High-sensitive measurement of uranium LIII-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials

The uranium L_III-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg⁻¹ were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U L_III-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.     

Fault configuration produced by initial arc rifting in the Parece Vela Basin as deduced from seismic reflection data

Abstract   The Parece Vela Basin (PVB), which is a currently inactive back-arc basin of the Philippine Sea Plate, was formed by separation between the Izu-Ogasawara Arc (IOA) and the Kyushu-Palau Ridge (KPR). Elucidating the marks of the past back-arc opening and rifting is important for investigation of its crustal structure. To image its fault configurations and crustal deformation, pre-stack depth migration to multichannel seismic reflection was applied and data obtained by the Japan Agency for Marine-Earth Science and Technology and Metal Mining Agency of Japan and Japan National Oil Corporation (Japan Oil, Gas and Metals National Corporation). Salient results for the pre-stack depth-migrated sections are: (i) deep reflectors exist around the eastern margin of KPR and at the western margin of IOA down to 8 km depth; and (ii) normal fault zones distributed at the eastern margin of the KPR (Fault zone A) and the western margin of the IOA (Fault zone B) have a total displacement of greater than 500 m associated with synrift sediments. Additional normal faults (Fault zone C) exist 20 km east of the Fault zone B. They are covered with sediment, which indicates deposition of recent volcanic products in the IOA. According to those results: (i) the fault displacement of more than 500 m with respect to initial rifting was approximately asymmetric at 25 Ma based on PSDM profiles; and (ii) the faults had reactivated after 23 Ma, based on the age of deformed sediments obtained from past ocean drillings. The age of the base sediments corresponds to those of spreading and rotation after rifting in the PVB. Fault zone C is covered with thick and not deformed volcanogenic sediments from the IOA, which suggests that the fault is inactive.     

A practical model to estimate photosynthetically active radiation using general meteorological elements in a temperate humid area and comparison among models

Although accurately evaluating photosynthetically active radiation is important, much effort is required to measure this radiation using a quantum sensor. We develop a new model that makes estimates using only general meteorological data—solar radiation, atmospheric pressure, air temperature, and relative humidity. Root mean square deviations for eight datasets at five sites in Japan were smaller than 5.2 %, similar to error in other studies and to individual differences of quantum sensors. Most root mean square deviations of nine previous models and our eight datasets are larger than that of the new estimation model, which performed well. This suggests that the model is useful for estimating photosynthetically active radiation in a temperate, humid area of Japan.     

Pre-Japan-ARGO: Experimental Observation of Upper and Middle Layers South of the Kuroshio Extension Region Using Profiling Floats

We deployed two profiling floats in the region south of the Kuroshio Extension in March 2000. Temperature and salinity profiles from a depth of 1500 × 10⁴ Pa to the surface are reported every two and four weeks, respectively. The floats performed very well for first four months after deployment. Later they failed in surfacing for a few months when the sea surface temperature in the region was high. The salinity sensors seemed to suffer from some damage during their failure-in-surfacing period. Despite this trouble, the results clearly demonstrate that the profiling float is a very useful and cost-effective tool for physical oceanographic observation in the open sea. This revised version was published online in July 2006 with corrections to the Cover Date.     

银离子和含银不锈钢的抗菌性研究

基于银因其具有良好的广谱抗茵活性和低毒性而在医学方面有着较为广泛的应用,对银离子(硝酸银)和含银不锈钢的抗茵活性进行了初步研究。实验结果表明,在10^6CFu／mL的初始接种浓度下,银离子对枯草杆菌、大肠杆菌和假单胞茵的最小抑茵质量浓度和最小杀菌质量浓度分别为2,6,8mg／L和2,8,10mg／L。大肠杆菌经8mg／L的银离子处理2h后,有99．9％以上的细菌被破坏。含银不锈钢也表现了较强的抗菌性能。在普通的、银合金和银涂层的sus304不锈钢表面附着的单层生物膜浸泡在PBS溶液中3d后,经CFDA-DAPI双染色和荧光显微镜观察计数获得的假单胞菌的平均存活率为98．0％,38．5％和15．1％。     

Structural characteristics off Miyagi forearc region, the Japan Trench seismogenic zone, deduced from a wide-angle reflection and refraction study

