The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.     

Deep-water sediment transport patterns and basin floor topography in early rift basins: Plio-Pleistocene syn-rift of the Corinth Rift,Greece

Our current understanding on sedimentary deep-water environments is mainly built of information obtained from tectonic settings such as passive margins and foreland basins. More observations from extensional settings are particularly needed in order to better constrain the role of active tectonics in controlling sediment pathways, depositional style and stratigraphic stacking patterns. This study focuses on the evolution of a Plio-Pleistocene deep-water sedimentary system (Rethi-Dendro Formation) and its relation to structural activity in the Amphithea fault block in the Corinth Rift, Greece. The Corinth Rift is an active extensional basin in the early stages of rift evolution, providing perfect opportunities for the study of early deep-water syn-rift deposits that are usually eroded from the rift shoulders due to erosion in mature basins like the Red Sea, North Sea and the Atlantic rifted margin. The depocentre is located at the exit of a structurally controlled sediment fairway, approximately 15 km from its main sediment source and 12 km basinwards from the basin margin coastline. Fieldwork, augmented by digital outcrop techniques (LiDAR and photogrammetry) and clast-count compositional analysis allowed identification of 16 stratigraphic units that are grouped into six types of depositional elements: A—mudstone-dominated sheets, B—conglomerate-dominated lobes, C—conglomerate channel belts and sandstone sheets, D—sandstone channel belts, E—sandstone-dominated broad shallow lobes, F—sandstone-dominated sheets with broad shallow channels. The formation represents an axial system sourced by a hinterland-fed Mavro delta, with minor contributions from a transverse system of conglomerate-dominated lobes sourced from intrabasinal highs. The results of clast compositional analysis enable precise attribution for the different sediment sources to the deep-water system and their link to other stratigraphic units in the area. Structures in the Amphithea fault block played a major role in controlling the location and orientation of sedimentary systems by modifying basin-floor gradients due to a combination of hangingwall tilt, displacement of faults internal to the depocentre and folding on top of blind growing faults. Fault activity also promoted large-scale subaqueous landslides and eventual uplift of the whole fault block.     

Model studies of the influence of O2 photodissociation parameterizations in the Schumann-Runge bands on ozone related photolysis in the upper atmosphere

A new parameterization for atmospheric transmission and O₂ photodissociation in the Schumann-Runge band region has been developed and tested with a 1D radiative-photochemical model. The parameterization is based on the O₂-column along the line of sight to the Sun and the local temperature. Line-by-line calculations have served as a benchmark for testing this method and several other, commonly used, parameterizations. The comparisons suggest that differences between the line-by-line calculations and currently accepted parameterizations can be reduced significantly by using the new method, particularly at large solar zenith angles. The production rate of O-atoms computed with this method shows less than 6% deviation compared to the line-by-line calculations at any altitude, all solar zenith angles and in all seasons. The largest errors are found toward the shorter wavelengths in the Schumann-Runge region at low altitudes. Transmittance is approximated to better than 4% at any altitude and/or solar zenith angle. The total O-production rate above 20 km is approximated to better than 2%. The new parameterization is easily implemented in existing photochemical models and in many cases it may simply replace the existing algorithm. The computational effort exceeds that of other parameterizations but in view of the total computation time needed for the actual calculation of the parameterized Schumann-Runge bands this should not lead to significant performance degeneration. The first 14 coefficients of the parameterization are included in this study. Both the complete sets of coefficients and a simple algorithm can be obtained by contacting the authors. A photochemical model study shows the largest effect of the parameterization method is on odd hydrogen concentrations. Subsequent interaction with an odd oxygen family causes differences in the ozone concentrations between the different parameterizations of more than 10% at selected altitudes. Although it is already established that deficiencies in the treatment of Schumann-Runge band absorption are unlikely to explain the current underestimation of ozone concentration at the stratopause in a variety of photochemical models, this study does show that the choice of parameterization has a large impact on the accuracy of the results at large solar zenith angles and in different seasons.     

Use of incipient motion data for backward erosion piping models

Backward erosion piping involves the gradual removal of granular material under the action of water flow from the foundation of a dam or levee, whereby shallow pipes are formed that grow in the direction opposite to the flow. This pipe-forming process can ultimately lead to failure of a water-retaining structure and is considered one of the most important failure mechanisms for dikes and levees in the Netherlands and the United States. Modeling of this mechanism requires the assessment of hydraulic conditions in the pipe, which are controlled by the particle equilibrium at the pipe wall. Since the pipe's dimensions are controlled by the inflow to the pipe from the porous medium, the flow through the pipe is thought to be laminar for fine- to medium-grained sands. The literature provides data for incipient motion in laminar flow, which is reviewed here and complemented with data from backward erosion experiments. The experiments illustrate the applicability of the laminar incipient motion data to determine the erosion pipe dimensions and corresponding pipe hydraulics for fine- to medium-grained sands, for the purpose of backward erosion piping modeling.     

