Present environment and historic changes from the record of lake sediments, Dhaka City, Bangladesh

Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe₂O₃ and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe₂O₃ and Pb–Fe₂O₃ relations. Zn–Fe₂O₃ ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe₂O₃ ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe₂O₃ trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages.     

Geochemical study of arsenic and other trace elements in groundwater and sediments of the Old Brahmaputra River Plain,Bangladesh

The geochemical study of groundwaters and core sediments from the Old Brahmaputra plain of Bangladesh was conducted to investigate the distribution of arsenic and related trace elements. Groundwaters from tube wells are characterized by pH of 6.4–7.4, dissolved oxygen (DO) of 0.8–1.8 mg/l, Ca contents of 5–50 mg/l, and Fe contents of 0.2–12.9 mg/l. Arsenic concentrations ranged from 8 to 251 μg/l, with an average value of 63 μg/l. A strong positive correlation exists between As and Fe (r ² = 0.802; p = 0.001) concentrations in groundwater. The stratigraphic sequences in the cores consist of yellowish silty clays at top, passing downward into grayish to yellowish clays and sands. The uppermost 3 m and lower parts (from 13 to 31 m) of the core sediments are oxidized (average oxidation reduction potential (ORP) +170 and +220 mV, respectively), and the ORP values gradually become negative from 3 to 13 m depths (−35 to −180 mV), indicating that anoxic conditions prevail in the shallow aquifers of the Brahmaputra plain. Age determinations suggest that clay horizons at ~10 m depth were deposited at around 2,000 and 5,000 years BP (¹⁴C ages) during the transgressive phase of sea-level change. Elevated concentrations of As, Pb, Zn, Cu, Ni, Cr, and V are present in the silts and clays, probably due to adsorption onto clay particles. Significant concentrations of As occur in black peat and peaty sediments at depths between 9 and 13 m. A strong positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed onto Fe oxides in aquifer sediments.     

Aromatic ketones concentrated from Baltic Sea water

Aromatic ketones were concentrated from filtered Baltic Sea water by liquid—solid adsorption. After wet-chemical separation from acidic and basic components, the neutral fraction was column chromatographed to yield sub-fractions of increasing polarity. A subfraction eluted from silica gel with cyclopentane/diethyl ether contained a number of compounds which were identified by GC and GC—MS techniques as fluorenone, anthraquinone, benzanthrone, and benzene derivatives carrying an oxo group in the α-position relative to the aromatic ring. Formation and abiotic chemical reactions of these compounds in seawater are discussed.     

Ore deposits and epithermal evidences associated with intra-magmatic faults at Aïn El Araâr-Oued Belif ring structure (NW of Tunisia)

International Journal of Earth Sciences - Hydrothermal ore deposits at Aïn El Araâr-Oued Belif location are classified as epithermal deposits type. The ore bodies are hosted by upper...     

Beach and nearshore morphodynamic changes of the Tabarka coast,Northwest of Tunisia

Aerial photographs taken in the 1963 and 2001 and bathymetric charts, in conjunction with coastal processes are analyzed to assess changes in rate of shoreline position, seabed level, and seabed grain sizes along the Tabarka–Berkoukech beach at the north-western Tunisian coastline. The littoral cell of this beach, 12-km-long, is bounded by pronounced embayments and rocky headlands separated by sandy stretches. Although not yet very much undeveloped, this littoral is still experienced degradation and modification, especially along its shoreline, with significant coastal erosion at some places. Results obtained from analysis of shoreline position indicate that El Morjene Beach is experienced a landward retreat of more than −62 m, at a maximum rate of −1.64 m/year, whereas the El corniche beach is advanced about 16–144 m, at an average rate of 0.42 m–3.78 m/year. This beach accretion has been formed on the updrift side of the Tabarka port constructed between 1966 and 1970. Comparison of bottom contours deduced from bathymetric charts surveyed in 1881 and 1996 off the coastline between Tabarka Port and El Morjene Beach identifies erosional areas (sediment source) and accretionary zones (sediment sink). Erosion (0.87–4.35 cm/year) occurs between El kebir River Mouth and El Morjene beach, whereas accretion exists in the zone down wind of the port ranges between 0.87 and 5.21 cm/year. Morphological analyses of the shoreline and the seabed of the study nearshore area indicate that shoreline retreat corresponds to areas of seabed scour (sediment source) while shoreline accretion is associated with areas of seabed deposition (sediment sink). Furthermore, simulation of wave propagation using STWAVE model combined with grain size distributions of the seabed shows that fine sands are much dominated in depositional areas with low wave energy, whereas coarser sands in erosive zones with high wave energy. The results obtained suggest that the change of seabed morphology, wave height pattern and grain size sediment have a great influence on the modification of shoreline morphology and dynamics.     

