Application of226Ra,228Ra,223Ra, and224Ra in coastal waters to assessing coastal mixing rates and groundwater discharge to oceans

The fate of dissolved material delivered to the coastal ocean depends on its reactivity and the rate at which it is mixed offshore. To measure the rate of exchange of coastal waters, we employ two short-lived radium isotopes,²²³Ra and²²⁴Ra. Along the coast of South Carolina, shore-perpendicular profiles of²²³Ra and²²⁴Ra in surface waters show consistent gradients which may be modeled to yield eddy diffusion coefficients of 350–540 m²s⁻¹. Coupling the exchange rate with offshore concentration gradients yields estimates of offshore fluxes of dissolved materials. For systems in steady state, the offshore fluxes must be balanced by new inputs from rivers, groundwater, sewers or other sources. Two tracers that show promise in evaluating groundwater input are barium and²²⁶Ra. These tracers have high relative concentrations in the fluids and low-reactivity in the coastal ocean. Applying the eddy diffusion coefficients to the offshore gradient of²²⁶Ra concentration provides an estimate of the offshore flux of²²⁶Ra. Measuring the concentrations of²²⁶Ra in subsurface fluids provides an estimate of the fluid flux necessary to provide the²²⁶Ra. These estimates indicate that the volume of groundwater required to support these fluxes is of the order of 40% of the surface water flow.     

Fluxes and behavior of radium isotopes, barium, and uranium in seven Southeastern US rivers and estuaries

This paper demonstrates the importance of advective transport of water through permeable estuarine and salt marsh sediments. This transport delivers significant quantities of radium and barium to the coastal ocean; and, in some cases may remove significant quantities of uranium. These conclusions are based on repeated analyses of seven river–estuarine systems from North Carolina to Florida. Fluxes of radium and barium from these river systems are shown to be inadequate to balance the dissolved inventories of these elements in the South Atlantic Bight. The strong interactions that occur between surface and subsurface waters as these rivers encounter coastal marshes lead us to consider these river mouths as marsh-dominated in terms of their chemical fluxes to the ocean. Such interactions between the river and coastal marsh must be considered when estimating fluxes of material between the land and ocean.     

ENSO,the IOD and the intraseasonal prediction of heat extremes across Australia using POAMA-2

The simulation and prediction of extreme heat over Australia on intraseasonal timescales in association with the El Niño–Southern Oscillation (ENSO) and the Indian Ocean Dipole (IOD) is assessed using the Bureau of Meteorology’s Predictive Ocean Atmosphere Model for Australia (POAMA). The analysis is based on hindcasts over 1981–2010 and focuses on weeks 2 and 3 of the forecasts, i.e. beyond a typical weather forecast. POAMA simulates the observed increased probabilities of extreme heat during El Niño events, focussed over south eastern and southern Australia in SON and over northern Australia in DJF, and the decreased probabilities of extreme heat during La Niña events, although the magnitude of these relationships is smaller than observed. POAMA also captures the signal of increased probabilities of extreme heat during positive phases of the IOD across southern Australia in SON and over Western Australia in JJA, but again underestimates the strength of the relationship. Shortcomings in the simulation of extreme heat in association with ENSO and the IOD over southern Australia may be linked to deficiencies in the teleconnection with Indian Ocean SSTs. Forecast skill for intraseasonal episodes of extreme heat is assessed using the Symmetric Extremal Dependence Index. Skill is highest over northern Australia in MAM and JJA and over south-eastern and eastern Australia in JJA and SON, whereas skill is generally poor over south-west Western Australia. Results show there are windows of forecast opportunity related to the state of ENSO and the IOD, where the skill in predicting extreme temperatures over certain regions is increased.     

Antarctic tourism and environmental concerns

Increasing numbers of tourists are visiting the Antarctic. Totals from the past three seasons (1989–1990, 1990–1991, 1991–1992) were 2581, 4842, and 6495 respectively (Enzenbacher, 1992). Some environmental issues arising from Antarctic tourist activity include: wildlife tolerance, waste disposal, passenger education, tour operator management practices, personnel experience, frequency of visits and ship design. Current guidelines provide a practical approach to tourism, but do not address all issues arising from tourist activity. Antarctic Treaty Parties agreed to examine the question of a comprehensive regulation of tourist activities in the Antarctic Treaty Area and policies are under review. Some issues may prove difficult to resolve. Compliance with existing guidelines is to be encouraged, at least until more is known about the environmental effects of tourism. A management plan for tourism is needed along with more research on how tourism is conducted and the effects visits have on Antarctica's marine and terrestrial ecosystems. Cooperation between Treaty Parties and tour operators is important for the development of appropriate tourism regulations.     

