生物质燃烧颗粒物有机示踪化合物的测定和应用

使用气相色谱-质谱法对2002年7月-2003年7月的北京市大气粗、细颗粒物样品中的左旋葡聚糖等糖类化合物进行了测定。结果表明，左旋葡聚糖主要存在于细颗粒中，可以作为示踪化合物来研究生物质燃烧现象。生物质燃烧对北京市大气颗粒物有较重要的贡献。对应于12％-40％的PM2.5有机碳和10％-33％的PM10有机碳。北京市在2002年10月和11月受到明显的生物质燃烧的影响，可能由于农田秸杆焚烧和秋季落叶焚烧。2003年5月7日颗粒物样品受到直线距离约为1000km以外的内蒙古自治区呼伦贝尔市大兴安岭林区森林大火烟雾的影响。生物质燃烧事件具有突发性，可以长距离传输；生物质作为农村生物燃料的使用其燃烧排放具有经常性和持久性的特征。     

Comparison of volumetric and remote sensing methods (TLS) for assessing the development of a permanent forested loess gully

The gully systems develop a compact network dissecting the loess cover of the NW part of the Lublin Upland. They are overgrown by dense and multi-storey forest assemblages. It is very difficult to apply teledetection techniques, GPS positioning, and geodesic tools, such as a laser rangefinder or total station, for monitoring of gully development. The detailed research, involving the comparison of traditional and modern methods, was conducted in a gully with a secondary erosional dissection, developing in the gully bottom with varied intensity for the last 15 years. In the period of comparative research (2012/2013), the rate of development of the erosional dissection was measured by means of traditional methods as well as a Leica HDS 7000 laser scanner. 3D laser scanning permitted precise terrain modelling and the assessment of qualitative and quantitative spatial changes. This paper compares the results of three measurement campaigns. The analysis showed intensive development of the dissection, manifested in an increase in its volume (37 %), retreat of the erosion scarp (32 m), deep erosion (19 %), and lateral erosion (27 %). Registered moderate snowmelt in 2013 caused the volume dissection to increase by 57 m³, mainly as a result of the gully bottom scouring. During heavy rainfalls in June, the landforms were widened by a further 217 m³ and observed deepening and widening of erosive potholes. The prevalence of deep erosion resulted in the transformation back into a V-shaped cross section. A total of 37.3 Mg km⁻² of material was discharged from the gully catchment during snowmelt runoffs in 2013. A precipitation event in June 2013 caused the discharge of 856.9 Mg km⁻² of material from the catchment. The obtained results confirm that snowmelt erosion determines the spatial development of perennial gullies, but the volume of material discharged from the catchment depends on the occurrence of extreme precipitation during the warm season.

     

Changeability of Movable Bed‐Surface Particles in Natural,Gravel‐Bed Channels and Its Relation to Bedload Grain Size Distribution (Scott River,Svalbard)

The presented paper analyses the variability of grain size distribution parameters of bedload transported by the gravel‐bed Scott River (Svalbard) draining a glacier catchment with an area of 10 km². The grain size distribution analysis is one of the basic elements of identification of the fluvial transport mechanisms in gravel‐bed rivers. It is used for the determination of threshold values for bedload movement. It is also treated as an important indicator of the origin, routes of distribution, and conditions of transport and deposition of fluvial bedload. The field study in a natural proglacial gravel‐bed channel was carried out at two reaches in the mouth section of Scott River. The study revealed relatively high temporal variability and similar mean parameters of grain size distribution in conditions of low discharges. Bedload transport rates reached a mean of 71.9–76.0 kg d^?1 in channel cross‐section. Bedload texture was dominated by gravels with a proportional contribution of the fine‐grained fraction along with very fine‐grained gravels (8‐2 mm) of 38.8%. The medium‐grained fraction (16‐8 mm) constituted 33.7%, with a lower contribution from the coarse‐grained fraction (32‐16 mm) of 23.2%, and the very coarse‐grained fraction (64‐32 mm) of 4.4%. Two periods in the course of bedload transport and distribution of grain size distribution parameters were distinguished based on variation of hydro‐meteorological conditions. The first half of the measurement period was distinguished by significantly higher values of daily loads and increased contribution of the coarse‐grained and very coarse‐grained fraction (28–31% and 6.2–6.6%, respectively). During this time, the river discharged up to 94% of bedload. This resulted in a clear tendency for riverbed scouring. The second half was distinguished by generally low daily bedload transport rates (<10 kg d^?1), an increase in contribution of fine‐ and very fine‐grained gravels (42–55.6%), and a change in the tendency to aggradation. Grain size indices were more varied, and grains were usually finer and better sorted. Selective transport processes, often related to redeposition, were dominant in the channel. Along with an increase in flow velocity, conditions for material deposition became more variable. This was manifested in weaker sorting and an increase in grain diameter.     

