Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy

A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A²Π_3/2 ← X²Π_3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N₂O/CF₃I/N₂ mixtures with O₃ actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.     

The effects of several common anthropogenic contaminants on proliferation of the parasitic oyster pathogen Perkinsus marinus

Estuarine contaminants have varying effects on estuarine inhabitants and host-parasite interactions. Some field collected contaminant mixtures have been shown to increase oyster susceptibility to parasitism by Perkinsus marinus, but little is known about contaminant effects on the parasite itself. This study examined the effects of ammonium, nitrate, phosphate, fluoranthene, phenanthrene and a common herbicide mixture (Weed-B-Gone) on in vitro proliferation of P. marinus. Only the herbicide had a significant effect, but not at or below the manufacture's recommended application rate (7.81 microl ml(-1)). The herbicide's active ingredients (3.1% 2,4-dichlorophenoxyacetic acid, 10.6% mecoprop and 1.3% dicamba) mimic growth hormones of broadleaf plants; over stimulation of growth results in death. The mode of action of these compounds on P. marinus warrants further investigation which may provide insight towards the identification of biocides to control P. marinus.     

Phylogeographical patterns of the gastropod Siphonaria pectinata (Linnaeus, 1758)

Siphonaria pectinata is a marine gastropod distributed across the shores of the Western and Eastern Atlantic. Although previous studies have indicated that the species could be a recent introduction to Central and North America from Western Africa and Europe, other authors have questioned this statement. In fact, a recent study has shown that individuals from both sides of the Atlantic are genetically disconnected, rejecting the idea of a recent invasion. However, genetic information on this species is very scarce and based only on a single study using a limited number of specimens and sites. The data reported in the present study represent one step forward, collecting information from 119 specimens from 22 sites that cover the entire distributional range of the species. Populations from the Western Atlantic separated from eastern ones around 1.4?1.9 Mya, whereas the centre of dispersion is located on the eastern side of the Atlantic. Siphonaria pectinata should be considered native to the Western Atlantic and cannot be considered as a species with an amphi‐atlantic distribution owing to the lack of genetic connection between both sides of the Atlantic, as previous authors have pointed out. The presence of a star‐shaped phylogeny is discussed in the context of Plio‐Pleistocene glaciations.     

Artificial Marine Micro‐Reserves Networks (AMMRNs): an innovative approach to conserve marine littoral biodiversity and protect endangered species

Coastal engineering works, especially the outer breakwaters of ports where environmental conditions are usually good, often constitute new habitats for marine littoral species. Their potential indirect contribution to the regeneration and conservation of protected species opens up a new perspective in protection of marine biodiversity. This is particularly true when these works harbour, as we show here, important reproductive populations of species that are threatened or even in danger of extinction. We provide integrated data on protected marine species in Southern Iberia established on different substrata (quarried dolomitic rocks, concrete cubic blocks, concrete tetrapods and vertical concrete walls) that are used in the construction of artificial levees that could potentially be Artificial Marine Micro‐Reserves (AMMRs). We also present the first evidence of the ‘reserve effect’ in potential AMMRs and we discuss the need for the creation of AMMRs including their effective networking (AMMRNs), supporting data for which has been observed by studying coastal facilities subjected to strict access restrictions (for security reasons, not conservation). These facilities have acted as valuable proxies and, in reality, potentially act as AMMRs, as well as having a role in helping to detect and control invasive species. We discuss the ecological engineering aspects related to the design and type of materials used in coastal constructions with a view to aiding the integration of these into existing coastal ecosystems as well as promoting greater settlement of species and therefore increases in biodiversity. Finally, the environmental implications of AMMRNs within the future implementation strategy of the Water Framework Directive 2000/60 EC are also discussed.     