Calibration of Parameter Fields Consisting of Multiple Statistical Populations

If a parameter field to be calibrated consists of more than one statistical population, usually not only the parameter values are uncertain, but the spatial distributions of the populations are uncertain as well. In this study, we demonstrate the potential of the multimodal calibration method we proposed recently for the calibration of such fields, as applied to real-world ground water models with several additional stochastic parameter fields. Our method enables the calibration of the spatial distribution of the statistical populations, as well as their spatially correlated parameterization, while honoring the complete prior geostatistical definition of the multimodal parameter field. We illustrate the implications of the method in terms of the reliability of the posterior model by comparing its performance to that of a "conventional" calibration approach in which the positions of the statistical populations are not allowed to change. Information from synthetic calibration runs is used to show how ignoring the uncertainty involved in the positions of the statistical populations not only denies the modeler the opportunity to use the measurement information to improve these positions but also unduly influences the posterior intrapopulation distributions, causes unjustified adjustments to the cocalibrated parameter fields, and results in poorer observation reproduction. The proposed multimodal calibration allows a more complete treatment of the relevant uncertainties, which prevents the abovementioned adverse effects and renders a more trustworthy posterior model.     

Sorption and anaerobic biodegradation of soluble aromatic compounds during groundwater transport. 2. Computer modeling

. The natural attenuation of a binary mixture of toluene and 1,2,4-trimethylbenzene, which was previously experimentally demonstrated in anaerobic column experiments, was simulated with the newly-developed PHREEQC model to reveal the biogeochemical processes involved. The processes considered in this model include advection, diffusion, sorption, redox reactions (e.g., oxidation of toluene and 1,2,4-trimethylbenzene coupled to the reduction of microbial ferric iron), precipitation of secondary minerals such as siderite and magnetite, and dissolution of hydrous ferric oxides, as well as other thermodynamic equilibrium reactions. The functions of advection and diffusion built into the PHREEQC were conventionally simulated. The sorption was kinetically simulated based on a bicontinuum model, whereas biodegradation was described using a multiple-term Monod model. The processes mentioned above were coupled with a geochemical equilibrium model. The consistency between the experimental and modeling results indicates that the processes defined and the controlling parameters chosen could describe the coupled interactions between transport and biogeochemical reactions for the studied system. The discrepancy between modeling and experimental observations, however, also revealed the limitation of the modeling approach. In general, the model approach, which incorporates simplified mathematical representations of the true physico-chemical dynamics of the sorption and biodegradation processes of toluene and 1,2,4-trimethylbenzene under anaerobic conditions is a very efficient and good predictive tool in management and remediation of contaminant groundwater aquifers.     

The Kilo-Degree Survey

The Kilo Degree Survey (KiDS) is a 1500 square degree optical imaging survey with the recently commissioned OmegaCAM wide-field imager on the VLT Survey Telescope (VST). A suite of data products will be delivered to the European Southern Observatory (ESO) and the community by the KiDS survey team. Spread over Europe, the KiDS team uses Astro-WISE as its main tool to collaborate efficiently and pool hardware resources. In Astro-WISE the team shares, calibrates and archives all survey data. The data-centric architectural design realizes a dynamic ‘live archive’ in which new KiDS survey products of improved quality can be shared with the team and eventually the full astronomical community in a flexible and controllable manner.     

The Astro-WISE optical image pipeline

We have designed and implemented a novel way to process wide-field astronomical data within a distributed environment of hardware resources and humanpower. The system is characterized by integration of archiving, calibration, and post-calibration analysis of data from raw, through intermediate, to final data products. It is a true integration thanks to complete linking of data lineage from the final catalogs back to the raw data. This paper describes the pipeline processing of optical wide-field astronomical data from the WFI (http://www.eso.org/lasilla/instruments/wfi/) and OmegaCAM (http://www.astro-wise.org/~omegacam/) instruments using the Astro-WISE information system (the Astro-WISE Environment or simply AWE). This information system is an environment of hardware resources and humanpower distributed over Europe. AWE is characterized by integration of archiving, data calibration, post-calibration analysis, and archiving of raw, intermediate, and final data products. The true integration enables a complete data processing cycle from the raw data up to the publication of science-ready catalogs. The advantages of this system for very large datasets are in the areas of: survey operations management, quality control, calibration analyses, and massive processing.     

Sedimentation and chronology of heavy metal pollution in Oslo harbor, Norway

Stratigraphic profiles of Cu, Cd and Hg in ten sediment cores from the Oslo harbor, Norway, combined with results of radiometric dating demonstrate that pollution by these metals peaked between 1940 and 1970. Dating results indicate that Hg discharges peaked between 1940 and 1950, Cd reached maximum ca. 1955-1960, and Cu has the highest concentration in sediment interval corresponding to ca. 1970. Geochemical profiles and maxima of Cu, Cd and Hg concentrations can be used as chronostratigraphic markers for sediment cores from the Oslo harbor. Acoustic backscatter and sediment core data indicate that propeller wash affects the seabed in the Oslo harbor. The propeller-induced turbulence causes erosion, and in places exposes and remobilizes contaminated sediments that accumulated in the harbor during previous decades. Such re-exposure of contaminated sediments could be detrimental to local ecosystems and offset remediation efforts, warranting further impact studies and potential mitigation strategies to prevent redistribution.