Pyrolisis of phosphorylated molecules and survivability limits during the atmospheric passage in earth-like planets

There is evidence that space energy sources could give place to the appearance of phosphorylated nucleosides outside of Earth. These compounds may have been delivered mainly by interplanetary dust particles due to the lower temperatures experienced during atmospheric deceleration and impacts to the terrestrial surface. In this report, we communicate the results of pyrolytic studies to simulate atmospheric survivability of adenosine-5′-diphosphates (ADP) (and adenosine-5′-monophosphate, adenosine and adenine as degradation products) at temperatures <500°C and at various time intervals. Our results revealed that phosphorylated and non-phosphorylated nucleosides transported by IDPs having sizes of 10⁻⁶- could resist temperatures up to 500°C generated during atmospheric entry. However, atmospheric passage should not exceed a time due to the thermal lability of these molecules. Because of the high half-life showed by ADP in the presence of meteoritic powder, it is thought that extraterrestrial delivery of very complex biomolecules is more suitable under such protected conditions. These data indicate that the formation of a Fe²⁺- and/or Ca²⁺-complex could increase the stability of the molecules in the presence of meteoritic matter. Therefore, if the synthesis of nucleosides, nucleotides or oligonucleotides could take place in icy bodies, then micron-sized dust could have contributed significantly to the availability of phosphorylated nucleosides in the early Earth or in extrasolar early Earth-like planets, and thereby could have allowed the arising of an early biological activity.     

Effect of clouds on UV and total irradiance at Paradise Bay, Antarctic Peninsula, from a summer 2000 campaign

Summary ?The analysis of ground-based measurements of solar erythemal ultraviolet (UV) irradiance with a Solar Light 501 biometer, and total (300–3000 nm) irradiance with an Eppley B&W pyranometer at the Argentine Antarctic Base “Almirante Brown”, Paradise Bay (64.9° S, 62.9° W, 10 m a.s.l.) is presented. Measurement period extends from February 16 to March 28 2000. A relatively high mean albedo and a very clean atmosphere characterise the place. Sky conditions were of generally high cloud cover percentage. Clear-sky irradiance for each day was estimated with model calculations, and the effect of the cloudiness was studied through the ratio of measured to clear-sky value (r). Two particular cases were analysed: overcast sky without precipitation and overcast sky with rain or slight snowfall, the last one presenting frequently dense fog. Total irradiance was more attenuated than UV by the homogeneous cloudiness, obtaining mean r values of 0.54 for erythemal irradiance and 0.30 for total irradiance in the first case (without precipitation) and 0.27 and 0.17 respectively in the second case (with precipitation). Mean r values for the complete period were 0.58 for erythemal irradiance and 0.43 for total irradiance. Erythemal and total daily insolations reduce quickly at this epoch due to the increase of the noon solar zenith angle and the decrease of daylight time. Additionally, they were strongly modulated by cloudiness. Measured maxima were 2.71 kJ/m² and 18.42 MJ/m² respectively. Measurements were compared with satellite data. TOMS-inferred erythemal daily insolation shows the typical underestimation with respect to ground measurements at regions of high mean albedo. Measured mean total daily insolation agrees with climatological satellite data for the months of the campaign. Received August 9, 2002; revised January 4, 2003; accepted January 28, 2003 Published online May 20, 2003     

Geochemical fractionation of manganese in the Riogrande II reservoir, Antioquia, Colombia

The Riogrande II reservoir in Colombia has a total storage capacity of 240 million m³ and lies 2,270 m above sea level. The reservoir is used for power generation, water supply and environmental improvement. Dissolved manganese (Mn) is removed from reservoir water dedicated to domestic use by purification processes. Removal of Mn, however, poses a major challenge to purification processes and warrants the study of ways to naturally reduce dissolved Mn levels in the reservoir. The source of Mn within the reservoir is not well understood, however, presumably arises from sediment mobilization initiated by variation in pH, redox potential (ORP or Eh), dissolved oxygen (O₂) and ionic strength conditions. This study investigated conditions within the reservoir to further understand Mn transfer from the sediment into the water column. O₂, pH, oxidation–reduction potential (ORP or Eh), organic matter content and electric conductivity were measured in water samples and sediment from the reservoir. Sequential extraction (SE) procedures were used to test the specific effects exerted by each of these conditions on Mn mobilization from the sediments. The European Community Bureau of Reference (BCR) sequential extraction procedure was used to quantify metals in sediment (referred to as the BCR extraction below). Statistical analysis of geochemical data from water samples (both water column and sediment pore water) and sediments demonstrated the conditions under which Mn can be released from sediments into the water column. The results indicated a primarily oxic water column and anoxic reducing conditions in the sediment (ORP or Eh ≤ ?80 mV). The pH of water in contact with bottom sediments varied from 7.6 to 6.8. The pH of sedimentary pore water varied from 6.8 to 4.7. The sediments contained significant amounts of organic matter (20 %). Chemical extractions showed that the exchangeable fraction contained over 50 % of the total Mn within sediments. Microscopic analysis using scanning electron microscopy–energy dispersive spectroscopy (SEM–EDS) indicated that Mn does not occur within well-crystallized mineral phases in the Riogrande II sediments. A large proportion of Mn exists instead as material adsorbed onto the surfaces of recently deposited sediment particles. Bacterial oxidation of organic matter may cause the observed anoxic conditions at the bottom of the reservoir. Mineralization of organic matter therefore contributes to reducing conditions within the sediments. Mobilization of Mn from the sediment into the water column may result from reductive dissolution of this fraction. Manganese release by this mechanism diminishes the water quality of the Riogrande II reservoir and warrants further study.     

Predicting monthly precipitation along coastal Ecuador: ENSO and transfer function models

Theoretical and Applied Climatology - It is well known that El Niño-Southern Oscillation (ENSO) modifies precipitation patterns in several parts of the world. One of the most impacted areas is...