Surfactants enhanced recovery of endosulfan from contaminated soils

Soil pollution due to hydrophobic organic compounds is a wide environmental problem. Extensive use of endosulfan in cotton and paddy to meet the needs of the growing population has led to contamination of soil and other ecosystems. Endosulfan is hydrophobic, highly toxic to aquatic and human population and persists in soil for more than a year. To overcome the problem of hydrophobicity and limited availability, surfactants play a major role in soil remediation. In the present study, the potential of non-ionic synthetic surfactants (Tween 80, Triton X-100) and biosurfactant (Surfactin produced by Bacillus subtilis) for enhancing the release of endosulfan from contaminated agricultural soils was evaluated using the batch method. Incorporation of the surfactant concentrations at above Criticle Miceller Concentration (0.5, 1 and 2 g/L) into soil enhances the release of endosulfan. Surfactin produced from Bacillus subtilis recorded maximum (91.5%) recovery. The observed order of recovery being surfactin > Tween 80 > Triton X-100. The result suggest that surfactants could help in the remediation of soils polluted by pesticides.     

Gravity anomalies,flexure, and deformation of the converging Indian lithosphere in Nepal and Sikkim–Darjeeling Himalayas

Researchers ubiquitously noted that the common processes of partitioning oblique convergence in response to drag from the trench-hanging plate simultaneously produce radial slips, along-strike translation, and extension parallel to the deformation front. Here, we focus on the area between Nepal and Sikkim–Darjeeling Himalayas, and carry out gravity and finite-element stress modeling of the strike-orthogonal converging Indian lithosphere. We delineate the geometries of different layers and their interfaces through gravity modeling. The optimum model parameters along with rheological parameters of different layers are used for finite-element modeling. Finite-element modeling is done with boundary conditions of keeping the upper surface free and rigidly fixing the section of the northern boundary below the Main Himalayan Thrust. We impart on its frontal section an amount of 6 × 10¹² N/m force, equivalent to resistive force of the Himalayan–Tibet system, and analyze the maximum and minimum compressive stress fields evolved in the lithosphere. We testify our observations with earthquake database and other geophysical and geological studies. We note that an increasing flexing of the Indian lithosphere beyond the Main Boundary Thrust becomes maxima between the Main Central Thrust and South Tibetan Detachment in both the areas; however, more steepening of the Moho boundary is identified in the Sikkim–Darjeeling Himalaya. This abrupt change in lithospheric geometry beneath the Greater Himalaya is likely correlated with the sharp elevation changes in the topography. Although the highest seismicity concentration is dominant in this zone, the Lesser and the Tethys Himalayas in Sikkim–Darjeeling area also record relatively fair seismic activity. More compressive stress field in different layers right within the sharp bending zone supports this observation. We thus propose that the sharp bending zone beneath the Greater Himalaya is suffering maximum deformation, and the deformation is continued in the mantle too. We also identify both right-lateral shear and radial vergence slip, which are presumably associated with the general dynamics and kinematics of the Himalaya.     

Sea Surface Height Variability in the Indian Ocean from TOPEX/POSEIDON Altimetry and Model Simulations

Sea Surface Height (SSH) variability in the Indian Ocean during 1993-1995 is studied using TOPEX/POSEIDON (T/P) altimetry data. Strong interannual variability is seen in the surface circulation of the western Arabian Sea, especially in the Somali eddy structure. During the Southwest (SW) monsoon, a weak monsoon year is characterized by a single eddy system off Somalia, a strong or normal monsoon year by several energetic eddies. The Laccadive High (LH) and Laccadive Low (LL) systems off southwest India are observed in the altimetric SSH record. The variability of the East India Coastal Current (EICC), the western boundary current in the Bay of Bengal, is also detected. Evidence is found for the propagation of Kelvin and Rossby waves across the northern Indian Ocean; these are examined in the context of energy transfer to the western boundary currents, and associated eddies. A simple wind-driven isopycnal model having three active layers is implemented to simulate the seasonal changes of surface and subsurface circulation in the North Indian Ocean and to examine the response to different wind forcing. The wind forcing is derived from the ERS-1 scatterometer wind stress for the same period as the T/P altimeter data, enabling the model response in different (active/weak) monsoon conditions to be tested. The model output is derived in 10-day snapshots to match the time period of the T/P altimeter cycles. Complex Principal Component Analysis (CPCA) is applied to both altimetric and model SSH data. This confirms that long Rossby waves are excited by the remotely forced Kelvin waves off the southwest coast of India and contribute substantially to the variability of the seasonal circulation in the Arabian Sea.     

