Occurrence of noble metals in aluminum- and chromium- rich objects in ordinary chondrites and of baddeleyite (ZrO2) in a chromite inclusion

Abstract— Platinum group elements (PGE) enrichments are found in Fe-Ni blebs (<1 μm) in Al- and Cr-rich objects in the ordinary chondrites Ste. Marguerite, Forest Vale, Montferré. In Ste. Marguerite, high ZrO₂ concentrations (baddeleyite) are also present in a chromite inclusion. Iridium enrichment in this material compared to its metal content is confirmed by INAA. The widespread occurrence of PGE in Al- and Cr-rich objects, mostly present in H-group chondrites of nearly equilibrated types, must be taken into account to understand their conditions of formation.     

Dahmani,a highly oxidised LL6 chondrite bearing Ni-rich taenite

Abstract Dahmani is a shocked LL6 fragmental breccia. According to the composition of the silicates (olivine Fa_30,32.6, orthopyroxene Fs_24.5–26.3) and of the metal (a 60% Ni taenite) it is one of the most oxidised known.     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

Pico- and Nanophytoplankton Dynamics in Two Coupled but Contrasting Coastal Bays in the NW Mediterranean Sea (France)

Due to its ecological context, the Toulon bay represents a site of scientific interest to study temporal plankton distribution, particularly pico- and nanophytoplankton dynamics. A monthly monitoring was performed during a two-year cycle (October 2013–December 2015) at two coupled sampling sites, referred to as Little and Large bays, which had different morphometric characteristics and human pressures. Flow cytometry analyses highlighted the fact that pico- and nanophytoplankton were more abundant in the eutrophic Little bay. Furthermore, it evidenced two community structures across the Toulon bays: at times, a co-dominance of picoeukaryotes, nanoeukaryotes, Synechococcus 1-like cells and Prochlorococcus-like cells was found, and at other times, a Synechococcus 1-like dominated community existed. The alternation of one structure or the other can be explained by a combined action of temperature regime, nutrient conditions and degree of contamination. This study showed that pico- and nanophytoplankton dynamics were mainly driven by temperature in both sites, as in other temperate Mediterranean regions. Thus, the community was mainly composed of picoeukaryotes and Prochlorococcus-like cells in the winter (<?15 °C), while it was dominated by Synechococcus 1-like cells in the summer (>?20 °C). Additionally, the multiple human stressors in the Little bay seemed to affect the increase in abundance of Synechococcus 1-like cells as they were preferentially observed in the Large bay.     

Prediction of the calcium carbonate budget in a sedimentary basin: A “source-to-sink” approach applied to Great Salt Lake,Utah, USA

Most source-to-sink studies typically focus on the dynamics of clastic sediments and consider erosion, transport and deposition of sediment particles as the sole contributors. Although often neglected, dissolved solids produced by weathering processes contribute significantly in the sedimentary dynamics of basins, supporting chemical and/or biological precipitation. Calcium ions are usually a major dissolved constituent of water drained through the watershed and may facilitate the precipitation of calcium carbonate when supersaturating conditions are reached. The high mobility of Ca²⁺ ions may cause outflow from an open system and consequently loss. In contrast, in closed basins, all dissolved (i.e. non-volatile) inputs converge at the lowest point of the basin. The endoreic Great Salt Lake basin constitutes an excellent natural laboratory to study the dynamics of calcium on a basin scale, from the erosion and transport through the watershed to the sink, including sedimentation in lake's waterbody. The current investigation focused on the Holocene epoch. Despite successive lake level fluctuations (amplitude around 10 m), the average water level seems to have not been affected by any significant long-term change (i.e. no increasing or decreasing trend, but fairly stable across the Holocene). Weathering of calcium-rich minerals in the watershed mobilizes Ca²⁺ ions that are transported by surface streams and subsurface flow to the Great Salt Lake (GSL). Monitoring data of these flows was corrected for recent anthropogenic activity (river management) and combined with direct precipitation (i.e. rain and snow) and atmospheric dust income into the lake, allowing estimating the amount of calcium delivered to the GSL. These values were then extrapolated through the Holocene period and compared to the estimated amount of calcium stored in GSL water column, porewater and sediments (using hydrochemical, mapping, coring and petrophysical estimates). The similar estimate of calcium delivered (4.88 Gt) and calcium stored (3.94 Gt) is consistent with the premise of the source-to-sink approach: a mass balance between eroded and transported compounds and the sinks. The amount of calcium deposited in the basin can therefore be predicted indirectly from the different inputs, which can be assessed with more confidence. When monitoring is unavailable (e.g. in the fossil record), the geodynamic context, the average lithology of the watershed and the bioclimatic classification of an endoreic basin are alternative properties that may be used to estimate the inputs. We show that this approach is sufficiently accurate to predict the amount of calcium captured in a basin and can be extended to the whole fossil record and inform on the storage of calcium.     