Review: The Yucat��n Peninsula karst aquifer, Mexico

The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000? km² in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located in the vicinity of the North American/Caribbean plate boundary and has been reshaped by a series of tectonic events over its long geologic history. At the end of the Cretaceous period, the Yucatán Peninsula was hit by a large asteroid, which formed the Chicxulub impact crater. The Yucatán Peninsula karst aquifer hosts large amounts of groundwater resources which maintain highly diverse groundwater-dependent ecosystems. Large parts of the aquifer are affected by seawater intrusion. Anthropogenic pollution of the aquifer has been increasing over the past few decades, owing to relentless economic development and population growth on the Peninsula. This review summarizes the state of knowledge on the Yucatán Peninsula karst aquifer and outlines the main challenges for hydrologic research and practical groundwater-resources management on the Peninsula.     

Present environment of Dam Lake Sambe,southwestern Japan: a geochemical study of bottom sediments

Geochemical analyses of lakebed and core sediments from Lake Sambe on the outskirts of Oda City in Shimane prefecture in southwestern Japan were carried out in order to assess the water quality and the concentration and distribution patterns of sixteen elements. The lake water showed a stratified condition with respect to dissolved O₂, and As, Fe, and Mn concentrations in the bottom layers which increased in the summer. The chemical composition of the sediments, as measured by X-ray fluorescence, included major and trace elements (P, Ca, Sc, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Sr, Zr, Pb, and Th), and total sulfur (TS). Elevated values of As, Zn, V, Fe, P, and TS were present in several layers of the upper cores (from 0 to 5 cm) and other surface sediments. Increases in the abundances of these metals in lake sediments are probably related to the reducing condition of the sediments, fine-grained organic rich sediments, and post-depositional diagenetic remobilization. Moreover, correlations between the concentrations of trace metals and iron in the sediments suggest their adsorption onto Fe (oxy)hydroxides, whereas correlations with sulfur indicate that they were precipitated as Fe-sulfides. The average abundances of As, Pb, Zn, and Cu exceeded the lowest effect level and Interim Sediment Quality Guideline values that the New York State Department of Environmental Conservation and the Canadian Council of Ministers of the Environment determined to have moderate impact on aquatic organisms. In addition, concentrations of As and Zn exceeded the Coastal Ocean Sediment Database threshold value, indicating potentially toxic levels. Therefore, the presence of trace metals in the lake sediments may result in adverse effects on biota health.     

Distribution of arsenic and other trace elements in the Holocene sediments of the Meghna River Delta, Bangladesh

Geochemical study of the Holocene sediments of the Meghna River Delta, Chandpur, Bangladesh was conducted to investigate the distribution of arsenic and related trace and major elements. The work carried out includes analyses of core sediments and provenance study by rare earth element (REE) analysis. Results showed that the cores pass downward from silty clays and clays into fine to medium sands. The uppermost 3 m of the core sediments are oxidized [average oxidation reduction potential (ORP) + 230 mV], and the ORP values gradually become negative with depths (−45 to −170 mV), indicating anoxic conditions prevail in the Meghna sediments. The REE patterns of all lithotypes in the study areas are similar and are comparable to the average upper continental crust. Arsenic and other trace elements (Pb, Zn, Cu, Ni, and Cr) have greater concentrations in the silts and clays compared to those in the sands. Positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed on Fe oxides in aquifer sediments.     

Gravity analysis of salt structures. An example from the El Kef‐Ouargha region (northern Tunisia)

Triassic outcrops in the Atlassic zone of northern Tunisia may be modelled in two ways: salt bodies piercing through Cretaceous terrains or Triassic salt flows stratified within an Albian series. Both models find support from gravity data and are debatable. To evaluate the mass distribution changes with depth, the Bouguer anomaly of the El Kef‐Ouargha region was successively decomposed into regional and residual components to construct multiple pseudo‐depth slices and apparent density maps. Analyses of gravity lows clearly show a vertical continuity of less dense materials below the Triassic salt outcrops. These features can be explained by salt diapirism during Mesozoic and Cenozoic. Further, gravity data tend to indicate less dense materials below Aptian outcropping in Jebel Aite (Oued Bou Adila); thus suggesting Triassic materials occurring at depth. In addition, dense entities were recognized under Mio‐Pliocene and Quaternary deposits, which are thought to correspond to Cretaceous paleoshoals currently collapsed by non‐outcropping faults. Our findings lend support to a diapir model intruding overburden rather than the salt glacier model stratified in the Albian series proposed by some authors as the genetic structural model for Triassic material‐bearing series in the north of Tunisia.