Streams in the Harz National Parks (Germany) — a hydrochemical and hydrobiological evaluation

Between 1995 and 2001, 16 measuring points at small and medium sized brooks in the Harz National Parks were sampled. The samples have been evaluated by means of hydrochemistry and macroinvertebrate biology. Although nearly all streams are largely uncontaminated by oxygen-consuming substances, they are settled only by a small number of macroinvertebrate species. There is a clear correlation between this number and pH. The reduction in species number with decrease of pH is mainly caused by the absence of most Ephemeroptera, some Coleoptera and Trichoptera. Comparing biological evaluation of acidity with physico-chemical measurements, a unacceptable underestimation was found. The reason could be that different sensitivities to acidification between regional populations seem to exist.

Despite of the low species number, there is a very specific macroinvertebrate fauna that emphasizes the conservation value of the Harz National Parks.     

Dust emission by off-road driving: Experiments on 17 arid soil types, Nevada, USA

Field experiments were conducted in Nellis Dunes Recreational Area (Clark County, Nevada, USA) to investigate emission of dust produced by off-road driving. Experiments were carried out with three types of vehicles: 4-wheelers (quads), dirt bikes (motorcycles) and dune buggies, on 17 soil types characteristic for a desert environment. Tests were done at various driving speeds, and emissions were measured for a large number of grain size fractions. This paper reports the results for two size fractions of emissions: PM10 (particles < 10 μm) and PM60 (particles < 60 μm). The latter was considered in this study to be sufficiently representative of the total suspendable fraction (TSP). Off-road driving was found to be a significant source of dust. However, the amounts varied greatly with the type of soil and the characteristics of the top layer. Models predicting emission of dust by off-road driving should thus consider a number of soil parameters and not just one key parameter. Vehicle type and driving speed are additional parameters that affect emission. In general, 4-wheelers produce more dust than dune buggies, and dune buggies, more than dirt bikes. Higher speeds also result in higher emissions. Dust emitted by off-road driving is less coarse than the parent sediment on the road surface. Off-road driving thus results in a progressive coarsening of the top layer. Exceptions to this are silty surfaces with no, or almost no, vegetation. For such surfaces no substantial differences were observed between the grain size distribution of road dust and emitted dust. Typical emission values for off-road driving on dry desert soils are: for sandy areas, 30–40 g km^− 1 (PM10) and 150–250 g km^− 1 (TSP); for silty areas, 100–200 g km^− 1 (PM10) and 600–2000 g km^− 1 (TSP); for drainages, 30–40 g km^− 1 (PM10) and 100–400 g km^− 1 (TSP); and for mixed terrain, 60–100 g km^− 1 (PM10) and 300–800 g km^− 1 (TSP). These values are for the types of vehicles tested in this study and do not refer to cars or trucks, which produce significantly more dust.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Distribution, characterization, and geochemical controls of elements of concern in uranium mine tailings, Key Lake, Saskatchewan, Canada

The distribution of As, Mo, Ni and Se in the aqueous and solid phases of U mine tailings in the Deilmann Tailings Management Facility (DTMF), located at the Key Lake mine in northern Saskatchewan, Canada, was defined using as-discharged tailings samples collected monthly starting in 1996 and core samples collected from the DTMF from 3 locations on 3 occasions between 2004 and 2009. These data indicated that the DTMF can be divided into two geochemical zones; tailings generated from the Deilmann ore body between 1996 and 2000 and tailings from the McArthur River ore body, mined after July 2000. The Deilmann tailings solids are generally characterized by greater elemental concentrations than those in the McArthur River tailings, particularly for As, Co and Ni. These elevated concentrations are attributed to the abundance of Ni–Co–As–S minerals in this ore. The mean aqueous concentrations of As, Mo, Ni, and Se are 3.7, 23.2, 0.14, and 0.02 mg L⁻¹, respectively, in the Deilmann porewaters and 0.20, 4.16, 0.06, and 0.03 mg L⁻¹, respectively, in the McArthur River porewaters. Similarly, the mean As, Mo, Ni, and Se solid phase concentrations are 5.89 × 10³, 69.9, 3.20 × 10³, and 17.4 μg g⁻¹, respectively, for the Deilmann tailings and 440, 13.6, 551, and 3.03 μg g⁻¹ in the McArthur River tailings. Statistically, pH remained unchanged from the time of discharge while Eh values have remained oxic with no significant change between the two tailings types over 15 a of residence time. Results from sequential extractions, thermodynamic modeling, and results of complimentary research indicated that ferrihydrite solubility is the dominant control on aqueous As concentrations and also plays a role in controlling dissolved Mo, Ni and Se.     