Novel measurements of atmospheric iodine species by resonance fluorescence

A field instrument has been developed for the purpose of measuring gas-phase atmospheric iodine species in the marine boundary layer. Vacuum UV resonance-fluorescence (RF), generated using a microwave discharge lamp, is employed to detect atomic iodine via the (5p⁴6s)–(5p⁵) transitions around 178–184 nm. The system can be operated in two modes; either to directly measure ambient iodine atoms, or to measure the total photolabile iodine loading of ambient air, through broadband visible photolysis of photolabile iodine-containing species, with subsequent RF detection of the iodine atoms released. In both cases the instrument allows for the in situ measurement of the species detected, which is advantageous for gathering information concerning their local sources and distribution. The instrument is calibrated through generation of a known concentration of iodine atoms from the photolysis of I₂ using a mercury pen-ray lamp. The instrument was deployed for the first time in August 2007 at Mace Head on the west coast of Ireland; initial results from this field trial are presented. Ambient iodine atoms were measured at levels up to 22 ± 4.8 ppt during the day, coinciding with the lowest tides, when Laminaria seaweed beds were exposed. The total photolabile iodine loading was also measured during several night-time and day-time periods and was found to correlate inversely with tidal height. Inferred I₂ concentrations based on these measurements indicate levels of several hundred ppt at the Mace Head site. These measurements represent the first direct observations of ambient iodine atoms and measurement of total photolabile iodine in the atmosphere.     

Improved discrete element modeling for proppant embedment into rock surfaces

Brinell indentation tests were performed on Montney siltstone, and the results were compared with discrete element indentation simulations that use the micro-parameters calibrated using compression test data from the same siltstone samples. The simulated proppant indentation into the rock surface can be 15% less than the laboratory measurements. A lower effective particle–particle modulus and thus a lower Young’s modulus are needed in discrete element models for proper simulation of indentation. An equation to find the appropriate value of Young’s modulus for indentation simulation is proposed using Brinell indentation tests including 198 laboratory tests and 32 discrete element simulations. This equation can improve the prediction of Young’s modulus and thus the particle–particle effective modulus for indentation simulations to match the measured force–indentation depth curve in the laboratory. Using the improved micro-parameters, a parametric analysis of the influence of rock Young’s modulus and proppant particle size on proppant embedment was performed. An equation to estimate Brinell hardness as a function of Young’s modulus and closure stress was derived. A practical procedure was developed to predict proppant embedment from the estimated hardness. The predictions agree with the laboratory measurements in a case study on the Montney Formation.

     

Field observations from the Aquila, Italy earthquake of April 6, 2009

On April 6, 2009 an earthquake of magnitude 6.2 (M_w) struck the Abbruzzo region of Italy causing widespread damage to buildings in the city of L??Aquila and surrounding areas. This paper summarizes field observations made by the Earthquake Engineering Field Investigation Team (EEFIT) after the event. The paper presents an overview of seismological and geotechnical aspects of the earthquake as well as a summary of the observed damage to buildings and infrastructure. A brief overview of the earthquake casualties is also reported.     

Influence of habitat structure and nature of substratum on limpet recruitment: Conservation implications for endangered species

Habitat complexity has been recognised to exert a significant influence on the abundance and diversity of benthic invertebrates. This issue is especially important for the management of endangered species. The recruitment of limpet species was monitored monthly for one year on natural and artificial surfaces. Control plots showed the highest mean number of species and individuals settled per plot, followed by rough then smooth plots. Control plots presented the highest mean diversity values followed by rough and smooth plots. Recruits of the endangered limpet Patella ferruginea were mainly observed during the spring, from April to June. Recruitment seemed to be influenced by both the heterogeneity and nature of the substratum. P. ferruginea repopulation programmes involving the translocation of recruits on experimental plates should be conducted using similar materials to the natural substratum, such as granite or limestone, rather than plastic, avoiding surfaces with low levels of heterogeneity, and taking into account that translocation of adults is not feasible due to the high mortality observed.     

Observations and implications of damage from the magnitude Mw 6.3 Christchurch, New Zealand earthquake of 22 February 2011

This paper describes the observations made by a reconnaissance team following the 22nd February 2011, M_w 6.3, Christchurch, New Zealand earthquake (GNS Science, 2011). The team comprised of members of the UK based Earthquake Engineering Field Investigation Team who spent 5 days collecting observations on damage resulting from the earthquake. Although the magnitude of this earthquake was not particularly high (M_w 6.3), the shallow focus and close proximity resulted in locally very high ground motions, widespread damage and 182 fatalities. The earthquake is also particularly notable for the widespread liquefaction it caused, landslides and rockfalls in the hills south of Christchurch, and the significant damage suffered by unreinforced masonry and historic structures. Over wide areas of central Christchurch, recorded accelerations were in excess of those required by the current New Zealand seismic loadings standard (NZS1170.5:2004: Standards New Zealand 2004) and therefore the earthquake presented a valuable opportunity to assess performance of modern buildings under code-level ground acceleration.