Sulfate reduction and sulfide deposition in deep-sea sediments from the southwestern Japan Sea

Vertical profiles of total sulfur and organic carbon have been measured in two deep-sea piston cores from the southwestern Japan Sea where sulfate reduction is proceeding within the sediments. The content of total sulfur, most of which is present as pyrite, increases gradually with increasing depth, showing several peaks. The amount of diagenetically deposited sulfide-sulfur is estimated using a steady-state model that considers vertical change in the diffusion coefficient. It is suggested that two-thirds to three-fourths of the observed total sulfur content has been deposited diagenetically.     

The effects of the reed,Phragmites australis (Trin.), on substratum grain-size distribution in a salt marsh

The effects of the reed,Phragmites australis (Trin.), growing in a brackish water lagoon, were studied in relation to the grain-size distribution of the substratum. At the salt marshes near the lagoon, the upper soils from the surface to a depth of 20 cm contained much silt-clay. These fine particles were found to be transferred from the river and fish ponds near the lagoon, and to be deposited when the tidal rhythm changed, that is, when the water current stopped. In addition, the fine particles, which were deposited on the bottom of the lagoon adjacent to the marshes, became resuspended as a result of wind-caused wave action, and then were transported and redeposited in the salt marshes at the flood tide. Since the reeds further reduced the water current caused by the waves and tide, the reeds were thought to promote redeposition of the resuspended matter. In other words, the reeds were considered to protect deposited and redeposited particles such as silt and clay from resuspension as a result of wave action by reducing the effects of waves and wind. These processes suggested that silt-clay will become abundant in the substratum of the salt marsh adjacent to the lagoon.     

Degradation of lubricating oils by marine bacteria observed by quantitative mass spectrometry

Bacterial degradation of the hydrocarbons of lubricating oils was investigated by mass spectrometric analysis which gives both total amount and the composition of hydrocarbon types of residual oil. An unused lubricating oil, which mainly consisted of hydrocarbon types with only a small percentage ofn-alkanes, was degraded by marineBacillus sp. andPseudomonas sp. with 55 % and 25 % decreases in 10 days, respectively. Susceptibility of respective hydrocarbon types to biodegradation was in the following order: alkanes > non-condensed cycloalkanes, mono-aromatics > condensed cycloalkanes. A used lubricating oil of different brand showed a larger decrease than the unused oil. Both species of bacteria degraded large portions of alkane fraction of Arabian light crude oil.     

Finite-element Simulation of Seismic Ground Motion with a Voxel Mesh

— Accurate simulation of seismic ground motion for three-dimensionally complex topography and structures is one of the most important goals of strong motion seismology. The finite-element method (FEM) is well suited for this kind of simulation, since traction-free conditions are already included in the formulation, and the Courant condition is less strict than for the finite-difference method (FDM). However, the FEM usually requires both large memory and computation time. These limitations can be overcome by using a mesh consisting of voxels (rectangular prisms) with isotropy built into the explicit formulation of the dynamic matrix equation. Since operators in the voxel FEM are the combinations of ordinary FDM operators and additional terms, the method keeps accuracy of the same order as FDM and the terms relax the Courant condition. The voxel FEM requires a similar amount of memory and only takes 1.2～1.4 times longer computation time. The voxel mesh can be generated considerably faster than the popular tetrahedral mesh. Both ground motions and static displacements due to a point or line source can be calculated using the voxel FEM approach. Comparisons with the reflectivity method and theoretical solutions demonstrate the successful implementation of the method, which is then applied to more complex problems.     

Oxygen isotope speedometry in granulite facies garnet recording fluid/melt–rock interaction (Sør Rondane Mountains,East Antarctica)

In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ¹⁸O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ¹⁸O = ~15‰) to the rim (δ¹⁸O = ~11‰) suggests that the ¹⁸O/¹⁶O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the ¹⁸O/¹⁶O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ¹⁸O value of the garnet rim, together with the previously reported low δ¹⁸O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ¹⁸O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.     

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.     

Seasonal and spatial variation in the denitrifying activity in estuarine and lagoonal sediments

We have elucidated the seasonal and spatial variation in the potential denitrifying activity in estuarine and coastal lagoonal sediments in Lakes Shinji and Nakaumi, Japan. The denitrifying activity increased from summer through autumn and was positively correlated with the temperature of the overlying water at all sites except one, where the bottom was always more reductive than at the other sites and there was no NO₃ ⁻ as a substrate for denitrification from spring to autumn. Moreover, the relationship between the denitrifying activity and the distance from the sea showed different trends in estuarine and lagoonal sediments. These spatial differences indicate that different factors regulate the denitrification in estuarine and lagoonal sediments. Denitrifying activity in estuarine sediment was regulated by the discharge of freshwater containing NO₃ ⁻ or organic matter, while in the lagoonal sediments the occurrence of nitrification via the intrusion of oxic seawater into the reductive sediment appears to be a key requirement for the process of denitrification. Therefore, the denitrifying activity in the lagoonal sediment appears to be greater near the sea. Water intrusion is one of the key factors controlling denitrification in coastal marine ecosystems by affecting the supply of substrate available for denitrification.     

Space-time distribution patterns of destructive earthquakes in the inner belt of central Japan: Activity intervals and locations of earthquakes

Based on a block structure model of the inner belt of central Japan, an examination was conducted of the space-time distribution patterns of destructiv magnitudes M 6.4 or greater (M =Japan Meteorological Agency Scale). The distribution patterns revealed a periodicity in earthquake activit seismic gaps. Major NW—SE trending left-lateral active faults divide the inner belt of central Japan into four blocks, 20–80 km wide. The occurrenc A.D. with M ≥ 6.4, which have caused significant damage, were documented in the inner belt of central Japan. The epicenters of these earthquakes close to the block boundaries.

Using the relationship between the magnitude of earthquakes which occurred in the Japanese Islands and the active length of faults that generated them, movement is calculated for each historical earthquake. Space—time distributions of earthquakes were obtained from the calculated lengths, the latitud of generation. When an active period begins, a portion or segment of the block boundary creates an earthquake, which in turn appears on the ground surf active period ends when the block boundary generates earthquakes over the entire length of the block boundary without overlapping.

Five seismic gaps with fault lengths of 20 km or longer can be found in the inner belt of central Japan. It is predicted that the gaps will generate ea magnitudes of 7.0. These data are of significance for estimating a regional earthquake risk over central Japan in the design of large earthquake resist

The time sequences of earthquakes on the block boundaries reveal a similar tendency, with alternating active periods with seismic activity and quiet pe activity. The inner belt of central Japan is now in the last stage of an active period. The next active period is predicted to occur around 2500 A.D.