Comparison of isotope pairing and N2:Ar methods for measuring sediment denitrification—Assumption, modifications, and implications

Denitrification has been measured during the last few years using two different methods in particular: isotope pairing measured on a triple-collector isotopic ratio mass spectrometer and N₂:Ar ratios measured on a membrane inlet mass spectrometer (MIMS). This study compares these two techniques in short-term batch experiments. Rates obtained using the original N₂∶Ar method were up to 3 to 4 times higher than rates obtained using the isotope pairing technique due to O₂ reacting with the N₂ during MIMS analysis. Oxygen combines with N₂ within the mass spectrometer ion source forming NO⁺ which reduces the N₂ concentration. The decrease in N₂ is least at lower O₂ concentrations and since oxygen is typically consumed during incubations of sediment cores, the result is often a pseudo-increase in N₂ concentration being interpreted as denitrification activity. The magnitude of this ocygen effect may be instrument specific. The reaction of O₂ with N₂ and the subsequent decrease in N₂ was only partly correctly using an O₂ correction curve for the relationship between N₂ and O₂ concentrations. The O₂ corrected N₂∶Ar denitrification rates were lower, but still did not match the isotope pairing rates and the variability between replicates was much higher. Using a copper reduction column heated to 600°C to remove all of the O₂ from the sample before MIMS analysis resulted in comparable rates (slightly lower), and comparable variability between replicates, to the isotope pairing technique. The N₂:Ar technique determines the net N₂ production as the difference between N₂ production by denitrification and N₂ consumption by N-fixation, while N-fixation has little effect on the isotope pairing technique which determines a rate very close to the gross N₂ production. When the two different techniques were applied on the same sediment, the small difference in rates obtained by the two methods seemed to reflect N-fixation as also supported from measurements of ethylene production in acetylene enriched sediment cores. The N₂:Ar and isotope pairing techniques may be combined to provide simultaneous measurements of denitrification and N-fixation. Both techniques have several assumptions that must be met to achieve accurate rates; a number of tests are outlined that can be applied to demonstrate that these assumptions are being meet.     

Phase boundaries in finite amplitude mantle convection

Summary. Phase boundaries are included in dynamical finite element models of mantle convection. They are represented by point chains which act as additional sources of buoyancy forces when distorted, and as additional source or sink of heat. The influence of the exothermic olivine-spinel transition is studied in both shallow and deep convection models. The flow is only slightly enhanced by the transition. The increase of temperature due to latent heat release is step-like in the deep model, in the case of shallow convection it is more diffuse. Other quantities like ocean-floor topography, gravity anomalies, and stress distribution are no more than moderately affected. In a further investigation the effect of spinel post-spinel transition, whether endothermic or exothermic, on deep convection is examined. The effect on the flow is negligibly small in both cases.     

Theoretical intensity ratios for some Fe XIII coronal lines

Theoretical values for the relative intensities of the Fe XIII lines 110747, 110798, and 3388 are presented as functions of electron density using recent values of the cross-section for collisionl excitation by protons. Our results are compared with those of Chevalier and Lambert.     

Eruptive history and petrologic evolution of the Albano multiple maar (Alban Hills, Central Italy)

A comprehensive volcanological study of the Albano multiple maar (Alban Hills, Italy) using (i) ⁴⁰Ar/³⁹Ar geochronology of the most complete stratigraphic section and other proximal and distal outcrops and (ii) petrographic observations, phase analyses of major and trace elements, and Sr and O isotopic analyses of the pyroclastic deposits shows that volcanic activity at Albano was strongly discontinuous, with a first eruptive cycle at 69±1 ka producing at least two eruptions, and a second cycle with two peaks at 39±1 and 36±1 ka producing at least four eruptions. Contrary to previous studies, we did not find evidence of magmatic or hydromagmatic eruptions younger than 36±1 ka. The activity of Albano was fed by a new batch of primary magma compositionally different from that of the older activity of the Alban Hills; moreover, the REE and ⁸⁷Sr/⁸⁶Sr data indicate that the Albano magma originated from an enriched metasomatized mantle. According to the modeled liquid line of descent, this magma differentiated under the influence of magma/limestone wall rock interaction. Our detailed eruptive and petrologic reconstruction of the Albano Maar evolution substantiates the dormant state of the Alban Hills Volcanic District. Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan An erratum to this article can be found at     

Paleoclimatic changes in southern Africa during the intensification of Northern Hemisphere glaciation: evidence from ODP Leg 175 Site 1085

