitites is provided. We distinguish 14 geographical areas from the Helvetic domain in the South to the Hanau Basin in the North. For each geographical area, we give a synthesis of the biostratigraphy, lithofacies, and chronostratigraphic ranges. The relationships between this stratigraphic record and the global sea-level changes are generally disturbed by the geodynamic (e.g., subsidence) evolution of the basins. However, global sea-level changes probably affected the dynamic of transgression–regression in the URG (e.g., Middle Pechelbronn Beds and Serie Grise corresponding with sea-level rise between Ru1/Ru2 and Ru2/Ru3 sequences, respectively) as well as in the Molasse basin (regression of the UMM corresponding with the sea-level drop at the Ch1 sequence). The URGENT-project (Upper Rhine Graben evolution and neotectonics) provided an unique opportunity to carry out and present this synthesis. Discussions with scientists addressing sedimentology, tectonics, geophysics and geochemistry permitted the comparison of the sedimentary history and stratigraphy of the basin with processes controlling its geodynamic evolution. Data presented here back up the palaeogeographic reconstructions presented in a companion paper by the same authors (see Berger et al. in Int J Earth Sci 2005).  相似文献   
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This paper presents data concerning the energy budget in the surface layer in the Sahel region (a semi-desert area). The results are drawn from a measurement campaign made in the Niamey region in the Niger, in April–May 1984 (the Yantala Campaign). The sensible heat flux is computed with the profile method, the ground heat flux is deduced from measurement of the temperature field, and the radiative net flux is measured directly with a balancemeter. The latent heat flux, which is deduced from the energy budget balance is very weak and within the accuracy limit of the method. The diurnal variation of the net flux is symmetrical, with a maximum at noon. On the other hand, the sensible heat flux variation is asymmetrical, with an afternoon decrease much slower than the morning increase. After 3.30 pm, it becomes higher than the net flux. This is compensated for by the sign change of the ground heat flux, whose maximum is found in the morning at 11 am. The second part of this paper shows the importance of one term in the surface-layer energy budget: the long-wave radiative divergence between the ground and the top of the surface layer in high superadiabatic conditions. We show, with a radiative model on the one hand and direct measurement of the radiative divergence on the other hand, that this term reaches several tens of W m-2 in the superadiabatic conditions found in the Sahel region.   相似文献   
8.
Incoherent scatter radars are designed to detect scatter from thermalfluctuations in the ionosphere. These fluctuations contain, among other things,features associated with ion-acoustic waves driven by random motions within theplasma. The resulting spectra are generally broad and noisy, but neverthelessthe technique can, through a detailed analysis of spectra, be used to measure arange of physical parameters in the Earth's upper atmosphere, and provides apowerful diagnostic in studies of magnetosphere-ionosphere coupling,thermosphere dynamics and the geospace environment in general. In recent yearsthere has been much interest in naturally occurring (as opposed to artificiallystimulated) enhanced ion-acoustic spectra seen in the auroral zone andcusp/cleft region. A study of the plasma instability processes that lead tosuch spectra will help us to better understand auroral particle acceleration,wave-particle and wave-wave interactions in the ionosphere, and theirassociation with magnetospheric processes. There is now a substantial body ofliterature documenting observations of enhanced ion-acoustic spectra, but thereremains controversy over generation mechanisms. We present a review ofliterature documenting observations of naturally enhanced ion-acoustic spectra,observed mainly along the geomagnetic field direction, along with a discussionof the theories put forward to explain such phenomena.  相似文献   
9.
Large organic falls to the benthic environment, such as dead wood or whale bones, harbour organisms relying on sulfide-oxidizing symbionts. Nothing is known however, concerning sulfide enrichment at the wood surface and its relation to wood colonization by sulfide-oxidizing symbiotic organisms.In this study we combined in situ hydrogen sulfide and pH measurements on sunken wood, with associated fauna microscopy analyses in a tropical mangrove swamp. This shallow environment is known to harbour thiotrophic symbioses and is also abundantly supplied with sunken wood. A significant sulfide enrichment at the wood surface was revealed. A 72 h sequence of measurements emphasized the wide fluctuation of sulfide levels (0.1–>100 μM) over time with both a tidal influence and rapid fluctuations. Protozoans observed on the wood surface were similar to Zoothamnium niveum and to vorticellids. Our SEM observations revealed their association with ectosymbiotic bacteria, which are likely to be sulfide-oxidizers. These results support the idea that sunken wood surfaces constitute an environment suitable for sulfide-oxidizing symbioses.  相似文献   
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