Excess CO2 and pHexcess in the Intermediate Water Layer of the Northwestern Pacific

Excess CO₂ and pH_excess showing an increase in dissolved inorganic carbon and a decrease in pH from the beginning of the industrial epoch (middle of the 19th century) until the present time have been calculated in the intermediate water layer of the northwestern Pacific and the Okhotsk Sea. It is concluded that: (1) The Kuril Basin (Okhotsk Sea) and the Bussol' Strait areas are characterized by the greatest concentrations of excess CO₂ at isopycnal surfaces due to the processes of formation and transformation of intermediate water mass. (2) The largest difference in excess CO₂ concentration between the Okhotsk Sea and the western subarctic Pacific (about 8 µmol/kg) is found at the = 27.0. (3) The difference in excess CO₂ between the western subarctic Pacific and subtropical regions is significant only in the upper part of the intermediate water layer ( = 26.7–27.0). (4) About 10% of the excess CO₂ accumulation in the subtropical north Pacific is determined by water exchange with the subarctic Pacific and the Okhotsk Sea.     

Solubility and solution mechanisms of C-O-H volatiles in silicate melt with variable redox conditions and melt composition at upper mantle temperatures and pressures

Solubility and solution mechanisms in silicate melts of oxidized and reduced C-bearing species in the C-O-H system have been determined experimentally at 1.5 GPa and 1400 °C with mass spectrometric, NMR, and Raman spectroscopic methods. The hydrogen fugacity, f_H2, was controlled in the range between that of the iron-wüstite-H₂O (IW) and the magnetite-hematite-H₂O (MH) buffers. The melt polymerization varied between those typical of tholeiitic and andesitic melts.The solubility of oxidized (on the order of 1-2 wt% as C) and reduced carbon (on the order of 0.15-0.35 wt% as C) is positively correlated with the NBO/Si (nonbridging oxygen per silicon) of the melt. At given NBO/Si-value, the solubility of oxidized carbon is 2-4 times greater than under reducing conditions. Oxidized carbon dioxide is dissolved as complexes, whereas the dominant reduced species in melts are CH₃-groups forming bonds with Si⁴⁺ together with molecular CH₄. Formation of complexes results in silicate melt polymerization (decreasing NBO/Si), whereas solution of reduced carbon results in depolymerization of melts (increasing NBO/Si).Redox melting in the Earth’s interior has been explained with the aid of the different solution mechanisms of oxidized and reduced carbon in silicate melts. Further, effects of oxidized and reduced carbon on melt viscosity and on element partitioning between melts and minerals have been evaluated from relationships between melt polymerization and dissolved carbon combined with existing experimental data that link melt properties and melt polymerization. With total carbon contents in the melts on the order of several mol%, mineral/melt element partition coefficients and melt viscosity can change by several tens to several hundred percent with variable redox conditions in the range of the Earth’s deep crust and upper mantle.     

Application of frequency ratio,statistical index,and weights-of-evidence models and their comparison in landslide susceptibility mapping in Central Nepal Himalaya

The Mugling–Narayanghat road section falls within the Lesser Himalaya and Siwalik zones of Central Nepal Himalaya and is highly deformed by the presence of numerous faults and folds. Over the years, this road section and its surrounding area have experienced repeated landslide activities. For that reason, landslide susceptibility zonation is essential for roadside slope disaster management and for planning further development activities. The main goal of this study was to investigate the application of the frequency ratio (FR), statistical index (SI), and weights-of-evidence (WoE) approaches for landslide susceptibility mapping of this road section and its surrounding area. For this purpose, the input layers of the landslide conditioning factors were prepared in the first stage. A landslide inventory map was prepared using earlier reports, aerial photographs interpretation, and multiple field surveys. A total of 438 landslide locations were detected. Out these, 295 (67 %) landslides were randomly selected as training data for the modeling using FR, SI, and WoE models and the remaining 143 (33 %) were used for the validation purposes. The landslide conditioning factors considered for the study area are slope gradient, slope aspect, plan curvature, altitude, stream power index, topographic wetness index, lithology, land use, distance from faults, distance from rivers, and distance from highway. The results were validated using area under the curve (AUC) analysis. From the analysis, it is seen that the FR model with a success rate of 76.8 % and predictive accuracy of 75.4 % performs better than WoE (success rate, 75.6 %; predictive accuracy, 74.9 %) and SI (success rate, 75.5 %; predictive accuracy, 74.6 %) models. Overall, all the models showed almost similar results. The resultant susceptibility maps can be useful for general land use planning.     