Pliocene age sediments from Ocean Drilling Program Leg 175, Site 1085-A and B in the Cape Basin were analyzed to investigate the impact of the intensification of Northern Hemisphere glaciation (INHG) on the South Atlantic Benguela Current system from 4 to 2 Ma. Proxies for productivity (concentrations and mass accumulation rates of total organic carbon, carbon to nitrogen ratios, percent calcium carbonate, and percent biogenic silica) as well as weight percent sand (a proxy for preservation or winnowing) peak at 3.2, 3.0, 2.4, and 2.25 Ma. Normative calculations of allied trace and major elemental determinations indicate synchronous increases in productivity peaks, as well as high concentrations and accumulations of terrigenous sediments. Coeval increases in hemipelagic sedimentation and productivity indicators could be the result of enhanced eolian sedimentation resulting from strengthened winds, leading to elevated rates of upwelling and enhanced productivity. However, rapid burial, as indicated by high sedimentation rates, could also enhance preservation. The very high concentrations (>30%) and accumulations (up to 60 g/cm²/kyr) limit the likelihood that eolian sedimentation was the only transport mechanism, invoking an additional fluvial source. Rapid burial by either eolian or fluvial transport links these intervals of enhanced preservation and productivity with continental climate changes resulting from (1) increased winds and/or dust availability due to higher aridity in the Namibia/northern South Africa region; (2) lowered sea-level related to increased ice volume; (3) increased sediment load due to wetter conditions in the continental interior; or (4) some combination. Peaks at 3.2, 2.4 and 2.25 Ma are coincident with maximum precession, suggesting a link between hemipelagic sedimentation and enhanced monsoonal circulation over southern Africa. The Site 1085 sedimentary record during the INHG seems to be controlled by low-latitude processes linked to precession rather than hig-latitude processes.     

THEMIS-VIS observations of clouds in the martian mesosphere: Altitudes, wind speeds, and decameter-scale morphology

We present measurements of the altitude and eastward velocity component of mesospheric clouds in 35 imaging sequences acquired by the Mars Odyssey (ODY) spacecraft’s Thermal Emission Imaging System visible imaging subsystem (THEMIS-VIS). We measure altitude by using the parallax drift of high-altitude features, and the velocity by exploiting the time delay in the THEMIS-VIS imaging sequence.We observe two distinct classes of mesospheric clouds: equatorial mesospheric clouds observed between 0° and 180° L_s; and northern mid-latitude clouds observed only in twilight in the 200–300° L_s period. The equatorial mesospheric clouds are quite rare in the THEMIS-VIS data set. We have detected them in only five imaging sequences, out of a total of 2048 multi-band equatorial imaging sequences. All five fall between 20° south and 0° latitude, and between 260° and 295° east longitude. The mid-latitude mesospheric clouds are apparently much more common; for these we find 30 examples out of 210 northern winter mid-latitude twilight imaging sequences. The observed mid-latitude clouds are found, with only one exception, in the Acidalia region, but this is quite likely an artifact of the pattern of THEMIS-VIS image targeting. Comparing our THEMIS-VIS images with daily global maps generated from Mars Orbiter Camera Wide Angle (MOC-WA) images, we find some evidence that some mid-latitude mesospheric cloud features correspond to cloud features commonly observed by MOC-WA. Comparing the velocity of our mesospheric clouds with a GCM, we find good agreement for the northern mid-latitude class, but also find that the GCM fails to match the strong easterly winds measured for the equatorial clouds.Applying a simple radiative transfer model to some of the equatorial mesospheric clouds, we find good model fits in two different imaging sequences. By using the observed radiance contrast between cloud and cloud-free regions at multiple visible-band wavelengths, these fits simultaneously constrain the optical depths and particles sizes of the clouds. The particle sizes are constrained primarily by the relative contrasts at the available wavelengths, and are found to be quite different in the two imaging sequences: r_eff = 0.1 μm and r_eff = 1.5 μm. The optical depths (constrained by the absolute contrasts) are substantial: 0.22 and 0.5, respectively. These optical depths imply a mass density that greatly exceeds the saturated mass density of water vapor at mesospheric temperatures, and so the aerosol particles are probably composed mainly of CO₂ ice. Our simple radiative transfer model is not applicable to twilight, when the mid-latitude mesospheric clouds were observed, and so we leave the properties of these clouds as a question for further work.     

Optimal design of pumping tests in leaky aquifers for stream depletion analysis

We analyze the optimal design of a pumping test for estimating hydrogeologic parameters that are subsequently used to predict stream depletion caused by groundwater pumping in a leaky aquifer. A global optimization method is used to identify the test’s optimal duration and the number and locations of observation wells. The objective is to minimize predictive uncertainty (variance) of the estimated stream depletion, which depends on the sensitivities of depletion and drawdown to relevant hydrogeologic parameters. The sensitivities are computed analytically from the solutions of Zlotnik and Tartakovsky [Zlotnik, V.A., Tartakovsky, D.M., 2008. Stream depletion by groundwater pumping in leaky aquifers. ASCE Journal of Hydrologic Engineering 13, 43–50] and the results are presented in a dimensionless form, facilitating their use for planning of pumping test at a variety of sites with similar hydrogeological settings. We show that stream depletion is generally very sensitive to aquitard’s leakage coefficient and stream-bed’s conductance. The optimal number of observation wells is two, their optimal locations are one close to the stream and the other close to the pumping well. We also provide guidelines on the test’s optimal duration and demonstrate that under certain conditions estimation of aquitard’s leakage coefficient and stream-bed’s conductance requires unrealistic test duration and/or signal-to-noise ratio.