Sea Surface Height Variability in the Indian Ocean from TOPEX/POSEIDON Altimetry and Model Simulations

Sea Surface Height (SSH) variability in the Indian Ocean during 1993-1995 is studied using TOPEX/POSEIDON (T/P) altimetry data. Strong interannual variability is seen in the surface circulation of the western Arabian Sea, especially in the Somali eddy structure. During the Southwest (SW) monsoon, a weak monsoon year is characterized by a single eddy system off Somalia, a strong or normal monsoon year by several energetic eddies. The Laccadive High (LH) and Laccadive Low (LL) systems off southwest India are observed in the altimetric SSH record. The variability of the East India Coastal Current (EICC), the western boundary current in the Bay of Bengal, is also detected. Evidence is found for the propagation of Kelvin and Rossby waves across the northern Indian Ocean; these are examined in the context of energy transfer to the western boundary currents, and associated eddies. A simple wind-driven isopycnal model having three active layers is implemented to simulate the seasonal changes of surface and subsurface circulation in the North Indian Ocean and to examine the response to different wind forcing. The wind forcing is derived from the ERS-1 scatterometer wind stress for the same period as the T/P altimeter data, enabling the model response in different (active/weak) monsoon conditions to be tested. The model output is derived in 10-day snapshots to match the time period of the T/P altimeter cycles. Complex Principal Component Analysis (CPCA) is applied to both altimetric and model SSH data. This confirms that long Rossby waves are excited by the remotely forced Kelvin waves off the southwest coast of India and contribute substantially to the variability of the seasonal circulation in the Arabian Sea.     

Large Area X-Ray Proportional Counter (LAXPC) Instrument on AstroSat and Some Preliminary Results from its Performance in the Orbit

Large area X-ray propositional counter (LAXPC) instrument on AstroSat is aimed at providing high time resolution X-ray observations in 3–80 keV energy band with moderate energy resolution. To achieve large collecting area, a cluster of three co-aligned identical LAXPC detectors, is used to realize an effective area in access of \({\sim }6000\,\hbox {cm}^{2}\) at 15 keV. The large detection volume of the LAXPC detectors, filled with xenon gas at \({\sim }\)2 atmosphere pressure, results in detection efficiency greater than 50%, above 30 keV. In this article, we present salient features of the LAXPC detectors, their testing and characterization in the laboratory prior to launch and calibration in the orbit. Some preliminary results on timing and spectral characteristics of a few X-ray binaries and other type of sources, are briefly discussed to demonstrate that the LAXPC instrument is performing as planned in the orbit.     

Air-sea Coupling During the Tropical Cyclones in the Indian Ocean: A Case Study Using Satellite Observations

In the years 1999 and 2001, three intense tropical cyclones formed over the northern Indian Ocean—two over the Bay of Bengal during 15–19 and 25–29 October, 1999 and one over the Arabian Sea during 21–28 May, 2001. We examined the thermal, salinity and circulation responses at the sea surface due to these severe cyclones in order to understand the air-sea coupling using data from satellite measurements and model simulations. It is found that the Sea Surface Temperature (SST) cooled by about 0.5 °–0.8 °C in the Bay of Bengal and 2 °C in the Arabian Sea. In the Bay of Bengal, this cooling took place beneath the cyclone center whereas in the Arabian Sea, the cooling occurred behind the cyclone only a few days later. This contrasting oceanic response resulted mainly from the salinity stratification in the Bay of Bengal and thermal stratification in the Arabian Sea and the associated mixing processes. In particular, the cyclones moved over the region of low salinity and smaller mixed layer depth with a distinct mixed layer deepening to the left side of the cyclone track. It is envisaged that daily satellite estimates of SST and Sea Surface Salinity (SSS) using Outgoing Longwave Radiation (OLR) and model simulated mixed layer depth would be useful for the study of tropical cyclones and prediction of their path over the northern Indian Ocean.     

Long-term seismic observations along Myanmar–Sunda subduction margin: insights for 2004 Mw > 9.0 earthquake

International Journal of Earth Sciences - The present study investigates the temporal variation of few seismic parameters between the Myanmar (Zone I), Andaman–Nicobar–Northwest Sumatra...     

