雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

Results from several persistent train spectra intercompared

Some results following from two contemporary photographical programs (Slovakia and Japan) for persistent meteor train spectra are compared. It shows that even though both programs are not too different according to their lenses and films used, the spectral interval detected is very different. In this respect prism as a dispersion element is more favourable than the grating with blaze wavelength near 610 nm. However, some results previously assumed as typicai for presented persistent trains-e.g. the forbidden Herzberg O₂ emission, the NO₂ continuum and OH red emissions-seem to be substanciated especially due to higher and linear dispersion of those grating spectra.     

Comments on ‘A comparative study of ANN and neuro-fuzzy for the prediction of dynamic constant of rockmass’

Singh et al (2005) examined the potential of the ANN and neuro-fuzzy systems application for the prediction of dynamic constant of rockmass. However, the model proposed by them has some drawbacks according to fuzzy logic principles. This discussion will focus on the main fuzzy logic principles which authors and potential readers should take into consideration.     

Variations in the Rate of Anaerobic Succinate Accumulation within the Central and Marginal Regions of an Euryoxic Bivalve Mantle

Abstract. Anaerobic metabolism in the central and marginal portions of the mantle of Mercenaria mercenaria was compared. Anaerobic succinate accumulation was more rapid in the central region. This difference may be due to higher phosphoenolpyruvate carboxykinase activity in the central region. Thus, the central region is more specialized for anaerobic metabolism and the marginal region more for net shell growth. The original rate of succinate accumulation in the mantle is similar in isolated mantles and intact clams, suggesting that mantle succinate production does not require translocation of precursors from other tissues. However, in intact clams, the rate of succinate accumulation in the central region of the mantle slows after four hours. The reduced rate is probably caused by reducing the metabolic rate. Succinate accumulation and shell dissolution are slower in freshly collected clams than in clams that had been stored anaerobically. The difference may be due to induction of PEPCK synthesis during storage. Shell derived calcium did not accumulate in the mantle and, therefore did not alter the intracellular calcium concentration in the mantle.     

Triple diagram method for the prediction of wave height and period

Many formulations have been developed so far to predict the wave height and period from fetch length and wind blowing duration for a constant wind speed. This study aimed to predict wave parameters from fetch length and meteorological factors by using triple diagram methodology based on Kriging principles. Proposed model results were compared with Joint North Sea Wave Project (JONSWAP) model which is used so commonly in the ocean and coastal engineering studies. For the implementation of the methodology hourly wave and wind data were obtained from a buoy located in Lake Ontario. Numerical and graphical comparisons demonstrated that the proposed method outperforms the classical formulation.     

The Ah receptor in marine animals: phylogenetic distribution and relationship to cytochrome P4501A inducibility

In mammals, the induction of cytochrome P4501A forms by chlorinated dibenzo-p-dioxins, chlorinated dibenzofurans, and halogenated biphenyls is under control of a soluble protein known as the Ah (aromatic hydrocarbon) receptor. Little is known about the presence and properties of the Ah receptor in other vertebrate and invertebrate species. In these studies, we sought evidence for an Ah receptor in the liver or liver-equivalent of 20 species of marine and freshwater animals, using the photoaffinity ligand 2-azido-3-[¹²⁵I] iodo-7,8-dibromodibenzo-p-dioxin (N₃[¹²⁵I]Br₂DD). Specific labeling of cytosolic proteins by N₃[¹²⁵I]Br₂DD was observed in seven species of teleost and elasmobranch fish, in PLHC-I fish hepatoma cells, and in beluga whales. No specifically labeled proteins were found in cytosol from two species of agnathan fish nor in any of nine invertebrate species representing eight classes of four phyla. The presence or absence of specifically labeled polypeptides corresponds with the inducibility of cytochrome P4501A and sensitivity to the toxic effects of 2,3,7,8-tetrachlorodibenzo-p-dioxin and related planar halogenated aromatic hydrocarbons in many of these groups. Thus, Ah receptor function may have arisen early invertebrate evolution and has been conserved from elasmobranch and teleost fish to mammals.     

The effects of sewage discharge on water quality and phytoplankton of Hawai'ian coastal waters

The effects of sewage discharge on algal populations and the quality of Hawai'ian coastal waters were investigated. Two outfalls were studied. One discharges primary treated sewage and the other discharges secondary treated sewage but are otherwise similar. This enabled comparisons of the effects of these different levels of treatment on the water quality and algal productivity of receiving waters. Plumes were followed and repeatedly sampled in a time-series manner. Rhodamine dye was used as a conservative tracer to compare the dilution behavior of the plume constituents MRP, NO(3)+NO(2), NH(4), Silicate, TDP, TDN, total bacteria, PC, and PN. Rates of initial dilution ranged from two to almost three orders of magnitude, and were in reasonable agreement with engineering model predictions. Dilution of plume constituents approximated that of Rhodamine until background concentrations were reached, typically within 10 min of discharge. Chl a concentrations did not increase through time in the primary sewage plume but did increase up to 30% in the secondary sewage plume. However, rates of far-field dilution were so rapid that the increase could not have been due to algal growth. The increase was attributed to the plume mixing with a water mass whose relative chl a concentrations were greater. Rates of secondary dilution ranged from 2 to 3 orders of magnitude resulting in total dilutions of 10(5)-10(6) within 3 h of discharge. These rates of secondary dilution were much greater than model predictions. From a nutrient standpoint, secondary treatment exhibited no advantages over primary treatment because dilutions were so rapid.     

Damage risk assessment of breakwaters under tsunami attack

Turkey was struck by two major events on 17 August and 12 November 1999, named Izmit (M _w = 7.4) and Düzce (M _w = 7.2) earthquakes, respectively. Rubble mound breakwaters in Izmit Bay experienced little damage, as forecasted by the new risk assessment model in which tsunami occurrence risk was included in the damage estimations. In order to determine the occurrence probability of structural damage under design conditions, including the environmental loading parameters of tsunami and storm waves, tidal range and storm surge, the Conditional Expections Monte Carlo simulation was applied in the risk assessment model developed in this study for the Esenköy Fishery Harbour, Turkey. A tsunami was not the key design parameter when compared to storm waves for the main breakwater of the harbour, however, in places with great seismic activity, the tsunami risk should be important depending on the occurrence probability and magnitude of the tsunami.