The Japan Trench subduction zone, located east of NE Japan, has regional variation in seismicity. Many large earthquakes occurred in the northern part of Japan Trench, but few in the southern part. Off Miyagi region is in the middle of the Japan Trench, where the large earthquakes (M > 7) with thrust mechanisms have occurred at an interval of about 40 years in two parts: inner trench slope and near land. A seismic experiment using 36 ocean bottom seismographs (OBS) and a 12,000 cu. in. airgun array was conducted to determine a detailed, 2D velocity structure in the forearc region off Miyagi. The depth to the Moho is 21 km, at 115 km from the trench axis, and becomes progressively deeper landward. The P-wave velocity of the mantle wedge is 7.9–8.1 km/s, which is typical velocity for uppermost mantle without large serpentinization. The dip angle of oceanic crust is increased from 5–6° near the trench axis to 23° 150 km landward from the trench axis. The P-wave velocity of the oceanic uppermost mantle is as small as 7.7 km/s. This low-velocity oceanic mantle seems to be caused by not a lateral anisotropy but some subduction process. By comparison with the seismicity off Miyagi, the subduction zone can be divided into four parts: 1) Seaward of the trench axis, the seismicity is low and normal fault-type earthquakes occur associated with the destruction of oceanic lithosphere. 2) Beneath the deformed zone landward of the trench axis, the plate boundary is characterized as a stable sliding fault plain. In case of earthquakes, this zone may be tsunamigenic. 3) Below forearc crust where P-wave velocity is almost 6 km/s and larger: this zone is the seismogenic zone below inner trench slope, which is a plate boundary between the forearc and oceanic crusts. 4) Below mantle wedge: the rupture zones of thrust large earthquakes near land (e.g. 1978 off Miyagi earthquake) are located beneath the mantle wedge. The depth of the rupture zones is 30–50 km below sea level. From the comparison, the rupture zones of large earthquakes off Miyagi are limited in two parts: plate boundary between the forearc and oceanic crusts and below mantle wedge. This limitation is a rare case for subduction zone. Although the seismogenic process beneath the mantle wedge is not fully clarified, our observation suggests the two possibilities: earthquake generation at the plate boundary overridden by the mantle wedge without serpentinization or that in the subducting slab.     

Structural characteristics controlling the seismicity crustal structure of southern Japan Trench fore-arc region, revealed by ocean bottom seismographic data

The Japan Trench is a plate convergent zone where the Pacific Plate is subducting below the Japanese islands. Many earthquakes occur associated with plate convergence, and the hypocenter distribution is variable along the Japan Trench. In order to investigate the detailed structure in the southern Japan Trench and to understand the variation of seismicity around the Japan Trench, a wide-angle seismic survey was conducted in the southern Japan Trench fore-arc region in 1998. Ocean bottom seismometers (15) were deployed on two seismic lines: one parallel to the trench axis and one perpendicular. Velocity structures along two seismic lines were determined by velocity modeling of travel time ray-tracing method. Results from the experiment show that the island arc Moho is 18–20 km in depth and consists of four layers: Tertiary and Cretaceous sedimentary rocks, island arc upper and lower crust. The uppermost mantle of the island arc (mantle wedge) extends to 110 km landward of the trench axis. The P-wave velocity of the mantle wedge is laterally heterogeneous: 7.4 km/s at the tip of the mantle wedge and 7.9 km/s below the coastline. An interplate layer is constrained in the subducting oceanic crust. The thickness of the interplate layer is about 1 km for a velocity of 4 km/s. Interplate layer at the plate boundary may cause weak interplate coupling and low seismicity near the trench axis. Low P-wave velocity mantle wedge is also consistent with weak interplate coupling. Thick interplate layer and heterogeneous P-wave velocity of mantle wedge may be associated with the variation of seismic activity.     

钢材在海水—海气变换界面区的腐蚀行为

于1993年9月通过对241A，24KU，SS41三个不同钢种极化曲线的测定，对镜层本身的氧化还原电流的测定及X线分析，研究在海水一海气交换界面区锈层在腐蚀中所起的作用。结果表明，海一气交换界面区的钢由于锈层本身的氧化还原反应，其阴极电流均较裸钢为大，这说明锈层的还原反应起着重要作用．根据锈层本身的还原时间和还原电位，可以在某种程度上评价钢材本身耐腐蚀性能的好坏。     

阴极保护时碳钢的交流阻抗特性和最佳防蚀电位

测定了在3.5％食盐水中碳钢的法拉第交流阻抗,其结果与理论解析结果一致。阴极保护的实际效率(保护效率p和保护电流利用率q的乘积即r=p×q)在腐蚀电位E′_(cor)附近表现出最大值,这个电位可以认为是阴极保护的最佳保护电位。由于法拉第交流阻抗值容易被测得,为此提出了一种对阴极保护系统进行监测管理的一种新方法。