Seasonal patterns of carbon chemistry and isotopes in tufa depositing groundwaters of southwestern Japan

Annually laminated carbonates, known as tufas, commonly develop in limestone areas and typically record seasonal patterns of oxygen- and carbon-isotope compositions. δ¹⁸O values are principally controlled by seasonal changes of water temperature, whereas δ¹³C values are the result of complex reactions among the gaseous, liquid, and solid sources of carbon in the system. We examined the processes that cause the seasonal patterns of δ¹³C in groundwater systems at three tufa-depositing sites in southwestern Japan by applying model calculations to geochemical data. Underground inorganic carbon species are exchanged with gaseous CO₂, which is mainly introduced to the underground hydrological system by natural atmospheric ventilation and by diffusion of soil air. These processes control the seasonal pattern of δ¹³C, which is low in summer and high in winter. Among the three sites we investigated, we identified two extreme cases of the degree of carbon exchange between liquid and gaseous phases. For the case with high radiocarbon composition (Δ¹⁴C) and low pCO₂, there was substantial carbon exchange because of a large contribution of atmospheric CO₂ and a small water mass. For the other extreme case, which was characterized by low Δ¹⁴C and high pCO₂, the contribution of atmospheric CO₂ was small and the water mass was relatively large. Our results suggest that at two of the three sites water residence time within the soil profile was longer than 1 year. Our results also suggested a short residence time (less than 1 year) of water in the soil profile at the site with the smallest water mass, which is consistent with large seasonal amplitude of the springwater temperature variations. The Δ¹⁴C value of tufas is closely related to the hydrological conditions in which they are deposited. If the initial Δ¹⁴C value of a tufa-depositing system is stable, ¹⁴C-chronology can be used to date paleo-tufas.     

GEK measurements in a shallow water region

Evidence for the applicability of GEK (Geomagnetic Electrokinetography) measurements to shallow water regions is provided from observations in the shelf region of the East China Sea. The reason for the effectiveness of GEK measurements in this case is investigated theoretically, and it is shown to be attributable to the existence of a thick conductive sedimentary layer. In addition, it is shown that low conductive basement rock can be regarded as a good conductor for GEK measurements if the current width is broad enough and if the ratio of current width to water depth is larger than the resistivity ratio of basement rock to sea water. This implies that barotropic tidal currents can be measured with GEK in any ocean on the earth if they have significant magnitudes.     

Thermal and chemical evolution of the terrestrial magma ocean

The Earth is likely to have experienced a magma ocean stage during accretion. Thermal and chemical evolution of magma ocean is investigated based on a one-dimensional two-phase-flow heat and mass transfer model. Differentiation at lower mantle pressure depends on the type of magma ocean and surrounding atmosphere. If the magma ocean is formed by the blanketing effect of a solar-type proto-atmosphere, extensive differentiation proceeds at lower mantle pressure. If the magma ocean is formed by the blanketing effect of an impact-induced steam atmosphere, no differentiation at lower mantle pressure is likely. If a very deep magma ocean is formed by a giant impact, whether differentiation proceeds at lower mantle pressure or not depends on grain size, viscosity of melt and/or properties of a transient atmosphere. On the contrary, chemical differentiation likely proceeds at upper mantle pressure irrespective of magma ocean type. A shallow magma ocean can remain for 100 200 My without any heating processes.     

Seasonal variations of the surface currents in the Tsushima Strait

Seasonal variations of the surface currents in the Tsushima Strait were investigated by analyzing the monthly mean surface currents measured with HF radar. Several new features of the surface currents have been found. One notable feature is the large, complicated seasonal variation in the current structure in the eastern channel of the strait. For example, in the southeastern and northwestern regions of the channel, southwestward countercurrents are found in summer while southeastward acrossshore currents are found in autumn and winter. The wind-driven flow (Ekman flow) as well as surface geostrophic currents are responsible for these complicated variations of the surface currents. To quantify each variation of the flow and current, the wind-driven flow was calculated from the monthly wind (more precisely, the friction velocity) using the monthly speed factor and deflection angle estimated in our previous study, and the surface geostrophic currents were then estimated by subtracting the wind-driven flow from the measured surface currents. It was found that the acrossshore currents are the wind-driven flow, and that the surface geostrophic currents flow almost in the along-shore direction, indicating the validity of the decomposition of the surface velocity into the wind-driven flow and the geostrophic currents using the speed factor and deflection angle. A real-vector empirical orthogonal function (EOF) analysis of the surface geostrophic currents shows a pair of eddies in the lee of Tsushima and Iki Islands as the first mode, which indicates that the southwestward countercurrents in the eastern channel are formed primarily by the incoming Tsushima Warm Current.     

A Preliminary Study of Oceanic Bomb Radiocarbon Inventory in the North Pacific during the Last Two Decades

Radiocarbon and total carbonate data were obtained near the 1973 GEOSECS stations in the North Pacific along 30°N and along 175°E between 1993 and 1994. In these stations, we estimated radiocarbon originating from atomic bomb tests using tritium, trichlorofluoromethane and silicate contents. The average penetration depth of bomb radiocarbon during the two decades has deepened from 900 m to 1300 m. Bomb radiocarbon inventories above the average value for the whole North Pacific were found widely in the western subtropical region around 30°N both in the 1970s and 1990s, and its area in the 1990s was broader than that in the 1970s. In most of the North Pacific, while the bomb radiocarbon has decreased above 25.4, the bomb radiocarbon flux below 25.4 was over 1 × 10¹² atom m^-2yr^-1 in the subtropical region around 30°N. In the tropical area south of 20°N, the bomb radiocarbon inventory below 25.4 increased from zero to over 10 × 10¹² atom m^-2 during the last three decades. These distributions suggest that the bomb radiocarbon removed from the surface is currently accumulated with bomb ¹⁴C flux of over 1 × 10¹² atom m^-2yr^-1 below 25.4 in the subtropical region, mainly by advection from the higher latitude, and that part of the accumulated bomb ¹⁴C gradually spread southward with about 30 years.     

Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.     

Current Nature of the Kuroshio in the Vicinity of the Kii Peninsula

The Kuroshio flows very close to Cape Shionomisaki when it takes a straight path. The detailed observations of the Kuroshio were made both on board the R/V Seisui-maru of Mie University and on board the R/V Wakayama of the Wakayama Prefectural Fisheries Experimental Station on June 11–14, 1996. It was confirmed that the current zone of the Kuroshio touches the coast and bottom slope just off Cape Shionomiaki, and that the coastal water to the east of the cape was completely separated from that to the west. The relatively high sea level difference between Kushimoto and Uragami could be caused by this separation of the coastal waters when the Kuroshio takes a straight path. This flow is rather curious, as the geostrophic flow, which has a barotropic nature and touches the bottom, would be constrained to follow bottom contours due to the vorticity conservation law. The reason why the Kuroshio leaves the bottom slope to the east of Cape Shionomisaki is attributed to the high curvature of the bottom contours there: if the current were to follow the contours, the centrifugal term in the equation of motion would become large and comparablee to the Coriolis (or pressure gradient) term, and the geostrophic balance would be destroyed. This creates a current-shadow zone just to the east of the cape. As the reason why the current zone of the Kuroshio intrudes into the coastal region to the west of the cape, it is suggested that the Kii Bifurcation Current off the southwest coast of the Kii Peninsula, which is usually found when the Kuroshio takes the straight path, has the effect of drawing the Kuroshio water into the coastal region. The sea level difference between Kushimoto and Uragami is often used to monitor the flow pattern of the Kuroshio near the Kii Peninsula. It should be noted that Uragami is located in the current shadow zone, while Kushimoto lies in the region where the offshore Kuroshio water intrudes into the coastal region. The resulting large sea level difference indicates that the Kuroshio is flowing along the straight path.     

Seasonal variations of water system distribution and flow patterns in the southern sea area of Hokkaido,Japan

Hydrographic data and composite current velocity data (ADCP and GEK) were used to examine the seasonal variations of upper-ocean flow in the southern sea area of Hokkaido, which includes the “off-Doto” and “Hidaka Bay” areas separated by Cape Erimo. During the heating season (April–September), the outflow of the Tsugaru Warm Current (TWC) from the Tsugaru Strait first extends north-eastward, and then one branch of TWC turns to the west along the shelf slope after it approaches the Hidaka Shelf. The main flow of TWC evolves continuously, extending eastward as far as the area off Cape Erimo. In the late cooling season (January–March), part of the Oyashio enters Hidaka Bay along the shallower part of the shelf slope through the area off Cape Erimo, replacing almost all of the TWC water, and hence the TWC devolves. It is suggested that the bottom-controlled barotropic flow of the Oyashio, which may be caused by the small density difference between the Oyashio and the TWC waters and the southward migration of main front of TWC, permits the Oyashio water to intrude along the Hidaka shelf slope.     

Numerical forecasting of the time interval between successive M8 earthquakes along the Nankai Trough,southwest Japan,using ocean bottom cable network data

One possible approach to estimating the time interval between large-scale Tōnankai (Tōkai) and Nankai earthquakes on the Japan arc is sequential assimilation of crustal deformation data. We conducted numerical modeling of sequential assimilation using surface deformation calculated from earthquake generation cycle simulations along the Nankai Trough. To account for observation noise, we used measured ocean bottom pressure gauge data, excluding tidal modulation, from a station on the ocean bottom cable network Dense Oceanfloor Network System for Earthquakes and Tsunamis in the Kumano basin. We used sequential importance sampling as our data assimilation method. We found that as the amount of data increased, the estimated time interval between the Tōnankai and Nankai earthquakes approached the “true” observed interval. In addition, the noise in the pressure gauge data was sufficiently small that simulated crustal deformation patterns could be distinguished for different time intervals.     

A field study of physico-chemical states of artificial radionuclides in seawater

The physico-chemical states of artificial radionuclides,⁹⁰Sr,¹³⁷Cs and¹⁴⁴Ce in seawater were investigated by radiochemical analysis of filtered and unfiltered seawater. The difference of radionuclide concentrations between unfiltered and filtered seawaters was defined as the particulate form radioisotope and its particle ratio was discussed.Practically no particulate⁹⁰Sr, greater than 0.22 in size, was observed in both coastal and open seawaters, but some of¹³⁷Cs seemed to be insoluble in some circumstances, especially in coastal waters. A considerable amount of¹⁴⁴Ce was found to be particulate.An estimation of the radionuclides in particulate form was made for Kashima-nada seawaters collected in 1970 to 1972, and it was shown that the possible occurrence of particulate radionuclides, greater than 0.22 in size, were 1% or less for⁹⁰Sr and 6% for¹³⁷Cs. In the coastal water, 80 % of¹⁴⁴Ce were seemed to be in particulate form, but in the open seawater only a few%. The influences of suspended materials to¹³⁷Cs and¹⁴⁴Ce concentration levels in seawater were not negligible and further investigations are desirable.