Fluxes of uranium and thorium series isotopes in the Santa Barbara Basin

Samples from the MANOP Santa Barbara Basin sediment trap intercomparison were analyzed for the isotopes of uranium, thorium, radium, lead, and polonium. All of the traps showed approximately the same compositions and isotopic ratios, indicating that they trapped similar materials. The²³⁴Th flux via falling particles was very close to the flux predicted from the production and scavenging rates of²³⁴Th from the water column. The²¹⁰Pb content of the trapped particles and the surface sediments were the same, however, the measured flux of²¹⁰Pb was seven times greater than the predicted flux. Predicted and measured fluxes of²²⁸Th and²¹⁰Po were similarly out of balance. To explain this apparent inconsistency, we suggest (as others have done) that the Santa Barbara Basin is an area where scavenging from the water column is intensified and where sediments deposited initially on the margins may be physically remobilized on a short time scale. These two effects increase the apparent area from which the basin derives the longer-lived isotopes but does not increase significantly the supply of the short-lived²³⁴Th.     

226Ra behavior in the Pee Dee River-Winyah Bay estuary

Concentrations of dissolved²²⁶Ra in Winyah Bay, South Carolina, and in the adjacent Atlantic Ocean are augmented by the desorption of radium from sediments in the low-salinity area of the estuary and diffusion from bottom sediments. Desorption of²²⁶Ra is reflected by lower concentrations in suspended sediments from higher-salinity regions of the estuary. Bottom sediments from the high-salinity region have lower²²⁶Ra/²³⁰Th activity ratios than those from the low-salinity end.The shape of the dissolved²²⁶Ra vs. salinity profile is influenced by the river discharge. During average-discharge conditions, desorption of²²⁶Ra from suspended and bottom sediments increases the dissolved²²⁶Ra concentrations by a factor of 3.5 as the water passes through Winyah Bay. High river discharge produces an initial increase of dissolved²²⁶Ra by a factor of 2 to 3 and apparently reflects only desorption from suspended sediments. By driving the salt wedge down the estuary and reducing the zone of contact of salt water with bottom sediments, the high-flow conditions sharply reduce the flux of²²⁶Ra from bottom sediments.     

A geostatistically based inverse model for three-dimensional variably saturated flow

We present a geostatistically based inverse model for characterizing heterogeneity in parameters of unsaturated hydraulic conductivity for three-dimensional flow. Pressure and moisture content are related to perturbations in hydraulic parameters through cross-covariances, which are calculated to first-order. Sensitivities needed for covariance calculations are derived using the adjoint state sensitivity method. Approximations of the conditional mean parameter fields are then obtained from the cokriging estimator. Correlation between parameters and pressure – moisture content perturbations is seen to be strongly dependent on mean pressure or moisture content. High correlation between parameters and pressure data was obtained under saturated or near saturated flow conditions, providing accurate estimation of saturated hydraulic conductivity, while moisture content measurements provided accurate estimation of the pore size distribution parameter under unsaturated flow conditions.     

Sea level events and Pleistocene coral ages in the northern Bahamas

Emergent Pleistocene sea level indicators in the northern Bahamas include: a bioerosional notch at +5.3 to 5.9 m; sea caves, notches, and marine terraces at about +4.3 m; and lithified coral rubble and reef deposits between 0 and 3 m. Thorium 230 dates of the fossil corals, which were deposited as these features were being produced, span the age range from 100 to 145 thousand years BP with a majority falling between 115 and 130 thousand years BP. The notch at about +5.6 m is interpreted to be the product of a sea level stand 125 thousand years BP, while the features at +4.3 m are believed to be formed sometime later as sea level fell from the higher position. Part of the age span is inherent in the dating technique and possible sample alteration. Another cause of the spread may be mixing of corals of different ages into a single deposit.