Elemental composition of individual chondrules from carbonaceous chondrites,including Allende

Major and trace element analyses of over 180 individual chondrules from 12 carbonaceous chondrites are reported, including individual analyses of 60 chondrules from Pueblito de Allende. Siderophile elements in most chondrules are depleted, compared to the whole chondrite. Correlations of Al-Ir and Ir-Sc among chondrules high in Ca and Al were observed. A Cu-Mn correlation was also found for chondrules from some meteorites. No correlation was observed between Au and other siderophile elements (Fe, Ni, Co and Ir). It is suggested that these elemental associations were present in the material from which the chondrules formed. Compositionally, chondrules appear to be a multicomponent mixture of remelted dust. One component displaying an Al-Ir correlation is identified as Allende-type white aggregates. The other components are a material chemically similar to the present matrix and sulfides-plus-metal material. Abundances of the REE (rare earth elements) were measured in ‘ordinary’ Allende chondrules and were 50% higher than REE abundances in Mokoia chondrules; REE abundances in Ca-Al rich chondrules were similar to REE abundances in Ca-rich white aggregates.     

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.     

Tectonic implications of new age data for the Meratus Complex of south Kalimantan, Indonesia

Cretaceous subduction complexes surround the southeastern margin of Sundaland in Indonesia. They are widely exposed in several localities, such as Bantimala (South Sulawesi), Karangsambung (Central Java) and Meratus (South Kalimantan).
The Meratus Complex of South Kalimantan consists mainly of mélange, chert, siliceous shale, limestone, basalt, ultramafic rocks and schists. The complex is uncomformably covered with Late Cretaceous sedimentary-volcanic formations, such as the Pitap and Haruyan Formations.
Well-preserved radiolarians were extracted from 14 samples of siliceous sedimentary rocks, and K–Ar age dating was performed on muscovite from 6 samples of schist of the Meratus Complex. The radiolarian assemblage from the chert of the complex is assigned to the early Middle Jurassic to early Late Cretaceous. The K–Ar age data from schist range from 110 Ma to 180 Ma. Three samples from the Pitap Formation, which unconformably covers the Meratus Complex, yield Cretaceous radiolarians of Cenomanian or older.
These chronological data as well as field observation and petrology yield the following constraints on the tectonic setting of the Meratus Complex.
(1) The mélange of the Meratus Complex was caused by the subduction of an oceanic plate covered by radiolarian chert ranging in age from early Middle Jurassic to late Early Cretaceous.
(2) The Haruyan Schist of 110–119 Ma was affected by metamorphism of a high pressure–low temperature type caused by oceanic plate subduction. Some of the protoliths were high alluminous continental cover or margin sediments. Intermediate pressure type metamorphic rocks of 165 and 180 Ma were discovered for the first time along the northern margin of the Haruyan Schist.
(3) The Haruyan Formation, a product of submarine volcanism in an immature island arc setting, is locally contemporaneous with the formation of the mélange of the Meratus Complex.     

Groundwater-level Changes Due to Pressure Gradient Induced by Nearby Earthquakes off Izu Peninsula, 1997

Anomalous water level changes were observed at two wells associated with seismic swarm activity off Izu Peninsula on March, 1997. These are coseismic water level drops followed by gradual postseismic water level rise at the time of large earthquakes during the swarm activity. The post-seismic water level rises, which can be fitted by an exponential function with a time constant of about six hours, are explained in terms of the horizontal pressure diffusion due to the pressure gradient in the aquifer induced by the coseismic static strain.     

Mesozoic radiolarians and radiolarian-bearing sequences in the circum-Pacific regions: A report of the symposium-'Radiolarians and Orogenic Belts'

Abstract This paper contains extended abstracts of the seven papers presented at the symposium 'Radiolarians and Orogenic Belts' held at the seventh meeting of the International Association of Radiolarian Paleontologists (INTERRAD). Important results of the symposium include the following: (1) Upper Paleozoic and Mesozoic cherts are widely distributed within accretionary complexes in the circum-Pacific orogenic belt. Radiolarian dating reveals that long durations of chert sedimentation in a pelagic environment are recorded on both sides of Pacific-rim accretionary complexes (e.g. New Zealand, Japan, Russian Far East, Canadian Cordillera). (2) Triassic radiolarian faunas from New Zealand and the Omolon Massif, northeast Siberia are similar in composition and are characterized by the absence of typical Tethyan elements. This suggests that radiolarian faunal provincialism may have been established as early as the Triassic. High-latitude radiolarian taxa exhibit a bi-polar distribution pattern. (3) The Lower Triassic interval in chert dominant pelagic sequences is mechanically weaker than other levels and acted as a décollement in accretionary events. This lithologic. contrast in physical property is considered to reflect radiolarian evolution, such as the end-Permian mass extinction.     

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.     

Correction to: El Niño-related sea surface elevation and ocean bottom pressure enhancement associated with the retreat of the Oyashio southeast of Hokkaido,Japan

Marine Geophysical Research - In the original publication, the Fig. 2 was published incorrectly. The correct version (Fig. 2) is given in this correction. The original article has been...     

Origin of the metamorphosed clasts in the CV3 carbonaceous chondrite breccias of Graves Nunataks 06101, Vigarano,Roberts Massif 04143, and Yamato‐86009

We observed metamorphosed clasts in the CV3 chondrite breccias Graves Nunataks 06101, Vigarano, Roberts Massif 04143, and Yamato‐86009. These clasts are coarse‐grained polymineralic rocks composed of Ca‐bearing ferroan olivine (Fa_24–40, up to 0.6 wt% CaO), diopside (Fs_7–12Wo_44–50), plagioclase (An_52–75), Cr‐spinel (Cr/[Cr + Al] = 0.4, Fe/[Fe + Mg] = 0.7), sulfide and rare grains of Fe‐Ni metal, phosphate, and Ca‐poor pyroxene (Fs₂₄Wo₄). Most clasts have triple junctions between silicate grains. The rare earth element (REE) abundances are high in diopside (REE ~3.80–13.83 × CI) and plagioclase (Eu ~12.31–14.67 × CI) but are low in olivine (REE ~0.01–1.44 × CI) and spinel (REE ~0.25–0.49 × CI). These REE abundances are different from those of metamorphosed chondrites, primitive achondrites, and achondrites, suggesting that the clasts are not fragments of these meteorites. Similar mineralogical characteristics of the clasts with those in the Mokoia and Yamato‐86009 breccias (Jogo et al. 2012 ) suggest that the clasts observed in this study would also form inside the CV3 chondrite parent body. Thermal modeling suggests that in order to reach the metamorphosed temperatures of the clasts of >800 °C, the clast parent body should have accreted by ~2.5–2.6 Ma after CAIs formation. The consistency of the accretion age of the clast parent body and the CV3 chondrule formation age suggests that the clasts and CV3 chondrites could be originated from the same parent body with a peak temperature of 800–1100 °C. If the body has a peak temperature of >1100 °C, the accretion age of the body becomes older than the CV3 chondrule formation age and multiple CV3 parent bodies are likely.