Microphysical modeling of ethane ice clouds in titan’s atmosphere

A time-dependent microphysical model is used to study the evolution of ethane ice clouds in Titan’s atmosphere. The model simulates nucleation, condensational growth, evaporation, coagulation, and transport of particles. For a critical saturation of 1.15 (a lower limit, determined by laboratory experiments), we find that ethane clouds can be sustained between altitudes of 8 and 50 km. Growth due to coalescence is inefficient, limiting the peak in the size distribution (by number) to 10 μm. These clouds vary with a period of about 20 days. This periodicity disappears for higher critical saturation values where clouds remain subvisible. Rainout of ethane due to methane cloud formation raises the altitude of the ethane cloud bottom to near the tropopause and may eliminate ethane clouds entirely if methane cloud formation occurs up to 30 km. However, clouds formed above the troposphere from other gases in Titan’s atmosphere could be sustained even with rainout up to 30 km. Although the optical depth of ethane clouds above 20 km is typically low, short-lived clouds with optical depths of order 0.1-1 can be created sporadically by dynamically driven atmospheric cooling. Ethane cloud particles larger than 25 μm can fall to the surface before total evaporation. However, ethane clouds remain only a small sink for tholin particles. At the peak of their cycle, the optical depth of ethane clouds could be comparable to that of tholin in the near-infrared, resulting in a 5% increase in Titan’s albedo for wavelengths between 1 and 2 μm. A number of factors limit our ablility to predict the ethane cloud properties. These factors include the mixing time in the troposphere, the critical saturation ratio for ethane ice, the existence of a surface reservoir of ethane, the magnitude and timing of dynamically driven temperature perturbations, and the abundance and life cycle of methane clouds.     

Particulate barium fluxes and export production in the northwestern Mediterranean

Biogenic barium, mostly in the barite (BaSO₄) form, has been proposed as a tracer for export production in the ocean. Here we report on biogenic barium (Ba_xs) and particulate organic carbon (POC) fluxes from sediment traps deployed at the DYFAMED site in the Northwestern Mediterranean Sea. Ba_xs fluxes display average values of 37 ± 45 and 50 ± 58 μg/m²/d at 200 and 1000 m respectively, and are linearly correlated to POC fluxes (mean values of 7.9 ± 9.3 and 6.8 ± 6.8 mg C/m²/d at 200 and 1000 m). Export production estimates, calculated using published Ba_xs- or POC-based algorithms, all fall below or close to the lower limit of potential export values proposed in the literature. This work clearly demonstrates the usefulness of Ba_xs as a tracer of oceanic export production in the Northwestern Mediterranean Sea. However, development of a quantitative export production proxy requires a clear understanding of the underlying cause(s) for the observed spatial variations in the relationship between Ba_xs and POC fluxes. The present study confirms that the processes leading to barite formation differ between margin and open-ocean sites and probably account for much of the regional variability in the POC/Ba_xs ratio.     

Multiple magnetization events in the Red River carbonates, Williston Basin, Canada: Evidence for fluid-flow?

Samples collected from the Upper Ordovician Red River carbonates in a well at the centre of the Williston Basin revealed two paleomagnetic components with different inclinations, 60.3 ± 3.9° (k = 70.7, N = 12) and 20.4 ± 3.3° (k = 141.2, N = 8), but similar declination values in individual specimens. Inclination-only analysis indicates two possible scenarios for the age of these two magnetizations: in scenario (a) the timing of magnetization happened sometime between Late Ordovician to Devonian; and in scenario (b) there are two different remagnetizations, one that overlaps Pennsylvanian to Permian time while the other can have either a Late Jurassic or a Tertiary age. Whereas dolomitization and some isotopic data tend to support scenario (a), previous paleomagnetic data from the Williston Basin and from younger units in the same well, the tectonic evolution of the basin, and the hydrocarbon maturation pattern in the Red River carbonates all favour chemical remagnetization(s) driven by orogenic fluids during the Alleghenian and Laramide orogenies.     