Quantification of atmospheric oxygen levels during the Paleoproterozoic using paleosol compositions and iron oxidation kinetics

The increase in atmospheric oxygen during the Precambrian is a key to understand the co-evolution of life and environment and has remained as a debatable topic. Among various proxies for the estimation of atmospheric oxygen levels, paleosols, ancient weathering profiles, can provide a quantitative pattern of atmospheric oxygen increase during the Precambrian period of Earth history. We have re-evaluated the chemical compositions of paleosols, and presented a new method of applying Fe²⁺ oxidation kinetics to the Fe²⁺ and Fe³⁺ concentrations in paleosols to decipher the quantitative partial pressure of atmospheric oxygen (P_O2) between 2.5 and 2.0 Ga. We first estimated the compaction factor (CF, the fraction of original thickness) using the immobile elements such as Ti, Al and Zr on equal volume basis, which was then used to calculate retention fractions (M_R), a mass ratio of paleosol to parent rock, of redox-sensitive elements. The CF and Fe_R values were evaluated for factors such as homogeneity of immobile elements, erosion, and formation time of weathering. Fe_R increased gradually within the time window of ∼2.5-2.1 Ga and remained close to 1.0 since ∼2.1 Ga onwards. Mn_R also increased gradually similar to Fe_R but at a slower rate and near complete retention was observed ∼1.85 Ga, suggesting an almost continuous increase in the oxidation of Fe²⁺ and Mn²⁺ in paleosols ranging in age between ∼2.5 and 1.9 Ga.We have modeled P_O2 variations during the Paleoproterozoic by applying Fe²⁺ oxidation kinetics to the Fe²⁺ and Fe³⁺ concentrations in paleosols, which enabled us to derive an Fe²⁺ oxidation term referred to as ψ. Possible changes in temperature and P_CO2 during this time window and their effects on resulting models of P_O2 evolution have been also considered. We assumed four cases for the calculations of P_O2 variations between 2.5 and 2.0 Ga: no change in either temperature or P_CO2, long-term change in only P_CO2, long-term changes in both temperature and P_CO2, and short-term fluctuations of both temperature and P_CO2 during the possible, multiple global-scale glaciations. The calculations indicate that P_O2 increased gradually, linearly on the logarithmic scale, from <∼10⁻⁶ to >∼10⁻³ atm between 2.5 and 2.0 Ga. Our calculations show that the P_O2 levels would have fluctuated significantly, if intense, global glaciation(s) followed by period(s) of high temperature occurred during the Paleoproterozoic. This gradual rise model proposes a distinct, quantitative pattern for the first atmospheric oxygen rise with important implications for the evolution of life.     

Effect of tween 80 added to the soil on the degradation of endosulfan by Pseudomonas aeruginosa

Endosulfan, a chlorinated cyclodiene insecticide is of environmental concern because of its apparent persistence and toxicity to many non target organisms. Endosulfan is hydrophobic and persists in soil for more than a year. To overcome the problem of hydrophobic and limited availability, surfactants play a major role in soil remediation. In the present study, the effect of Tween 80 added to the soil on the degradation of endosulfan by Pseudomonas aeruginosa at different pH (7.0 and 8.5) was studied. The addition of synthetic surfactant Tween 80 enhanced the solubility and degradation of endosulfan. A significant degradation (94%) was observed in pH 8.5 and Tween 80 added soil; the bacterial population in the treatment unit T8 was 75 × 10⁹ CFU/g of soil. The unit T4 inoculated at pH 8.5 showed 86 % alpha and 60 % beta endosulfan degradation, the bacterial population was 73 × 10⁸ CFU / g of soil. The degradation of both the isomers were observed and accompanied with formation of endodiol and endosulfan sulfate.     

A new cache of Eoarchaean detrital zircons from the Singhbhum craton,eastern India and constraints on early Earth geodynamics

The dominant geodynamic processes that underpin the formation and evolution of Earth’s early crust remain enigmatic calling for new information from less studied ancient cratonic nuclei.Here,we present U-Pb ages and Hf isotopic compositions of detrital zircon grains from^2.9 Ga old quartzites and magmatic zircon from a 3.505 Ga old dacite from the Iron Ore Group of the Singhbhum craton,eastern India.The detrital zircon grains range in age between 3.95 Ga and 2.91 Ga.Together with the recently reported Hadean,Eoarchean xenocrystic(up to 4.24 Ga)and modem detritus zircon grains from the Singhbhum craton,our results suggest that the Eoarchean detrital zircons represent crust generated by recycling of Hadean felsic crust formed at^4.3-4.2 Ga and^3.95 Ga.We observe a prominent shift in Hf isotope compositions at^3.6-3.5 Ga towards super-chondritic values,which signify an increased role for depleted mantle and the relevance of plate tectonics.The Paleo-,Mesoarchean zircon Hf isotopic record in the craton indicates crust generation involving the role of both depleted and enriched mantle sources.We infer a short-lived suprasubduction setting around^3.6-3.5 Ga followed by mantle plume activity during the Paleo-,Mesoarchean crust formation in the Singhbhum craton.The Singhbhum craton provides an additional repository for Earth’s oldest materials.