Leaching mechanisms of oxyanionic metalloid and metal species in alkaline solid wastes: A review

An overview is presented on possible mechanisms that control the leaching behaviour of the oxyanion forming elements As, Cr, Mo, Sb, Se, V and W in cementituous systems and alkaline solid wastes, such as municipal solid waste incinerator bottom ash, fly ash and air pollution control residues, coal fly ash and metallurgical slags. Although the leachability of these elements generally depends on their redox state, speciation measurements are not common. Therefore, experimental observations available in the literature are combined with a summary of the thermal behaviour of these elements to assess possible redox states in freshly produced alkaline wastes, given their origin at high temperature. Possible redox reactions occurring at room temperature, on the other hand, are reviewed because these may alter the initial redox state in alkaline wastes and their leachates. In many cases, precipitation of oxyanions as a pure metalate cannot provide a satisfactory explanation for their leaching behaviour. It is therefore highly likely that adsorption and solid solution formation with common minerals in alkaline waste and cement reduce the leachate concentration of oxyanions below pure-phase solubility.     

Distribution and Abundance of Arsenic in the Soils and Sediments of O‘ahu,Hawai‘i

Lack of high-spatial-resolution soil and sediment arsenic data for Hawai‘i has generated substantial disagreement between researchers and regulators regarding the magnitude of natural levels of arsenic in Hawai‘i and rendered difficult the defining of areas of anthropogenically elevated arsenic. Our earlier research into the occurrence of arsenic in terrestrial and marine environments revealed widely disparate concentrations of arsenic with no apparent spatial pattern. To better understand the distribution and abundance of arsenic in soils and sediments of O‘ahu, we collected an additional 64 samples at locations chosen to represent different environments with varying degrees of human impact. We found surface arsenic values that ranged from 0.28 to 740 ppm with a median concentration of 8.1 ppm, which is above the global median of 5 ppm and US soil median of 5.2 ppm. Higher concentrations of arsenic (up to 913 ppm) were encountered at depth in soil cores. The median arsenic in streambed sediments from one of our earlier studies of 6.1 ppm was comparable to the conterminous US median of 6.3 ppm; however, we encountered arsenic concentrations as high as 43.9 ppm (median = 8.60 ppm, n = 75) in marine sediments in recent work off the leeward coast of O‘ahu. Overall, arsenic in the soils and sediments of O‘ahu is elevated relative to world and national values, but there still is no readily discernible pattern in the distribution of arsenic to explain these elevated values.     

Rappresentazioni parziali e totali dell’ellissoide di rotazione sulla sfera

Riassunto L’A., partendo dall’idea di minimizzare l’energia di deformazione della rete geografica ellissoidica, supposta elastica, per adattarla a una sfera, determina una corrispondenza fra l’ellissoide di rotazione e la sfera locale in un intorno del punto di osculazione fino a 250 km di raggio. Ne risultano semplici formule per le correzioni angolari ai limiti dell’intorno e per la trasformazione delle coordinate. Successivamente l’A. sottopone a un esame critico varie funzioni che, estremate, dànno luogo a buone rappresentazioni dell’intero ellissoide sulla sfera ed introduce una nuova latitudine, utile per la costruzione di carte geografiche globulari, che risulta media fra la latitudine geocentrica e quella ridotta.

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Summary The Author, starting from the idea of minimizing the deformation energy of the ellipsoidic geographical network, which he supposes to be perfectly elastic in order to adapt it to a sphere, determines a correspondence between the rotation ellipsoid and the local sphere in the neighbourhood of the osculation point, to the distance of 250 km. He hereby deduces simple formulas for the angular corrections in the border of the neighbourhood and for appropriate transformation of coordinates. In the second part the A. takes into critical examination some functions, which, minimized, afford good representation of the whole ellipsoid on the sphere; he also introduces a new latitude that is revealed useful for the construction of globular geographical maps and numerically can be considered as a mean between the geocentric latitude and the reduced one.

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Dr.Carlo Bernasconi, Istituto Geofisico e Geodetico dell’Università diGenova.     