探测冰盖和多年冻土层的融冰探头研发

The exploration of ice sheets by melting vertical holes into the ground has some tradition in terrestrial glaciology. Such probes have been used since the 1960's to investigate the vertical structure of the ice in Greenland and Antarctica and in alpine glaciers. In this paper we look into the possibility to develop similar devices for use on extraterrestrial icy bodies, like e.g. the polar areas on Mars or the icy satellites of the outer solar system. We report on some basic experiments performed in the cryo-vacuum laboratory of the Space Research Institute of the Austrian Academy of Sciences, Graz. In these experiments the penetration of a simple melting probe into compact and porous water ice (with a snow-like texture) was monitored, both under vacuum conditions and under air pressure. The observed penetration speeds for a given power supply are compared with a simple mathematical model. We conclude that a miniature melting probe with small overall dimensions and a reasonable power demand could well be part of the payload of a future planetary mission, for example to the poles of Mars. Such missions are currently under discussion in several space agencies. Moreover such probes could also e? ectively be used in terrestrial environments. A possible design is presented at the end of the paper.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Thermal conductivity measurements of road construction materials in frozen and unfrozen state

A series of thermal conductivity measurements for various materials was performed in a large climate chamber. The size of the chamber allowed the preparation of relatively large samples in a controlled thermal environment. Three types of thermal sensors were used: (1) two needle probes; (2) a grid of temperature sensors, evenly distributed inside the sample; (3) two additional thermal probes, which were simplified versions of an instrument originally developed for measuring thermal properties of the ice/dust mixture expected to exist at the surface of a comet nucleus. They consist of a series of individual temperature sensors integrated into a glass fibre rod. Each of these sensors can be operated in an active (heated) or passive (only temperature sensing) mode. The following sample materials were used: fine-grained reddish sand, coarse-grained moist sand, gravels with various grain size distributions from < 1 cm up to about 6 cm, and for comparison and calibration pure water (with convection suppressed by adding agar-agar), compact ice, and compact granite. Of particular interest are the measurements with composite samples, like stones embedded in an agar-agar matrix. We describe the evaluation methods and present the results of the thermal conductivity measurements.     

Sensitivity of the regional climate model RegCM4.2 to planetary boundary layer parameterisation

This study investigates the performance of two planetary boundary layer (PBL) parameterisations in the regional climate model RegCM4.2 with specific focus on the recently implemented prognostic turbulent kinetic energy parameterisation scheme: the University of Washington (UW) scheme. When compared with the default Holtslag scheme, the UW scheme, in the 10-year experiments over the European domain, shows a substantial cooling. It reduces winter warm bias over the north-eastern Europe by 2 °C and reduces summer warm bias over central Europe by 3 °C. A part of the detected cooling is ascribed to a general reduction in lower tropospheric eddy heat diffusivity with the UW scheme. While differences in temperature tendency due to PBL schemes are mostly localized to the lower troposphere, the schemes show a much higher diversity in how vertical turbulent mixing of the water vapour mixing ratio is governed. Differences in the water vapour mixing ratio tendency due to the PBL scheme are present almost throughout the troposphere. However, they alone cannot explain the overall water vapour mixing ratio profiles, suggesting strong interaction between the PBL and other model parameterisations. An additional 18-member ensemble with the UW scheme is made, where two formulations of the master turbulent length scale in unstable conditions are tested and unconstrained parameters associated with (a) the evaporative enhancement of the cloud-top entrainment and (b) the formulation of the master turbulent length scale in stable conditions are systematically perturbed. These experiments suggest that the master turbulent length scale in the UW scheme could be further refined in the current implementation in the RegCM model. It was also found that the UW scheme is less sensitive to the variations of the other two selected unconstrained parameters, supporting the choice of these parameters in the default formulation of the UW scheme.     

