Natural background levels and threshold values of monitored parameters in the Cambrian-Vendian groundwater body,Estonia

The Cambrian-Vendian groundwater body plays an important role in drinking water supply of capital Tallinn and other settlements in northern Estonia. Water quality in this deep-seated confined groundwater body is influenced by the intrusion of present-day seawater and pumping-induced upward migration of deeper saline groundwater. The aim of this study is to evaluate the threshold values applying the methodology worked out within the EU 6th FP project “Background criteria for the identification of groundwater thresholds (BRIDGE)” and to compare the results with the values proposed by local authorities. A database containing 250 monitoring points was completed and used for the calculation of natural background levels (as the 90 and 97.7 percentile) in groundwater. The calculation of threshold values is based on natural background levels and reference values. In case of Cambrian-Vendian groundwater body the receptor is drinking water, thus limit values set by Estonian drinking water standard were used as reference values. The threshold values proposed by local authorities are more or less the same as calculated by BRIDGE methodology. Exceptionally different values are derived in case of chloride and ammonium.     

The Colider and Roosevelt Volcanic rocks (sw amazonian craton): geochemistry and sm-nd isotope characteristics of a silicic large igneous province

The volcanic rocks of the Colíder and Roosevelt formations are extensively exposed in the south-central portion of the Amazonian Craton where effusive and pyroclastic rocks have been mapped. Both units, topped by chemical sediments and oceanic facies as rhyolite and andesite lavas, rhyodacite, and porphyritic dacite, with frequent intercalations of pyroclastic and epiclastic deposits. Whole-rock geochemistry for 55 samples of rhyolitic to andesitic composition suggests the involvement of fertile mantle-derived components with E-MORB to OIB compositions. The analyzed rocks display calc-alkaline to shoshonitic affinity consistent with generation related to an active continental margin. The whole-rock Sm-Nd isotope data from selected felsic volcanic rocks of the Colíder and Roosevelt formations yield negative initial ε_Nd values between –3 and –9, indicating the predominantly crustal nature of the parental magmas with early Archean to late Paleoproterozoic (ca. 2.5–2.0 Ga) depleted mantle model ages.

     

Spot patterns and differential rotation in the eclipsing pre-cataclysmic variable binary, V471 Tau

We present surface spot maps of the K2V primary star in the pre-cataclysmic variable binary system, V471 Tau. The spot maps show the presence of large high-latitude spots located at the sub-white dwarf longitude region. By tracking the relative movement of spot groups over the course of four nights (eight rotation cycles), we measure the surface differential rotation rate of the system. Our results reveal that the star is rotating rigidly with a surface shear rate,  dΩ= 1.6 ± 6 mrad d⁻¹  . The single active star AB Dor has a similar spectral type, rotation period and activity level as the K star in V471 Tau, but displays much stronger surface shear  (46 < dΩ < 58 mrad d⁻¹)  . Our results suggest that tidal locking may inhibit differential rotation; this reduced shear, however, does not affect the overall magnetic activity levels in active K dwarfs.     

Barium anomaly in the Cambrian-Vendian aquifer system in North Estonia

A barium anomaly with a maximum Ba²⁺ concentration of 6.37 mg/l was distinguished in a Cambrian-Vendian (Cm-V) aquifer system that is widely used as a drinking water source in the towns Kunda, Rakvere and Kohtla-Järve of North-Estonia. The modelling results show that at low sulphate concentrations (below 3 mg/l) Ba²⁺ contents can exceed the limit values for drinking water (such as 2 mg/l set by US EPA). Bicarbonate ions in their common concentration range in groundwater cannot limit Ba²⁺ at its content below 10 mg/l. The probable natural sources of the anomaly are the crystalline basement and its weathering zone. Groundwater in the clayey weathering core is hydraulically connected with the overlying Cm-V aquifer system, thus the upconing of deeper-seated groundwater, caused by intensive exploitation of wells, is possible.     

