Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

Viscous liquid film flow on dune slopes of Mars

It is shown that viscous liquid film flow (VLF-flow) on the surfaces of slopes of martian dunes can be a low-temperature rheological phenomenon active today on high latitudes. A quantitative model indicates that the VLF-flows are consistent with the flow of liquid brines similar to that observed by imaging at the Phoenix landing site. VLF-flows depend on the viscosity, dynamics, and energetics of temporary darkened liquid brines. The darkening of the flowing brine is possibly, at least partially, attributed to non-volatile ingredients of the liquid brines. Evidence of previous VLF-flows can also be seen on the dunes, suggesting that it is an ongoing process that also occurred in the recent past.     

Multiple generation magmatic and hydrothermal processes in a Martian subvolcanic environment based on the analysis of Yamato-000593 nakhlite meteorite

We studied the occurrence of secondary minerals and inferred their formation in the Yamato-000593 Martian meteorite using multiple technological approaches such as electron probe micro analysis, optical microscope, Raman spectroscopy, scanning electron microscopy, as well as Fourier transform-infrared microscopy and spectroscopy. Two separate hydrothermal alteration events and their sequence of formation (based on superpositional relationship) can be identified: an elevated temperature phase producing high-temperature sulfidic hydrothermal alteration and a lower temperature hydrothermal alteration phase by iron-rich fluids. This meteorite shows signatures more compatible with magmatic effects, rather than impact-induced hydrothermal alteration, as has been proposed earlier. The sulfidic alteration probably formed by magmatic hydrothermal fluids, whereas iron-rich hydrothermal fluid circulation after a possible early impact event has also been proposed, when the fluids cooled down to 50 °C. Most of the secondary minerals formed at alkaline-neutral conditions, and the few observed signatures (clay–silica-bearing veins, siderite-iron-oxide veins) of briny conditions are probably from local spatial effects in larger cavities. The ferrous minerals (hematite and siderite) along the fractures could be crystallized from Fe-HCO₃-bearing fluids. Alternatively, the primary magmatic minerals could have been oxidized easily (Fe-rich olivines, magnetite) during the cooling to iron oxides (hematite, goethite). The results suggest the possible existence of at least ephemerally habitable environments on Mars, mainly at volcanically heated locations. Following published geochemical models, the carbonates formed within acidic-circumneutral condition, which was followed by formation of phyllosilicates in alkaline condition.     

Alteration processes in the CV chondrite parent body based on analysis of NWA 2086 meteorite

Analysis of the NWA 2086 CV3 chondrite showed a matrix/chondrule ratio of 52%, similar to Bali, Mokoia, and Grosanaja. Nearly twice as many chondrule fragments as intact ones demonstrate that an early fragmentation phase occurred prior to final accretion. After this event, no substantial mechanical change or redeposition is evident. Rims with double‐layered structures were identified around some chondrules, which, in at least one case, is attributed to an accretionary origin. The rim's outer parts with a diffuse appearance were formed by in situ chemical alteration. During this later process, Mg content decreased, Fe content increased, and olivine composition was homogenized, producing a rim composition close to that of the matrix. This alteration occasionally happened along fractures and at confined locations, and was probably produced by fluid interactions. Iron oxides are the best candidate for a small grain‐sized alteration product; however, technical limitations in the available equipment did not allow exact phase identification. These results suggest that NWA 2086 came from a location (possible more deeply buried) in the CV parent body than Mokoia or Bali, and suffered less impact effects—although there is no evidence of sustained thermal alteration. This meteorite may represent a sample of the CV parent asteroid interior and provide a useful basis for comparison with other CV meteorites in the future.     

Locations of thin liquid water layers on present-day Mars

CRISM indicates the presence of water ice patches in Richardson crater, located on Mars’ southern polar region at the area of the seasonal ice cap. Numerical simulations suggest that the maximum daytime temperature of the ice at these locations is between 195 and 220 K during local spring. Previous studies suggest that at these temperatures liquid interfacial water could be present. Here, for the first time, we provide an example where the environmental conditions allow for the formation of such liquid films on present day Mars at the southern hemisphere. The upper bound estimated H₂O loss during the presence of these water ice patches is approximately 30 μm between Ls = 200 and 220, though it may be as low as 0.1 μm depending on the ambient water vapor. The upper bound value is larger than the expected condensation thickness in autumn; however, it may still be realistic due to CO₂ gas jet generated deposition and possible subsequent accumulation on mineral grains. The presence of this interfacial water may have impact on local chemical processes along with astrobiological importance.     

Snow depth estimation accuracy using a dual-interface GPS-IR model with experimental results

GPS Solutions - Measuring snow depth using the GPS interferometric reflectometry is an active microwave remote sensing technique and an emerging approach because of its relatively large spatial...     

Indications of brine related local seepage phenomena on the northern hemisphere of Mars

Springtime low albedo features, called Dark Dune Spots, on the seasonal frost covered dunes on Mars between 77°N and 84°N latitude have been analyzed. Two groups of these spots have been identified: “small” and “large” ones, where large spots have diameters above 4 m, and complex internal structure. From these “large” spots branching seepage-like features emanate and grow on the steep slopes. They show a characteristic sequence of changes: first only wind-blown features emanate from them, while later a bright circular and elevated ring forms, and dark seepage-features start from the spots. These streaks grow with a speed between 0.3 m/day and 7 m/day respectively, first only from the spots, later from all along the dune crest.During this “seepage period” the temperature is between 150 K and 180 K at a 3-9 km spatial resolution scale, indicating that CO₂ ice-free parts must be present at the observed dark spots. Around the receding northern seasonal CO₂ cap, an annulus of water ice lags behind, which is probably present in the spots too where the CO₂ frost has sublimated. Our model estimates show in the present work and in Kereszturi et al. (Kereszturi, A., Möhlmann, D., Berczi, Sz., Ganti, T., Kuti, A., Sik, A., Horvath, A. [2009b]. Icarus 201, 492-503) that the warming driven by solar insolation may produce not only interfacial water, but also bulk brines around the dune grains. The brine can support the movement of liquids and dune grains, enhances the sublimation of CO₂ frost, and produce the dark features, as well as liquid modifies the optical properties of the surface.Signs of movement of dune material after the total defrosting of the terrain is also visible but it is uncertain because of the limit of resolution. In our previous work (Kereszturi et al., 2009b) we showed that resembling seepage-like streaks at the southern hemisphere might have been formed by ephemeral interfacial water, as well as these northern features. Such wet environments may have astrobiological importance too.