The layered structure of lunar maria: Identification of the HF-radar reflector in Mare Serenitatis using multiband optical images

Comparison of the Lunar Radar Sounder (LRS) data to the Multiband Imager (MI) data is performed to identify the subsurface reflectors in Mare Serenitatis. The LRS is FM-CW radar (4–6 MHz) and the 2 MHz bandwidth leads to the range resolution of 75 m in a vacuum, whereas the sampling interval in the flight direction is about 75 m when an altitude of the spacecraft with polar orbit is nominal (100 km). Horizontally continuous reflectors were clearly detected by LRS in limited areas that consist of about 9% of the whole maria. The typical depth of the reflectors is estimated to be a few hundred meters. Layered structures of mare basalts are also discernible on some crater walls in the MI data of the visible bands (VIS). The VIS range has nine wavelengths of 415, 750, 900, 950, and 1000 nm, and their spatial resolution is 20 m/pixel at a nominal altitude. The stratigraphies around Bessel and Bessel-H craters in Mare Serenitatis are examined in this paper. It was revealed that the subsurface reflectors lie on the boundaries between basalt units with different chemical compositions. In addition, model calculations using the simplified radar equation indicate that the subsurface reflectors are not compositional interfaces but layer boundaries with a high-porosity contrast. These results suggest that the detected reflectors in Mare Serenitatis are regolith accumulated during so long hiatus of mare volcanisms enough for chemical composition of magma to change, not instantaneously. Therefore combination of the LRS and MI data has a potential to reveal characteristics of a series of magmatism forming each lithostratigraphic unit in Mare Serenitatis and other maria.     

Temporal and spatial variations of radiocarbon in Japan Sea bottom water

In 1995 and 2000, the radiocarbon ratio (Δ¹⁴C) of total dissolved inorganic carbon was measured in the Japan Sea where deep and bottom waters are formed within the sea itself. We found that (1) since 1979, the Δ¹⁴C in bottom water below about 2000-m depth in the western Japan Basin (WJB) had increased by about 30‰ by 1995, and (2) the bottom Δ¹⁴C in the WJB did not change between 1995 and 2000. The former finding was due to penetration of surface bomb-produced radiocarbon into the bottom water owing to bottom ventilation, whereas the latter was caused by stagnation of the bottom ventilation there. In the eastern Japan Basin (EJB), the bottom Δ¹⁴C also increased by about 30‰ between 1979 and 2002. Recent stagnation of the bottom ventilation in the EJB is also suggested from analyses of constant bomb-produced tritium between 1984 and 1999. The temporal variations of Δ¹⁴C, tritium, and dissolved oxygen in the bottom waters indicate that: (1) new bottom water is formed south of Vladivostok in the WJB only in severe winters; and (2) the new bottom water then follows the path of a cyclonic abyssal circulation of the Japan Sea, which results in the increases in dissolved oxygen and the transient tracers in the bottom waters in the EJB and Yamato Basin with an approximate 3-to 6-year time lag. This process is consistent with the spatial variations of Δ¹⁴C, bomb-produced ¹³⁷Cs, and chlorofluorocarbon-11 in the bottom waters of the Japan Sea.     

Effects of the Anticyclonic Eddies on Water Masses, Chemical Parameters and Chlorophyll Distributions in the Oyashio Current Region

Data from the R/V Mirai cruise (May–June 2000) have been examined to discover how mesoscale processes associated with eddy dynamics direct affect the water masses, the distributions and the vertical fluxes of the dissolved oxygen, nutrients and dissolved inorganic carbon in the western subarctic Pacific. Using maps of the temperature, salinity, dissolved oxygen, nutrients, chlorophyll and sea-air pCO₂ difference we show that the boundaries of the anticyclone eddies in the study region were composed of high productivity coastal Oyashio water. The coastal waters were wrapped around the anticyclone eddies (thus creating a high productivity belt) and intruded inside of them. Using SeaWifs data we demonstrate that temporal variations in the position and the strength of anticyclone eddies advected the Kuril island coastal high productivity waters to the pelagic part, resulting in temporal variations of the chlorophyll in the Oyashio region. Computed vertical fluxes of the dissolved oxygen (DO), inorganic carbon (DIC) and silicate show that the anticylonic eddies in the Kuroshio-Oyashio Zone are characterized by enhanced vertical fluxes of the DO and DIC between the upper (σ_θ = 26.7–27.0) and lower (σ_θ = 27.1–27.5) intermediate layer, probably due to the intrusions of the Oyashio waters into the eddies. This revised version was published online in August 2006 with corrections to the Cover Date.     

Temporal variation of the partial pressure of CO2 in surface seawater of Iyo Nada in the Seto Inland Sea,Japan

The temporal variation of the partial pressure of carbon dioxide in surface seawater of Iyo Nada in the western Seto Inland Sea was measured by infrared absorption of carbon dioxide (CO₂) in air equilibrated with seawater. The variation of from January to late May in 1994 was relatively small (from 270 to 340 atm). on the contrary, the measured in September 1993 ranged from 200 to 450 atm. It seems that the relative high observed in the north and the south of Iyo Nada in September were caused by destruction of a stratification owing to tidal currents at straits between Hiroshima Bay and Iyo Nada and Hayasui Straits, respectively. The low observed in the central Iyo Nada in September was ascribed to a tidal front where high concentrations of chlorophyll-a and a relation between and chlorophyll-a in negative sense were found. Except the observation in the north of Iyo Nada in September, the in the surface seawater of Iyo Nada were lowe than the atmospheric (about 367 atm). The results obtained by this work and Kimotoet al. (1993) lead to the conclusion that Iyo Nada acts as a sink of the atmospheric CO₂ on the average.