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1.
Jack B. Epstein 《Geological Journal》1986,21(3):283-306
Many contributions that have led to a better understanding of Appalachian geology have resulted directly from work in the folded Appalachian Mountain and Great Valley sections of the Valley and Ridge physiographic province of eastern Pennsylvania. Disagreements have been common since H.D. Rogers first described the geology of the area in 1858. Many differing opinions still exist regarding the stratigraphy, structural geology, geomorphology, and glacial geology. The rocks in the area, which range from Middle Ordovician to Late Devonian in age, are more than 25000 feet (7620 m) thick. This diversified group of sedimentary rocks was deposited in many different environments, ranging from deep sea, through neritic and tidal, to alluvial. In general, the Middle Ordovician through Lower Devonian strata are a sedimentary cycle related to the waxing and waning of Taconic tectonism. The sequence began with a greywacke-argillite suite (Martinsburg Formation) representing synorogenic basin deepening. This was followed by basin filling and pro-gradation of a sandstone-shale clastic wedge (Shawangunk Formation and Bloomsburg Red Beds) derived from the erosion of the mountains that were uplifted during the Taconic orogeny. The sequence ended with deposition of many thin units of carbonate, sandstone, and shale on a shelf marginal to a land area of low relief. Another tectonic-sedimentary cycle, related to the Acadian orogeny, began with deposition of Middle Devonian rocks. Deep-water shales (Marcellus Shale) preceded shoaling (Mahantango Formation) and turbidite sedimentation (Trimmers Rock Formation) followed by another molasse (Catskill Formation). 相似文献
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Solvent extractions were done on the carbonaceous chondrites Murray, Murchison, Orgueil and Renazzo, using CCl4 and CH3OH. Between 2 and 10% of the total carbon in these meteorites is extractable by ordinary techniques, most of it in CH3OH. After demineralization with HF, perhaps as much as 30% of the total carbon in Murray may be extractable with CH3OH. The extracts from Renazzo have isotopic ratios which suggest that they are mainly terrestrial organic matter, with lesser contributions from indigenous organics. The CH3OH-soluble organic matter from Murchison and both untreated and HF-treated Murray has δ13C values of about +5 to + 10%. and δ15N values of about +90 to +100%., both of which are significantly higher than the bulk meteorite values. The Orgueil CH3OH-extract also has a δ15N value well above the value in residual organic matter. Values for δD of +300 to +500%. are found for the CH3OH-soluble organic matter. The combined data for C, H and N isotopes makes it highly unlikely that the CH3OH-soluble components are derivable from, or simply related to, the insoluble organic polymer found in the same meteorites. A relationship is suggested between the event that formed hydrous minerals in CI1 and CM2 meteorites and the introduction of water-soluble (methanol-soluble) organic compounds. Organic matter soluble in CCl4 has essentially no nitrogen, and δ3C and δD values are lower than for CH3OH-soluble phases. Either there are large isotopic fractionations for carbon and hydrogen between different soluble organic phases, or the less polar components are partially of terrestrial origin. 相似文献
4.
Carbonate cementation in the surface layer of reefs and beachrock eliminates porosity and partially replaces detrital quartz grains. The uptake and release of CO2 by photosynthesis and respiration in reef communities cause a shift in the carbonate buffer system of seawater. Field studies and experimentation simulating the natural settings show minimum values of CO2 (1.9 mmoles 1?1) and HCO3? (2.4 meq 1?1) in association with maximum values of pH (9.8) and O2 (> 100% oxygen saturation) in waters covering corals and algae prior to sunset. The converse is true for these variables prior to sunrise, when minimum values of pH (7.6) and O2 (<66% oxygen saturation) occur with maximum values of CO2 (2.7 mmoles 1?1) and HCO3? (2.7 meq 1?1). Experimental tanks containing plain seawater showed almost no diurnal variability in pH (a constant 7.5–7.6) or O2 (80–90% oxygen saturation) measurements. Seawater adjacent to reef biomass, with elevated pH and supersaturated with calcium carbonate, is periodically pumped into the underlying reef and beach sediments due to pressure-buildups between the reef framework or algal zones and open waters. Carbonate precipitation and quartz dissolution follow. As the system equilibrates, pH values progressively decrease. 相似文献
5.