Erosion rates and sediment budgets in vineyards at 1-m resolution based on stock unearthing (Burgundy, France)

A new and simple method is developed to efficiently quantify erosion and deposition rates based on stock unearthing measurements. This is applicable to spatial scales ranging from plot to hillslopes, and to time scales ranging from single hydrologic events to centennial scales. The method is applied to a plot area on vineyard hillslopes in Burgundy (Monthélie, France), with measurement of 4328 vine plants. A sediment budget established at the plot scale shows a mean soil lowering of 3.44 ± 1 cm over 20 years, involving a minimal erosion rate of 1.7 ± 0.5 mm yr^− 1. Locally, erosion rates can reach up to 8.2 ± 0.5 mm yr^− 1.This approach allows the sediment redistribution to be mapped and analyzed at 1-m resolution. It provides novel insights into the characterization of erosion patterns on pluri-decennial scales and into the analysis of spatial distribution of erosion processes on cultivated hillslopes.     

Stratigraphic modelling of platform architecture and carbonate production: a Messinian case study (Sorbas Basin,SE Spain)

The late Messinian mixed carbonate‐siliciclastic platforms of the Sorbas Basin, known as the Terminal Carbonate Complex, record significant changes in carbonate production and geometry. Their facies and stratigraphic architecture result from complex interactions between base‐level fluctuations, evaporite deformation/dissolution and detrital inputs. A 3D quantitative approach (with DIONISOS software) is used to explore the basin‐scale platform architecture and to quantify the carbonate production of the Terminal Carbonate Complex. The modelling strategy consists in integrating detailed 2D field‐based transects and modern carbonate system parameters (e.g. carbonate production rates, bathymetric and hydrodynamic ranges of production). This approach limits user impact and so provides more objective output results. Tests are carried out on carbonate production rates, subsidence and evaporite deformation/dissolution. Numerical modelling provides accurate predictions of geometries, facies distributions and depositional sequence thicknesses, validated by field data. Comparative statistical testing of the field transects and of the various model outputs are used to discern the relative contribution of the parameters tested to the evolution of basin filling. The 3D visualization and quantification of the main carbonate producers (ooids and microbialites) are discussed in terms of changes in base‐level and detrital supply. This study demonstrates that base‐level fluctuations have the greatest impact on the carbonate budget. Evaporite deformation/dissolution affects the type and amount of carbonate production, inducing a transition from an ooid‐ to microbialite‐dominated system and also has a major effect on stratigraphic architecture by inducing the migration of depocentres. The numerical modelling results obtained using modern carbonate system parameters could also be applied to subsurface ooid‐microbialite reservoirs, and the Terminal Carbonate Complex is a good analogue for such systems.     

Growth fold controls on carbonate distribution in mixed foreland basins: insights from the Amiran foreland basin (NW Zagros,Iran) and stratigraphic numerical modelling

The evolution from Late Cretaceous to early Eocene of the well dated Amiran foreland basin in the NW Iranian Zagros Mountains is studied based on the reconstruction of successive thickness, palaeobathymetry and subsidence maps. These maps show the progressive forelandwards migration of the mixed carbonate‐siliciclastic system associated with a decrease in creation of accommodation. Carbonate facies variations across the basin suggest a structural control on the carbonate distribution in the Amiran foreland basin, which has been used as initial constraint to study the control exerted by syndepositional folding in basin architecture and evolution by means of stratigraphic numerical modelling. Modelled results show that shallow bathymetries on top of growing folds enhance carbonate production and basin compartmentalization. As a consequence, coarse clastics become restricted to the internal parts of the basin and only the fine sediments can by‐pass the bathymetric highs generated by folding. Additionally, the development of extensive carbonate platforms on top of the anticlines favours the basinwards migration of the depositional system, which progrades farther with higher fold uplift rates. In this scenario, build‐ups on top of anticlines record its growth and can be used as a dating method. Extrapolation of presented modelling results into the Amiran foreland basin is in agreement with an early folding stage in the SE Lurestan area, between the Khorramabad and Kabir Kuh anticlines. This folding stage would enhance the development of carbonate platforms on top of the anticlines, the south‐westward migration of the system and eventually, the complete filling of the basin north of the Chenareh anticline at the end of the Cuisian. Incremental thickness maps are consistent with a thin (0.4–2 km) ophiolite complex in the source area of the Amiran basin.