Iron oxidation state in the Fe‐rich layer and silica matrix of Libyan Desert Glass: A high‐resolution XANES study

Abstract— Libyan Desert Glass (LDG) is an enigmatic type of glass that occurs in western Egypt in the Libyan Desert. Fairly convincing evidence exists to show that it formed by impact, although the source crater is currently unknown. Some rare samples present dark‐colored streaks with variable amounts of Fe, and they are supposed to contain a meteoritic component. We have studied the iron local environment in an LDG sample by means of Fe K‐edge highresolution X‐ray absorption near edge structure (XANES) spectroscopy to obtain quantitative data on the Fe oxidation state and coordination number in both the Fe‐poor matrix and Fe‐rich layers. The pre‐edge peak of the high‐resolution XANES spectra of the sample studied displays small but reproducible variations between Fe‐poor matrix and Fe‐rich layers, which is indicative of significant changes in the Fe oxidation state and coordination number. Comparison with previously obtained data for a very low‐Fe sample shows that, while iron is virtually all trivalent and in tetrahedral coordination (^[4]Fe³⁺) in the low‐Fe sample, the sample containing the Fe‐rich layers display a mixture of tetra‐coordinated trivalent iron (^[4]Fe³⁺) and penta‐coordinated divalent iron (^[5]Fe²⁺), with the Fe in the Fe‐rich layer being more reduced than the matrix. From these data, we conclude the following: a) the significant differences in the Fe oxidation state between LDG and tektites, together with the wide intra‐sample variations in the Fe‐oxidation state, confirm that LDG is an impact glass and not a tektite‐like glass; b) the higher Fe content, coupled with the more reduced state of the Fe, in the Fe‐rich layers suggests that some or most of the Fe in these layers may be directly derived from the meteoritic projectile and that it is not of terrestrial origin.     

Geomagnetic Effects of Corotating Interaction Regions

We present an analysis of the geoeffectiveness of corotating interaction regions (CIRs), employing the data recorded from 25 January to 5 May 2005 and throughout 2008. These two intervals in the declining phase of Solar Cycle 23 are characterised by a particularly low number of interplanetary coronal mass ejections (ICMEs). We study in detail how four geomagnetic-activity parameters (the Dst, Ap, and AE indices, as well as the Dst time derivative, \(\mathrm{dDst}/\mathrm{d}t\)) are related to three CIR-related solar wind parameters (flow speed, \(V\), magnetic field, \(B\), and the convective electric field based on the southward Geocentric solar magnetospheric (GSM) magnetic field component, \(\mathit{VB}_{s}\)) on a three-hour time resolution. In addition, we quantify statistical relationships between the mentioned geomagnetic indices. It is found that Dst is correlated best to \(V\), with a correlation coefficient of \(\mathrm{cc}\approx0.6\), whereas there is no correlation between \(\mathrm{dDst}/\mathrm{d}t\) and \(V\). The Ap and AE indices attain peaks about half a day before the maximum of \(V\), with correlation coefficients ranging from \(\mathrm{cc}\approx0.6\) to \(\mathrm{cc}\approx0.7\), depending on the sample used. The best correlations of Ap and AE are found with \(\mathit{VB}_{s}\) with a delay of 3 h, being characterised by \(\mathrm{cc}\gtrsim 0.6\). The Dst derivative \(\mathrm{dDst}/\mathrm{d}t\) is also correlated with \(\mathit{VB}_{s}\), but the correlation is significantly weaker \(\mathrm{cc}\approx 0.4\)?–?0.5, with a delay of 0?–?3 h, depending on the employed sample. Such low values of correlation coefficients indicate that there are other significant effects that influence the relationship between the considered parameters. The correlation of all studied geomagnetic parameters with \(B\) are characterised by considerably lower correlation coefficients, ranging from \(\mathrm{cc}=0.3\) in the case of \(\mathrm{dDst}/\mathrm{d}t\) up to \(\mathrm{cc}=0.56\) in the case of Ap. It is also shown that peak values of geomagnetic indices depend on the duration of the CIR-related structures. The Dst is closely correlated with Ap and AE (\(\mathrm{cc}=0.7\)), Dst being delayed for about 3 h. On the other hand, \(\mathrm{dDst}/\mathrm{d}t\) peaks simultaneously with Ap and AE, with correlation coefficients of 0.48 and 0.56, respectively. The highest correlation (\(\mathrm{cc}=0.81\)) is found for the relationship between Ap and AE.     

Vertical distribution of dust particles in the Earth's atmosphere during the 1998 Leonids

Abstract— Photometric observations of the twilight sky were carried out during Leonids 1998. The obtained vertical distributions of aerosol between 20 and 140 km demonstrate the processes of the intrusion of fine meteor dust and its subsequent intra-atmospheric dynamics. The characteristic radii of two fractions of the meteor dust particles were estimated by their sedimentation velocities. They varied within r_p = 0.006–0.06 μm and r_p = 19–81 μm limits depending on an assumed particle density within ρ_p = 0.4–4.0 g cm^?3. The assumption of ρ_p = 2.0 g cm^?3 gave radii of the two fractions to be 0.01 and 30 μm, respectively.     

