Variations in the stratospheric ozone field inferred from Nimbus satellite observations

The ultraviolet Earth radiance data from the backscatter ultraviolet experiment on Nimbus 4 have been inverted to infer ozone profiles using a single Rayleigh scattering model. Two methods of solution give essentially the same results. Comparison of these profiles with simultaneous rocket sounding data shows satisfactory agreement at low and middle latitudes.Vertical cross-sections of ozone mixing ratio along the orbital tracks indicate that while the gross characteristics of the ozone field above 10 mb are under photochemical control, the influence of atmospheric motions can be found up to the 4 mb level.     

The global distribution of total ozone: TOMS satellite measurements

The general behavior of total ozone by season and latitude was known before 1930 through the pioneering observations by G. M. B. Dobson. The ozone record at Oxford and other European stations was dominated by an annual cycle and by irregular short term fluctuations. The amplitude and phase of the annual cycle were determined at representative latitudes in both hemispheres. However, the short term variations appeared to be of meteorological origin, although the specific cause could not be identified. Data from the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus 7 spacecraft, with global coverage at an average spatial resolution of 66 km, can now be used to completely map the total ozone field. These maps demonstrate that troughs and ridges in the upper troposphere are responsible for the large, short term ozone variations found at middle latitudes, while in the troplcs, the steady, low ozone levels show broad scale structure associated with the Hadley circulation.     

Testing dark energy with the Advanced Liquid-mirror Probe of Asteroids, Cosmology and Astrophysics

The Advanced Liquid-mirror Probe of Asteroids, Cosmology and Astrophysics (ALPACA) is a proposed 8-m liquid-mirror telescope surveying  ∼1000 deg²  of the Southern hemisphere sky. It will be a remarkably simple and inexpensive telescope that none the less will deliver a powerful sample of optical data for studying dark energy. The bulk of the cosmological data consist of nightly, high signal-to-noise ratio, multiband light curves of Type Ia supernovae (SNe Ia). At the end of the 3-yr run, ALPACA is expected to collect  ≳100 000  SNe Ia up to   z ∼ 1  . This will allow us to reduce present systematic uncertainties affecting the standard-candle relation. The survey will also provide several other data sets such as the detection of baryon acoustic oscillations in the matter power spectrum and shear weak-lensing measurements. In this preliminary analysis, we forecast constraints on dark energy parameters from SNe Ia and baryon acoustic oscillations. The combination of these two data sets will provide competitive constraints on the dark energy parameters under minimal prior assumptions. Further studies are needed to address the accuracy of weak-lensing measurements.     

GSFC optical ozonesonde results during the Gap,France, intercomparisons,June 1981

A GSFC Super Loki optical ozonesonde instrument was flown as part of the ozone sensor intercomparison balloon campaign at Gap, France, in June 1981. A primary objective was to confirm biases between external absorption techniques, such as the GSFC sonde, and in situ techniques, which include ECC, Mast-Brewer, and DASIBI sondes. Ozone distributions were obtained with the GSFC sonde on three of the four ascent-descent legs of the first flight on 19 June. Ozone densities were measured redundantly over altitudes from 22 to 32 km using filters centered at 303 and 300 nm. The three profiles obtained by averaging the data from the two channels are in close agreement with an average S.E. of 1.4%. However, small but consistent differences were found between the ozone densities measured at the two wavelengths. The average difference is 5% using Vigroux cross sections and 4% using preliminary Bass cross sections. The integral ozone amount above the first ceiling altitude of 32.85 km was determined by the Langley plot method to be 45 D.U. The total ozone derived by integrating the optical ozonesonde and ECC profiles is within 2% of the Chiran Dobson Spectrophotometer observation based on a pre-campaign calibration but is 9% greater than the amount derived using a post-campaign calibration.     

The chemical compositions of 10 new sub-DLAs and strong Lyman-limit systems at z≲ 1.5

We present chemical abundance measurements from medium-resolution observations of eight subdamped Lyα (sub-DLA) absorber and two strong Lyman-limit systems at   z ≲ 1.5  observed with the Magellan Inamori Kyocera Echelle (MIKE) spectrograph on the 6.5-m Magellan II Clay telescope. These observations were taken as part of an ongoing project to determine abundances in   z _abs≲ 1.5  quasar absorption line systems focusing on sub-DLA systems. These observations increase the sample of Zn measurements in   z _abs≲ 1.5  sub-DLAs by ∼50 per cent. Lines of Mg  i , Mg  ii , Al  ii , Al  iii , Ca  ii , Mn  ii , Fe  ii and Zn  ii were detected and column densities were determined. Zn  ii , a relatively undepleted element and tracer of the gas-phase metallicity is detected in two of these systems, with  [Zn/H]=−0.05 ± 0.12  and  [Zn/H] > +0.86  . The latter one is however a weak system with   N _{H  I} < 18.8  , and therefore may need significant ionization corrections to the abundances. Fe  ii lines were detected in all systems, with an average Fe abundance of  〈[Fe/H]〉=−0.68  , higher than typical Fe abundances for DLA systems at these redshifts. This high mean [Fe/H] could be due to less depletion of Fe on to dust grains, or to higher abundances in these systems. We also discuss the relative abundances in these absorbers. The systems with high metallicity show high ratios of [Mn/Fe] and [Zn/Fe], as seen previously in another sub-DLA. These higher values of [Mn/Fe] could be a result of heavy depletion of Fe on to grains, unmixed gas, or an intrinsically non-solar abundance pattern. Based on cloudy modelling, we do not expect ionization effects to cause this phenomenon.     