Changes in extremes and hydroclimatic regimes in the CREMA ensemble projections

We analyze changes of four extreme hydroclimatic indices in the RCP8.5 projections of the Phase I CREMA experiment, which includes 21st century projections over 5 CORDEX domains (Africa, Central America, South America, South Asia, Mediterranean) with the ICTP regional model RegCM4 driven by three CMIP5 global models. The indices are: Heat Wave Day Index (HWD), Maximum Consecutive Dry Day index (CDD), fraction of precipitation above the 95th intensity percentile (R95) and Hydroclimatic Intensity index (HY-INT). Comparison with coarse (GPCP) and high (TRMM) resolution daily precipitation data for the present day conditions shows that the precipitation intensity distributions from the GCMs are close to the GPCP data, while the RegCM4 ones are closer to TRMM, illustrating the added value of the increased resolution of the regional model. All global and regional model simulations project predominant increases in HWD, CDD, R95 and HY-INT, implying a regime shift towards more intense, less frequent rain events and increasing risk of heat wave, drought and flood with global warming. However, the magnitudes of the changes are generally larger in the global than the regional models, likely because of the relatively low “climate sensitivity” of the RegCM4, especially when using the CLM land surface scheme. In addition, pronounced regional differences in the change signals are found. The data from these simulations are available for use in impact assessment studies.     

Macrofaunal density and biomass in the Campeche Canyon, Southwestern Gulf of Mexico

The composition, density and community structure of the benthic macrofauna were investigated in sediments of the Campeche Canyon in the SW Gulf of Mexico. Total macrofaunal density ranged from 9466±2736 ind m⁻² at the continental shelf station to 1550±195 ind m⁻² in the canyon. Density values significantly diminished with distance from the coast and depth; only a few stations in the center of the canyon displayed larger density values (E-37 with 4666±1530 ind m⁻², E-36 with 5791±642 ind m⁻² and E-26 with 6925±2258 ind m⁻²). Densities were positively correlated to organic nitrogen in the sediment (r=0.82) and coarse silt (r=0.43), and negatively with depth (r=−0.74) and distance from the coast (r=−0.68). At all stations, the polychaete worms contributed most to the multi-species community structure. The nematodes and Foraminifera displayed their highest densities in the center of the canyon. The biomass values declined significantly with depth. We conclude that the macrofauna density and biomass changed in response to organic matter contents in the sediment, both with distance from the coast and with depth.     

The determination of potential difference by the joint application of measured and synthetical gravity data: a case study in Hungary

In an elementary approach every geometrical height difference between the staff points of a levelling line should have a corresponding average g value for the determination of potential difference in the Earth’s gravity field. In practice this condition requires as many gravity data as the number of staff points if linear variation of g is assumed between them. Because of the expensive fieldwork, the necessary data should be supplied from different sources. This study proposes an alternative solution, which is proved at a test bed located in the Mecsek Mountains, Southwest Hungary, where a detailed gravity survey, as dense as the staff point density (~1 point/34 m), is available along a 4.3-km-long levelling line. In the first part of the paper the effect of point density of gravity data on the accuracy of potential difference is investigated. The average g value is simply derived from two neighbouring g measurements along the levelling line, which are incrementally decimated in the consecutive turns of processing. The results show that the error of the potential difference between the endpoints of the line exceeds 0.1 mm in terms of length unit if the sampling distance is greater than 2 km. Thereafter, a suitable method for the densification of the decimated g measurements is provided. It is based on forward gravity modelling utilising a high-resolution digital terrain model, the normal gravity and the complete Bouguer anomalies. The test shows that the error is only in the order of 10⁻³mm even if the sampling distance of g measurements is 4 km. As a component of the error sources of levelling, the ambiguity of the levelled height difference which is the Euclidean distance between the inclined equipotential surfaces is also investigated. Although its effect accumulated along the test line is almost zero, it reaches 0.15 mm in a 1-km-long intermediate section of the line.