A survey of photogeochemistry

The participation of sunlight in the natural chemistry of the earth is presented as a unique field of study, from historical observations to prospects for future inquiry. A compilation of known reactions shows the extent of light-driven interactions between naturally occurring components of land, air, and water, and provides the backdrop for an outline of the mechanisms of these phenomena. Catalyzed reactions, uncatalyzed reactions, direct processes, and indirect processes all operate in natural photochemical transformations, many of which are analogous to well-known biological reactions. By overlaying photochemistry and surface geochemistry, complementary approaches can be adopted to identify natural photochemical reactions and discern their significance in the environment.     

Globalization,economic crisis and Africa's informal economy women workers

The processes of globalization and debt crisis led to dramatic changes in African countries. In the context of a new economic crisis – now on a global scale – it is useful to revisit debates regarding the impact of earlier policies in response to economic crisis on the poor, with a focus on very low‐income informal women workers. In this paper, we adopt a gender analysis framework to examine contending perspectives about the differential impacts of globalization, liberalization and structural adjustment programs on African women and men. We comment on two predominant schools of thought that appear to underlie and define the majority of case studies situated in African countries. While one asserts that globalization and liberalization offer entrepreneurial opportunities for women, an opposing view contends that the neoliberal political and economic reforms connected with structural adjustment policies have been devastating for poor women workers. A review of available empirical research on the responses of informal economy women workers to challenges of increased workload, reduced income and curtailed access to social services, cautions against dogmatic adherence to conceptual perspectives that either assume workers in the informal economy to be dynamic entrepreneurs when they cannot be, or condemn only contemporary policies for conditions that are the product of complex historical processes.     

Velocity-Resolved Observations of Hα Emission From Comet C/1995 O1 (Hale–Bopp)

We present hydrogen Balmer-α spectra of comet C/1995 O1(Hale–Bopp) recorded on 5 nights from 1997 February 1 to April 19 by ahigh-resolution (Δ v = 5 km s^-1) Fabry–Pérot spectrometer for a4'.1 (∼2.7 × 10⁵ km) FOV centered 5' sunwardof the nucleus. The Hα line profile is an important diagnostic ofphotolytic heating in cometary atmospheres. Extraction of the spectrafrom the Fabry–Pérot ring images was complicated by obscuration of the telescope FOV due to Hale–Bopp's low elevation, but the measuredH-α line widths of 11–13 km s^-1 (FWHM) are insensitive to the spectral extraction technique. The line widths are consistent withestimates derived from a successful model of Hale–Bopp's hydrogenLyman-α coma assuming the inner coma is opaque to Hα. Wediscuss methods for improving the spectral extraction technique andderiving a precise instrument profile which will allow the detailedshape of the line profile to constrain coma models.     

The Gas Production Rate and Coma Structure of Comet C/1995 O1 (Hale–Bopp)

The University of Wisconsin–Madison and NASA–Goddard conducted acomprehensive multi-wavelength observing campaign of coma emissionsfrom comet Hale–Bopp, including OH 3080 Å, [O I] 6300 Å H₂O⁺ 6158 Å, H Balmer-α 6563 Å, NH₂ 6330 Å, [C I] 9850 ÅCN 3879 Å, C₂ 5141 Å, C₃ 4062 Å,C I 1657 Å, and the UV and optical continua. In thiswork, we concentrate on the results of the H₂O daughter studies.Our wide-field OH 3080 Å measured flux agrees with other, similarobservations and the expected value calculated from published waterproduction rates using standard H₂O and OH photochemistry.However, the total [O I] 6300 Å flux determined spectroscopically overa similar field-of-view was a factor of 3-4 higher than expected.Narrow-band [O I] images show this excess came from beyond theH₂O scale length, suggesting either a previously unknown source of[O I] or an error in the standard OH + ν→ O(¹ D) + H branching ratio. The Hale–Bopp OH and[O I] distributions, both of which were imaged tocometocentric distances >1 × 10⁶ km, were more spatiallyextended than those of comet Halley (after correcting for brightnessdifferences), suggesting a higher bulk outflow velocity. Evidence ofthe driving mechanism for this outflow is found in the Hα lineprofile, which was narrower than in comet Halley (though likelybecause of opacity effects, not as narrow as predicted by Monte-Carlomodels). This is consistent with greater collisional coupling betweenthe suprathermal H photodissociation products and Hale–Bopp's densecoma. Presumably because of mass loading of the solar wind by ionsand ions by the neutrals, the measured acceleration of H₂O⁺ downthe ion tail was much smaller than in comet Halley. Tailwardextensions in the azimuthal distributions of OH 3080 Å,[O I], and [C I] , as well as a Doppler asymmetry in the[O I] line profile, suggest ion-neutral coupling. While thetailward extension in the OH can be explained by increased neutralacceleration, the [O I] 6300 Å and [C I] 9850 Å emissions show 13%and >200% excesses in this direction (respectively), suggesting anon-negligible contribution from dissociative recombination of CO⁺and/or electron collisional excitation. Thus, models including theeffects of photo- and collisional chemistry are necessary for the fullinterpretation of these data.