Integration of earth observation and census data for mapping a multi-temporal flood vulnerability index: a case study on Northeast Italy

Climate sciences foresee a future where extreme weather events could happen with increased frequency and strength, which would in turn increase risks of floods (i.e. the main source of losses in the world). The Mediterranean basin is considered a hot spot in terms of climate vulnerability and risk. The expected impacts of those events are exacerbated by land-use change and, in particular, by urban growth which increases soil sealing and, hence, water runoff. The ultimate consequence would be an increase of fatalities and injuries, but also of economic losses in urban areas, commercial and productive sites, infrastructures and agriculture. Flood damages have different magnitudes depending on the economic value of the exposed assets and on level of physical contact with the hazard. This work aims at proposing a methodology, easily customizable by experts’ elicitation, able to quantify and map the social component of vulnerability through the integration of earth observation (EO) and census data with the aim of allowing for a multi-temporal spatial assessment. Firstly, data on employment, properties and education are used for assessing the adaptive capacity of the society to increase resilience to adverse events, whereas, secondly, coping capacity, i.e. the capacities to deal with events during their manifestation, is mapped by aggregating demographic and socio-economic data, urban growth analysis and memory on past events. Thirdly, the physical dimension of exposed assets (susceptibility) is assessed by combining building properties acquired by census data and land-surface characteristics derived from EO data. Finally, the three components (i.e. adaptive and coping capacity and susceptibility) are aggregated for calculating the dynamic flood vulnerability index (FVI). The approach has been applied to Northeast Italy, a region frequently hit by floods, which has experienced a significant urban and economic development in the past decades, thus making the dynamic study of FVI particularly relevant. The analysis has been carried out from 1991 to 2016 at a 5-year steps, showing how the integration of different data sources allows to produce a dynamic assessment of vulnerability, which can be very relevant for planning in support of climate change adaptation and disaster risk reduction.

     

A land-use-based modelling chain to assess the impacts of Natural Water Retention Measures on Europe’s Green Infrastructure

This article details the process of integrating models to answer a specific policy-driven question: ‘What could be the impact of proposed Natural Water Retention Measures (NWRMs) on Europe’s Green Infrastructure (GI)?’ It describes the new Land Use Modelling Platform (LUMP), now enabling a high spatial scale (100-m) and large coverage (pan-European), whereby several sector-specific models contribute to assessing the impact of regional-level policy on a given spatial topic of concern. The configuration (land claims and land allocations modules) and calibration (accessibility and biophysical suitability) of the LUMP are explained. Four NWRM scenarios (riparian areas, afforestation, grassland and baseline scenario) are configured to run the simulations. For the reference: year 2006, the spatial representation of GI is based on land-use features of a refined version of the CORINE Land Cover (CLC), and resumed as connected components made of nodes and links.

Mathematical morphological image processing and network graph theory model, available from the free software package GUIDOS (the Joint Research Center of the European Commission), enabled the measurement of the GI connectivity and identified most critical links. Results show that the competition for land claimed by different economic sectors, combined with policy-driven rule-sets for the implementation of different NWRMs, yields very different results for the 2030 land-use projections, and subsequently for the morphology of GI. Three indicators associated with the morphology of GI are computed in order to assess the model outputs for 2030. The indicators are computed to answer the following questions: (1) How is the quantity of GI affected by each of the NWRM, and what proportion of that GI is most valuable? (2) What is the location of the most critical nodes and connectors of GI, and what land-use conversions occur under these? (3) Are the average components getting larger or smaller?

Whereas the grassland measure results in the largest net increase of GI, the afforestation measure results in the overall largest number of hectares of key nodes and links within the network. Land conversions occur under the critical GI nodes and links, with a large increase in agricultural areas, especially for the riparian measure under critical nodes and the grassland measure under critical links. Also predominant is the swapping of land from pasture to forest under critical links with the afforestation measure. The riparian measure most increases the average size of GI components, and all three measures contribute to bridging two large components which were divided in the 2006 land-use map, thus increasing the size of the largest component by more than 50%.     