Donald W. Northfelt Michael J. DeNiro Samuel Epstein 《Geochimica et cosmochimica acta》1981,45(10):1895-1898
The and C ratios of the cellulose nitrate and saponifiable lipid fractions prepared from eleven annual growth rings of a California redwood were determined. The ratios of the two fractions are related to one another for the annual rings in the sapwood portion of the tree, but not for those in the heartwood or in the wood undergoing the transition from sapwood to heartwood. No relationship was observed between the ratios of the two fractions. These results suggest that analysis of the hydrogen isotopic composition of the saponifiable lipid fractions in plants will provide information useful for climatic reconstruction provided the initial isotopic record has not been changed by subsequent physiological or diagenetic processes. 相似文献
6.
Hydrogen isotope fractionation factors between hydroxyl-bearing minerals and water were determined at temperatures ranging between 400 and 850°C. The hydrogen isotope exchange rates for the mineral-water pairs examined were very slow. In most cases it was necessary to use an interpolation method for the determination of the hydrogen isotope equilibrium fractionation factor, αe.For the temperature range of 450–850°C the hydrogen isotope fractionation factors for the mica-water and amphibole-water systems are simply expressed as a function of temperature and the molar fractions of the six-fold coordinated cations in the crystal, regardless of mineral species, as follows: 103 In αe(mineral-water) = ? 22.4 (106T?2) + 28.2 + (2XAl ? 4XMg ? 68XFe), where X is the molar fraction of the cations. As the equation indicates, for any specific composition of the OH-bearing minerals, the change of αe with temperature, over the temperature range investigated, is the same for all minerals studied. Thus for any specified values of XAl, XMg, and XFe for these minerals, the relationship between αe and T is 103 In αe = αT?2 + k. Consequently, hydrogen isotope fractionation among coexisting minerals is temperature independent and cannot be used as a hydrogen isotope geothermometer.Some exceptions to the above general observations exist for minerals such as boehmite and kaolinite. In these minerals hydrogen bonding modifies the equilibrium hydrogen isotopic fractionation between mineral and water. 相似文献
7.
In recent times major changes have occurred in extensive areas of Lapland inhabited by the reindeer-herding Lapps of northern Fennoscandia (Norway, Sweden, Finland, and the Kola Peninsula in the Soviet Union). Their customary way of life, delicately attuned to the ecological conditions of the arctic and subarctic areas, is buffetet between the environment-adapted life of the timeless tundra, forests, and swapms and the modern industrialized economy of northern Europe.The Lapps in the northern part of the reindeer-herding region have maintained some of the old nomadic ways and are closely tied to the habits of the reindeer, providing a simple but excellent example of the way that man can use nature without destroying it. The continued practice of reindeer ecology may serve as the catalyst that will keep the occupation of reindeer husbandry alive and make possible an orderly fusion with modern trends. 相似文献
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Stacy D. Jupiter Graham Epstein Natalie C. Ban Sangeeta Mangubhai Margaret Fox Michael Cox 《社会与自然资源》2017,30(9):1096-1111
Locally managed marine areas (LMMAs) are often recommended as a strategy to achieve conservation and fisheries management, though few studies have evaluated their performance against these objectives. We assessed the effectiveness of eight periodically harvested closures (PHCs), the most common form of management within Fijian LMMAs, focusing on two outcomes: protection of resource units and biodiversity conservation. Of the eight PHCs, only one provided biodiversity benefits, whereas three were moderately successful in protecting resource units (targeted fish biomass). Protection of resource units was more likely when PHCs were harvested less frequently, less recently, and when total fish biomass in open areas was lower. Our findings further suggest that monitoring, enforcement, and clearly defined boundaries are critical, less frequent harvesting regimes are advised, and culturally appropriate management incentives are needed. Although PHCs have some potential to protect resource units, they are not recommended as a single strategy for broad-scale biodiversity conservation. 相似文献
10.
There has been a great deal of discussion about global warming from accumulation of anthropogenic greenhouse gases in the atmosphere (Houghton et al., 1990). Relatively less attention has been paid to spatial and/or temporal climatic variations that may be associated with a warmer climate (Rind et al., 1989) or with anthropogenic activities (Schneider, 1994). In this article, we show that an increase in climatic variability may have started. Fourteen isotopic time series of tree rings are presented. These trees were randomly collected from world-wide locations and cover time periods of 120 to over 200 years. The isotopic records show increasing D values that suggest a consistent and progressive warming occurred in the 19th century in all locations where the trees were sampled. The rate of warming is greater at relatively cold locations than at warm locations with two exceptions. The records also suggest greater climatic variations both temporally and spatially in the 20th century than in the 19th century. 相似文献