Mechanics of a sandy subsoil subjected to cyclic loadings

A simple model for compaction of a sand, that may be useful in various geotechnical applications is presented. The model has been formulated in terms of the cyclic stress and strain amplitudes. The compaction properties of a dry sand are characterized by a common compaction curve described by two coefficients. The second aim of this paper is to show some applications of the theory proposed. The attention has been restricted to the two extreme cases of practical importance, namely to the behaviour of a dry sand (or a saturated sand but in free draining conditions), and to the behaviour of saturated sand in undrained conditions. Some numerical algorithms showing how to deal with those problems are presented and illustrated on the following examples: settlement and pore pressure generation in a soil stratum subjected to an earthquake, settlement of a foundation, pore pressure generation and liquefaction in a sea-bed. The results obtained suggest that the model proposed, as well as a method of dealing with boundary value problems can serve as a useful tool for the analysis of a sandy subsoil subjected to cyclic loadings.     

Integration of the elliptic restricted three-body problem with Lie series

The method of Lie series is used to construct a solution for the elliptic restricted three body problem. In a synodic pulsating coordinate system, the Lie operator for the motion of the third infinitesimal body is derived as function of coordinates, velocities and true anomaly of the primaries. The terms of the Lie series for the solution are then calculated with recurrence formulae which enable a rapid successive calculation of any desired number of terms. This procedure gives a very useful analytical form for the series and allows a quick calculation of the orbit.The project is supported by the Austrian Fonds zur Förderung der wissénschaftlichen Forschung under Project No. 4471.     

Reaction of soil enzymes and spring barley to copper chloride and copper sulphate

Study was carried out to compare the effect of the degree of contamination of soil with copper on the soil enzyme activity, depending on the type of chemical compound with which a metal reaches the soil and on the method of soil use. An effect of increasing doses of copper on growth and the development of spring barley has been studied. The study was carried out as a pot experiment on two types of soil: loamy sand and light loam. Copper was introduced to soil as copper(II) sulphate(VI) and copper(II) chloride at four doses: 150, 300, 450 and 600 mg Cu²⁺ kg^?1 d.m. of soil. Soil without copper was used as a control sample. The experiment showed that contamination of soil with copper applied as CuCl₂ and CuSO₄·5H₂O upset the homeostasis of soil. Dehydrogenases and urease were the most sensitive to contamination of soil with Cu²⁺, both as copper(II) chloride and as copper(II) sulphate(VI), and acid phosphatase and alkaline phosphatase were the least sensitive. Greater changes in enzymatic activity were observed in loamy sand than in light loam. The differences in the impact of copper(II) sulphate(VI) and copper(II) chloride on the soil microbiome were relatively small, because mean ED₅₀ for copper(II) chloride was 341 mg Cu²⁺ kg^?1 d.m. of soil, and for copper(II) sulphate(VI) it was 364 mg Cu²⁺ kg^?1 d.m. of soil. This inhibitory effect of copper persisted throughout the period of the experiment. The sensitivity of spring barley to copper compounds was lower than the enzymes under study.     

The role of biophysical interactions within the ijzermonding tidal flat sediment dynamics

This paper focuses on the importance of biophysical interactions on short-term and long-term sediment dynamics. Therefore, various biological (macrobenthos, photopigments, colloidal EPS) and physical parameters (grain size, water content, sediment stability, bed level) were determined (bi)monthly in nine sampling plots on the IJzermonding tidal flat (Belgium, 51°08′N, 2°44′E) during three consecutive years (July 2005–June 2008). Results showed that sediment stability varied on the short timescale and was directly influenced by biota, while bed level varied mainly on the long-term due to interannual variability. The short-term dynamic relationships between mud content, water content, fucoxanthin and macrobenthos density resulted in a seasonal mud deposition and erosion cycle, and directly influenced sediment stability. Moreover, macrobenthos was proven to be the most important parameter determining sediment stability. On the long-term, a shift was observed from high fucoxanthin/chla concentration, high mud content and zero to moderate densities of Corophium volutator towards low fucoxanthin/chl a and mud content and high Corophium densities, which resulted in a transition from net accretion to net erosion. However, most measured variables proved to be poor predictors for these long-term bed level changes, indicating that external physical forces, such as waves and storminess, probably were the most important factors triggering long-term sediment dynamics. Nevertheless, biota indirectly influenced bed level changes by mediating short-term changes in sediment stability, thereby influencing the erodability of the sediment. The macrobenthos, and especially the mud shrimp Corophium, was suggested as the (indirect) driving destabilising factor for the sampling plots in the IIzermonding when considering the long-term evolution.     

Electrical structure of the upper mantle beneath Central Europe: Results of the CEMES project

In the years 2001–2003, we accomplished the experimental phase of the project CEMES by collecting long-period magnetotelluric data at positions of eleven permanent geomagnetic observatories situated within few hundreds kilometers along the south-west margin of the East European Craton. Five teams were engaged in estimating independently the magnetotelluric responses by using different data processing procedures. The conductance distributions at the depths of the upper mantle have been derived individually beneath each observatory. By averaging the individual cross-sections, we have designed the final model of the geoelectrical structure of the upper mantle beneath the CEMES region. The results indicate systematic trends in the deep electrical structure of the two European tectonic plates and give evidence that the electrical structure of the upper mantle differs between the East European Craton and the Phanerozoic plate of west Europe, with a separating transition zone that generally coincides with the Trans-European Suture Zone.