New abundance determinations in z < 1.5 QSO absorbers: seven sub-DLAs and one DLA

We present chemical abundance measurements from high-resolution observations of seven subdamped Lyα (sub-DLA) absorbers and one DLA system at   z < 1.5  . Three of these objects have high metallicity, with near or supersolar Zn abundance. Grids of cloudy models for each system were constructed to look for possible ionization effects in these systems. For the systems in which we could constrain the ionization parameter, we find that the ionization corrections as predicted by the cloudy models are generally small and within the typical error bars (∼0.15 dex), in general agreement with previous studies. The Al  iii to Al  ii ratio for these and other absorbers from the literature are compared, and we find that while the sub-DLAs have a larger scatter in the Al  iii to Al  ii ratios than the DLAs, there appears to be little correlation between the ratio and   N _{H  i}   . The relationship between the metallicity and the velocity width of the profile for these systems is investigated. We show that the sub-DLAs that have been observed to date follow a similar trend as DLA absorbers, with the more metal rich systems exhibiting large velocity widths. We also find that the systems at the upper edge of this relationship with high metallicities and large velocity widths are more likely to be sub-DLAs than DLA absorbers, perhaps implying that the sub-DLA absorbers are more representative of massive galaxies.     

TOMS measurement of the sulfur dioxide emitted during the 1985 Nevado del Ruiz eruptions

The eruptions of Nevado del Ruiz in 1985 were unusually rich in sulfur dioxide. These eruptions were observed with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) which can quantitatively map volcanic sulfur dioxide plumes on a global scale. A small eruption, originally believed to be of phreatic origin, took place on September 11, 1985. However, substantial amounts of sulfur dioxide from this eruption were detected with TOMS on the following day. The total mass of SO₂, approximately 9 ± 3 × 10⁴ metric tons, was deposited in two clouds, one in the upper troposphere, the other possibly at 15 km near the stratosphere.The devastating November 13 eruptions were first observed with TOMS at 1150 EST on November 14. Large amounts of sulfur dioxide were found in an arc extending 1100 km from south of Ruiz northeastward to the Gulf of Venezuela and as an isolated cloud centered at 7°N on the Colombia-Venezuela border. On November 15 the plume extended over 2700 km from the Pacific Ocean off the Colombia coast to Barbados, while the isolated mass was located over the Brazil-Guyana border, approximately 1600 km due east of the volcano. Based on wind data from Panama, most of the sulfur dioxide was located at 10–16 km in the troposphere and a small amount was quite likely deposited in the stratosphere at an altitude above 24 km.The total mass of sulfur dioxide in the eruption clouds was approximately 6.6 ± 1.9 × 10⁵ metric tons on November 14. When combined with quiescent sulfur dioxide emissions during this period, the ratio of sulfur dioxide to erupted magma from Ruiz was an order of magnitude greater than in the 1982 eruption of El Chichon or the 1980 eruption of Mount St. Helens.     

Tracking volcanic sulfur dioxide clouds for aviation hazard mitigation

Satellite measurements of volcanic sulfur dioxide (SO₂) emissions can provide critical information for aviation hazard mitigation, particularly when ash detection techniques fail. Recent developments in space-based SO₂ monitoring are discussed, focusing on daily, global ultraviolet (UV) measurements by the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite. OMI’s high sensitivity to SO₂ permits long-range tracking of volcanic clouds in the upper troposphere and lower stratosphere (UTLS) and accurate mapping of their perimeters to facilitate avoidance. Examples from 2006 to 2007 include eruptions of Soufriere Hills (Montserrat), Rabaul (Papua New Guinea), Nyamuragira (DR Congo), and Jebel at Tair (Yemen). A tendency for some volcanic clouds to occupy the jet stream suggests an increased threat to aircraft that exploit this phenomenon. Synergy between NASA A-Train sensors such as OMI and the Atmospheric Infrared Sounder (AIRS) on the Aqua satellite can provide critical information on volcanic cloud altitude. OMI and AIRS SO₂ data products are being produced in near real-time for distribution to Volcanic Ash Advisory Centers (VAACs) via a NOAA website. Operational issues arising from these improved SO₂ measurements include the reliability of SO₂ as proxy for co-erupted ash, the duration of VAAC advisories for long-lived volcanic clouds, and the potential effects of elevated concentrations of SO₂ and sulfate aerosol in ash-poor clouds on aircraft and avionics (including cumulative effects after multiple inadvertent transits through dilute clouds). Further research is required in these areas. Aviation community assistance is sought through continued reporting of sulfurous odors or other indications of diffuse volcanic cloud encounters, in order to validate the satellite retrievals.