Colloidal arsenic composition from abandoned gold mine tailing leachates in Nova Scotia,Canada

Asymmetric-Flow Field-Flow Fractionation (AsFlFFF) coupled to an inductively coupled plasma-mass spectrometer (ICP-MS) was used to determine whether colloidal As exists in mine tailings from abandoned Au mine sites in Nova Scotia. Using this technique, the chemical composition and the size of the colloidal material was determined. Tailings samples were collected from the sites and leachates were analyzed. The resulting fractograms showed the presence of colloidal As. Arsenic co-elutes with Fe and Al suggesting that the As is associated with colloids containing these elements. The colloidal material present in the samples has a calculated median size of 7 nm. The leachates were also analyzed for totalAs, Fe and Al using ICP-MS. The colloidal fraction was determined to account for approximately 20% of the total dissolved As present in these samples. Dissolved As concentrations at the selected mine sites are very high and the arbitrary cutoff for dissolved still incorporates colloidal material. Therefore. it is important to distinguish between truly dissolved and colloidal As as the speciation will affect the toxicity and mobility of As at these locations.     

The Summer Surface Energy Balance of the High Antarctic Plateau

The summertime surface energy balance (SEB) at Kohnen station, situated on the high Antarctic plateau (75°00′ S, 0°04′ E, 2892m above sea level) is presented for the period of 8 January to 9 February 2002. Shortwave and longwave radiation fluxes were measured directly; the former was corrected for problems associated with the cosine response of the instrument. Sensible and latent heat fluxes were calculated using the bulk method, and eddy-correlation measurements and the modified Bowen ratio method were used to verify these calculated fluxes. The calculated sub-surface heat flux was checked by comparing calculated to measured snow temperatures. Uncertainties in the measurements and energy-balance calculations are discussed. The general meteorological conditions were not extraordinary during the period of the experiment, with a mean 2-m air temperature of −27.5°C, specific humidity of 0.52×10⁻³kg kg⁻¹ and wind speed of 4.1ms⁻¹. The experiment covered the transition period from Antarctic summer (positive net radiation) to winter (negative net radiation), and as a result the period mean net radiation, sensible heat, latent heat and sub-surface heat fluxes were small with values of −1.1, 0.0, −1.0 and 0.7 Wm⁻², respectively. Daily mean net radiation peaked on cloudy days (16 Wm⁻²) and was negative on clear-sky days (minimum of −19 W m⁻²). Daily mean sensible heat flux ranged from −8 to +10 Wm⁻², latent heat flux from −4 to 0 Wm⁻² and sub-surface heat flux from −8 to +7 Wm⁻².     

The Deformational Response of a Viscoelastic Solid Earth Model Coupled to a Thermomechanical Ice Sheet Model

We apply a coupled thermomechanical ice sheet—self-gravitating viscoelastic solid Earth model (SGVEM), allowing for the dynamic exchange of ice thickness and bedrock deformation, in order to investigate the effect of viscoelastic deformation on ice dynamics and vice versa. In a synthetic glaciation scenario, we investigate the interaction between the ice sheet and the solid Earth deformation, the glacial-isostatic adjustment (GIA), accounting for an atmospheric forcing depending on the ice sheet surface altitude. We compare the results from the coupled model to runs with the common elastic lithosphere/relaxing asthenosphere (ELRA) model, where the lithosphere is represented by a thin plate and the mantle relaxes with one characteristic relaxation time, as well as to a rigid Earth without any deformation. We find that the deformational behaviour of the SGVEM on ice dynamics (i.e. stored ice volume, ice thickness and velocity field) is comparable to the ELRA for an optimal choice of the parameters in steady state, but exhibits differences in the transient behaviour. Beyond the ice sheet, in the region of peripheral forebulge, the differences in the transient surface deformation between ELRA and SGVEM are substantial, demonstrating the inadequacy of the ELRA model for interpreting constraints on GIA in the periphery of the ice sheet, such as sea-level indicators and GPS uplift rates.     

Functioning of intertidal flats inferred from temporal and spatial dynamics of O<Subscript>2</Subscript>, H<Subscript>2</Subscript>S and pH in their surface sediment

In this article, we describe the dynamics of pH, O₂ and H₂S in the top 5–10 cm of an intertidal flat consisting of permeable sand. These dynamics were measured at the low water line and higher up the flat and during several seasons. Together with pore water nutrient data, the dynamics confirm that two types of transport act as driving forces for the cycling of elements (Billerbeck et al. 2006b): Fast surface dynamics of pore water chemistry occur only during inundation. Thus, they must be driven by hydraulics (tidal and wave action) and are highly dependent on weather conditions. This was demonstrated clearly by quick variation in oxygen penetration depth: Seeps are active at low tide only, indicating that the pore water flow in them is driven by a pressure head developing at low tide. The seeps are fed by slow transport of pore water over long distances in the deeper sediment. In the seeps, high concentrations of degradation products such as nutrients and sulphide were found, showing them to be the outlets of deep-seated degradation processes. The degradation products appear toxic for bioturbating/bioirrigating organisms, as a consequence of which, these were absent in the wider seep areas. These two mechanisms driving advection determine oxygen dynamics in these flats, whereas bioirrigation plays a minor role. The deep circulation causes a characteristic distribution of strongly reduced pore water near the low water line and rather more oxidised sediments in the centre of the flats. The two combined transport phenomena determine the fluxes of solutes and gases from the sediment to the surface water and in this way create specific niches for various types of microorganisms.