Recovering the real-space correlation function from photometric redshift surveys

Measurements of clustering in large-scale imaging surveys that make use of photometric redshifts depend on the uncertainties in the redshift determination. We have used light-cone simulations to show how the deprojection method successfully recovers the real-space correlation function when applied to mock photometric redshift surveys. We study how the errors in the redshift determination affect the quality of the recovered two-point correlation function. Considering the expected errors associated with the planned photometric redshift surveys, we conclude that this method provides information on the clustering of matter useful for the estimation of cosmological parameters that depend on the large-scale distribution of galaxies.     

Carbon isotope systematics of the Cambrian–Vendian aquifer system in the northern Baltic Basin: Implications to the age and evolution of groundwater

Groundwater in the Cambrian–Vendian aquifer system has a strongly depleted stable isotope composition (δ¹⁸O values of about −22‰) and a low radiocarbon concentration, which suggests that the water is of glacial origin from the last Ice Age. The aim of this paper was to elucidate the timing of infiltration of glacial waters and to understand the geochemical evolution of this groundwater. The composition of the dissolved inorganic C (DIC) in Cambrian–Vendian groundwater is influenced by complex reactions and isotope exchange processes between water, organic materials and rock matrix. The δ¹³C composition of dissolved inorganic C in Cambrian–Vendian water also indicates a bacterial modification of the isotope system. The corrected radiocarbon ages of groundwater are between 14,000 and 27,000 radiocarbon years, which is coeval with the advance of the Weichselian Glacier in the area.     

Magma yield stress and permeability: Insights from multiphase percolation theory

Magmas often contain multiple interacting phases of embedded solid and gas inclusions. Multiphase percolation theory provides a means of modeling assemblies of these different classes of magmatic inclusions in a simple, yet powerful way. Like its single phase counterpart, multiphase percolation theory describes the connectivity of discrete inclusion assemblies as a function of phase topology. In addition, multiphase percolation employs basic laws to distinguish separate classes of objects and is characterized by its dependency on the order in which the different phases appear. This paper examines two applications of multiphase percolation theory: the first considers how the presence of bubble inclusions influences yield stress onset and growth in a magma's crystal network; the second examines the effect of bi-modal bubble-size distributions on magma permeability. We find that the presence of bubbles induces crystal clustering, thereby 1) reducing the percolation threshold, or critical crystal volume fraction, ?_c, at which the crystals form a space-spanning network providing a minimum yield stress, and 2) resulting in a larger yield stress for a given crystal volume fraction above ?_c. This increase in the yield stress of the crystal network may also occur when crystal clusters are formed due to processes other than bubble formation, such as heterogeneous crystallization, synneusis, and heterogeneity due to deformation or flow. Further, we find that bimodal bubble size distributions can significantly affect the permeability of the system beyond the percolation threshold. This study thus demonstrates that larger-scale structures and topologies, as well as the order in which different phases appear, can have significant effects on macroscopic properties in multiphase materials.     

Clusters and groups of galaxies in the 2dF galaxy redshift survey: A new catalogue

We create a new catalogue of groups and clusters, applying the friends‐of‐friends method to the 2dF GRS final release. We investigate various selection effects due to the use of a magnitude limited sample. For this purpose we follow the changes in group sizes and mean galaxy number densities within groups when shifting nearby observed groups to larger distances. We study the distribution of sizes of dark matter haloes in N ‐body simulations and compare properties of these haloes and the 2dF groups. We show that at large distances from the observer luminous and intrinsically greater groups dominate, but in these groups only very bright members are seen, which form compact cores of the groups. These two effects almost cancel each other, so that the mean sizes and densities of groups do not change considerably with distance. Our final sample contains 10750 groups in the Northern part, and 14465 groups in the Southern part of the 2dF survey with membership N _gal ≥ 2. We estimate the total luminosities of our groups, correcting for group members fainter than the observational limit of the survey. The cluster catalogue is available at our web‐site ( http://www.aai.ee/∼maret/2dfgr.html ). (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)