Evolution of Solar and Geomagnetic Activity Indices, and Their Relationship: 1960?�C?2001

We employ annually averaged solar and geomagnetic activity indices for the period 1960??C?2001 to analyze the relationship between different measures of solar activity as well as the relationship between solar activity and various aspects of geomagnetic activity. In particular, to quantify the solar activity we use the sunspot number R _s, group sunspot number R _g, cumulative sunspot area Cum, solar radio flux F10.7, and interplanetary magnetic field strength IMF. For the geomagnetic activity we employ global indices Ap, Dst and Dcx, as well as the regional geomagnetic index RES, specifically estimated for the European region. In the paper we present the relative evolution of these indices and quantify the correlations between them. Variations have been found in: i) time lag between the solar and geomagnetic indices; ii) relative amplitude of the geomagnetic and solar activity peaks; iii) dual-peak distribution in some of solar and geomagnetic indices. The behavior of geomagnetic indices is correlated the best with IMF variations. Interestingly, among geomagnetic indices, RES shows the highest degree of correlation with solar indices.     

Estimation of the normal geomagnetic field and geological interpretation of the normal field anomalies over middle-northern Croatia

Based on the ground survey of total-field magnetic data at 53 sites, which recorded a time-series over the interval 2003–2005, the core field + long wavelength lithospheric field over the middle-northern Croatia region was calculated. The area of the survey was 18900 km², an average distance between the neighbouring sites being 12 km. The results were reduced to 2004.5 epoch. This “normal” total-field was estimated using the firstorder Taylor polynomial as a function of geographic coordinates, and the polynomial coefficients were calculated with three methods of adjustment: simple and weighted least squares fits and adjustment according to the most frequent value. The stability of the normal field was tested using the Monte Carlo-type test, by decreasing the input data set in each adjustment (up to 90%). All obtained field residuals (measured-“normal”) were mutually compared, as well as fit coefficients of the Taylor polynomials. The residual values indicate the presence of shorter-wavelength anomalies, specifically three major residual anomalies were found (−106 nT, 74 nT and 57 nT). The geostatistical analysis of the ground survey data and the normal field residuals (respectively), using the median absolute deviation method, was further conducted in order to evaluate the calculated anomalies. The geological situation around the anomalies derived by the median absolute deviation method, and around the normal field residual anomalies, is given. The correlation was found between higher value anomalies of the normal field residuals, and shallow volcanic rocks and oil field, respectively.     

On the solar rotation and activity

The interaction between differential rotation and magnetic fields in the solar convection zone was recently modelled by Brun (2004). One consequence of that model is that the Maxwell stresses can oppose the Reynolds stresses, and thus contribute to the transport of the angular momentum towards the solar poles, leading to a reduced differential rotation. So, when magnetic fields are weaker, a more pronounced differential rotation can be expected, yielding a higher rotation velocity at low latitudes taken on the average. This hypothesis is consistent with the behaviour of the solar rotation during the Maunder minimum. In this work we search for similar signatures of the relationship between the solar activity and rotation determined tracing sunspot groups and coronal bright points. We use the extended Greenwich data set (1878–1981) and a series of full-disc solar images taken at 28.4 nm with the EIT instrument on the SOHO spacecraft (1998–2000). We investigate the dependence of the solar rotation on the solar activity (described by the relative sunspot number) and the interplanetary magnetic field (calculated from the interdiurnal variability index). Possible rotational signatures of two weak solar activity cycles at the beginning of the 20th century (Gleissberg minimum) are discussed. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Simulation and modeling of rainfall radar measurements for hydrological applications

A procedure is described for the simulation of rainfall radar reflectivity (absolute and differential) measurements by dual linear polarization meteorological radars. The basic requirement that the proposed procedure aims at satisfying is that radar data obtained at the end of the process be correlated in a physically plausible manner to the rainfall field at ground, the latter being generated by means of a stochastic space-time rainfall model. The main goal of the model is to give the possibility to easily check the accuracy of radar rainfall estimates derived by means of procedures and algorithms aimed at minimizing or compensating for the effects of measurement errors associated with several types of meteorological events, with particular reference to requirements of hydrogeological forecast systems. Within the limits imposed by the validity of the adopted model, an analysis was carried out indicating general criteria that may be adopted to achieve a better accuracy in rainfall estimates and a full exploitation of the advantages offered by the radar dual polarization measurement technique.     

Spatial Distribution and North–South Asymmetry of Coronal Bright Points from Mid-1998 to Mid-1999

Full-disc full-resolution (FDFR) solar images obtained with the Extreme Ultraviolet Imaging Telescope (EIT) on board the Solar and Heliospheric Observatory (SOHO) were used to analyse the centre-to-limb function and latitudinal distribution of coronal bright points. The results obtained with the interactive and the automatic method, as well as for three subtypes of coronal bright points for the time period 4 June 1998 to 22 May 1999 are presented and compared. An indication of a two-component latitudinal distribution of coronal bright points was found. The central latitude of coronal bright points traced with the interactive method lies between 10^∘ and 20^∘. This is closer to the equator than the average latitude of sunspots in the same period. Possible implications for the interpretation of the solar differential rotation are discussed. In the appendix, possible differences between the two solar hemispheres are analysed. More coronal bright points were present in the southern solar hemisphere than in the northern one. This asymmetry is statistically significant for the interactive method and not for the automatic method. The visibility function is symmetrical around the central meridian.     

Determination of the Croatian geomagnetic observatory location

Ground survey within the Nature Park Lonjsko Polje, placed in the middle-northern Croatia was performed during the time interval 2007–2010 in order to find the best location for installing the geomagnetic observatory. The total magnetic field has been measured a few times using the Overhauser proton magnetometers. The horizontal and vertical gradients of the total field, and its temporal behaviour were investigated over the restricted region that we estimated as suitable for the observatory. The results obtained from thoroughly conducted measurements allowed us to find definitive positions for the instrument pillars. These results are in agreement with previously suggested location found based on combination of Comprehensive CM4 model prediction and measurements conducted from 2003 to 2005. This study contributes to the development of geomagnetism in Croatia and paves a way to install the first geomagnetic observatory in Croatia.