Efficiency of base isolation systems in structural seismic protection and energetic assessment

This paper concerns the seismic response of structures isolated at the base by means of High Damping Rubber Bearings (HDRB). The analysis is performed by using a stochastic approach, and a Gaussian zero mean filtered non‐stationary stochastic process is used in order to model the seismic acceleration acting at the base of the structure. More precisely, the generalized Kanai–Tajimi model is adopted to describe the non‐stationary amplitude and frequency characteristics of the seismic motion. The hysteretic differential Bouc–Wen model (BWM) is adopted in order to take into account the non‐linear constitutive behaviour both of the base isolation device and of the structure. Moreover, the stochastic linearization method in the time domain is adopted to estimate the statistical moments of the non‐linear system response in the state space. The non‐linear differential equation of the response covariance matrix is then solved by using an iterative procedure which updates the coefficients of the equivalent linear system at each step and searches for the solution of the response covariance matrix equation. After the system response variance is estimated, a sensitivity analysis is carried out. The final aim of the research is to assess the real capacity of base isolation devices in order to protect the structures from seismic actions, by avoiding a non‐linear response, with associated large plastic displacements and, therefore, by limiting related damage phenomena in structural and non‐structural elements. In order to attain this objective the stochastic response of a non‐linear n‐dof shear‐type base‐isolated building is analysed; the constitutive law both of the structure and of the base devices is described, as previously reported, by adopting the BWM and by using appropriate parameters for this model, able to suitably characterize an ordinary building and the base isolators considered in the study. The protection level offered to the structure by the base isolators is then assessed by evaluating the reduction both of the displacement response and the hysteretic dissipated energy. Copyright © 2003 John Wiley & Sons, Ltd.     

Seabed Morphology and Pollution Along the Bagnoli Coast (Naples, Italy): a Hypothesis for Environmental Restoration

Abstract. The interaction of coastal and submarine morphology with the hydrodynamic regimes exerts a control on coastal dynamic processes, conditioning the dispersion of sediments and potential pollutants existing in the area. Thus, the study of such parameters is useful in order to define environmental threats. Within the submerged sector of the Bagnoli coast and particularly in the southern part of the investigated area, there are sediment groups composed of very fine sands located in low-energy zones due to wave refraction and diffraction; they can also be found on the sea bottom and on the man-made structures typical of this zone. These areas show high pollutant levels of N, P, Cu, Fe, Mn, Ni, Pb, Zn, Cd, polyaromatic hydrocarbons (PAHs) and polychlorinated bi-phenyls (PCBs). The northern area, a place of high-energy hydrodynamic processes, also shows high concentration levels of pollutants due to the presence of secondary cell circulation.
Morphological research and analysis of textural characteristics of bottom sediments along the Bagnoli coast allowed the actual processes and their evolution in space and time to be defined. It has also been possible to correlate such processes to the seabed morphology system, the wave formations which affect the coast, the complex system of sediment transport, as well as to the man-made interventions in the area. The results of recent chemical analyses of beach sediments and bottom sediments off the Bagnoli coast were also incorporated. They prove the presence of heavy metals, PAHs and PCBs in high and sometimes very high concentrations. Finally, based on the results of research and analyses, a hypothesis for an intervention for environmental restoration has been formulated in order to renaturalise the coast through dredging and treatment of the sand, both on the seabed and on the emerged beach.     

Nir surface photometry of star-forming regions

We present a set of maps of the star-forming regions S140, Re 50, and Mon R2 in theJ, H, andK infrared bands (i.e., 1.2, 1.65, and 2.2 m), obtained with a resolution of 7 and 14 arc sec at the infrared 1.5 m TIRGO telescope, with the TIRGO InSb single channel photometer operating in a mapping mode.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

Diffuse radio emission from the intracluster medium

An important aspect of the radio emission from galaxy clusters is represented by the diffuse radio sources associated with the intracluster medium: radio halos, relics and mini-halos. The radio halos and relics are indicators of cluster mergers, whereas mini-halos are detected at the center of cooling core clusters. SKA will dramatically improve the knowledge of these sources, thanks to the detection of new objects, and to detailed studies of their spectra and polarized emission. SKA will also provide the opportunity to investigate the presence of halos produced by radiation scattered by a powerful radio galaxy at the cluster centers.