Multiforced statistical assessments of greenhouse-gas-induced surface air temperature change 1890–1985

Based on univariate correlation and coherence analyses and considering the physical basis of the relationships, a simple multiforced (multiple) statistical concept is used which correlates observational climatic time series simultaneously with volcanic, solar, ENSO, and the anthropogenic greenhouse gases forcing. This is appropriate to remove some natural climate noise in the observed data and to evaluate the components (signals) possibly due to the anthropogenic greenhouse gas forcing (CO₂, or equivalent CO₂ implying additional gases) during industrial time. In this paper, we apply this technique to 100 global box data time series 1890–1985, of the surface air temperature, using observed data from Hansen and Lebedeff. The results are presented in terms of latitudinal-seasonal and regional trends, where the observed trend patterns are compared with the hypothetical signals (statistical assessments) possibly due to anthropogenic greenhouse forcing. These latter signals can be amplified to enable a comparison with corresponding results from general circulation model (GCM) CO₂ doubling experiments. These observed-statistical assessments lead to results which are, at least qualitatively and in respect to the zonal mean temperatures, very similar to some GCM experiments indicating the maximum CO₂ doubling signals (statistical assessment > 12 K) in the arctic winter. However, these signals are moderate in the tropics and in the Southern Hemisphere (global average 2.8–4.4 K). As far as the industrial signals are concerned (observed period) these signals are somewhat larger (maximum 7 K, global average 0.5–0.9 K) than the observed trends (maximum 5 K, global average 0.5 K). Phase shifts of cause and effect may amplify these signals but are very uncertain.This paper was presented at the International Conference on Modelling of Global Climate Change and Variability, held in Hamburg 11–15 September 1989 under the auspices of the Meteorological Institute of the University of Hamburg and the Max Planck Institute for Meteorology. Guest Editor for these papers is Dr. L. Dümenil     

The role of flares, CMEs and CME shocks in the generation of solar energetic proton events

We examined solar energetic proton (SEP) events associated with intense H flares. We located these flares on the solar disk and obtained their distribution in heliographic longitude as well as their angular distance distribution with respect to the neutral lines corresponding to the heliospheric current sheet at 2.5R. We found that the SEP-associated H flares tend to occur in active regions at the feet of those helmet streamers which form the heliomagnetic equator and are related to coronal mass ejections (CMEs) and CME shocks. We discuss the possible role of flares, CMEs and CME shocks in generating SEPs.     

Boulder 1, Station 2, Apollo 17: Petrology and petrogenesis

Boulder 1, Station 2, Apollo 17 is a stratified boulder containing dark clasts and dark-rimmed light clasts set in a light-gray friable matrix. The gray to black clasts (GCBx and BCBx) are multigenerational, competent, high-grade metamorphic, and partially melted breccias. They contain a diverse suite of lithic clasts which are mainly ANT varieties, but include granites, basaltic-textured olivine basalts, troctolitic and spinel troctolitic basalts, and unusual lithologies such as KREEP norite, ilmenite (KREEP) microgabbro, and the Civet Cat norite, which is believed to be a plutonic differentiate. The GCBxs and BCBxs are variable in composition, averaging a moderately KREEPy olivine norite. The matrix consists of mineral fragments derived from the observed lithologies plus variable amounts of a component, unobserved as a clast-type, that approximates a KREEP basalt in composition, as well as mineral fragments of unknown derivation. The high-temperature GCBxs cooled substantially before their incorporation into the friable matrix of Boulder 1. The light friable matrix (LFBx) is texturally distinct from the competent breccia clasts and, apart from the abundant ANT clasts, contains clasts of a KREEPy basalt that is not observed in the competent breccias. The LFBx lacks such lithologies as the granites and the Civet Cat norite observed in the competent breccias and in detail is a distinct chemical as well as textural entity. We interpret the LFBx matrix as Serenitatis ejecta deposited in the South Massif, and the GCBx clasts as remnants of an ejecta blanket produced by an earlier impact. The source terrain for the Serenitatis impact consisted of the competent breccias, crustal ANT lithologies, and the KREEPy basalts, attesting to substantial lunar activity prior to the impact. The age of the older breccias suggests that the Serenitatis event is younger than 4.01±0.03 b.y.     

Mercury speciation and mobilization in contaminated soils of the Valle del Azogue Hg mine (SE,Spain)

Hg mobilization from contaminated soils and mine wastes was the source of environmental contamination in the Valle del Azogue mining area. We researched solid-phase speciation and aqueous mobility of Hg through Scanning electron microscopy-energy dispersive X-ray spectroscopy and electron probe microanalysis analysis, solid-phase-Hg-thermo-desorption (SPTD) and laboratory column experiments. We found that in contaminated soils and mine wastes, the predominant Hg species was cinnabar (HgS), mainly formed from the weathering of Hg-rich pyrite, and metallic Hg (0) in the matrix, whereas in calcines and tailings the dominant species was metallic Hg (0). The mobilization of Hg in the aqueous phase seems to have originated from the dissolution of elemental Hg (0) present in soils and wastes, reaching concentrations of up to 67 μg l⁻¹, and showing a higher long-term environmental potential risk, in addition to atmospheric emissions.     

Land-Parcel Land-Use History as a Key to Site Selection for Documenting Soil Contamination Risk： a Case Study from Australian Suburbia

In that orcharding in early-to-mid twentieth century southeastern Australia involved use of certain heavy metal and As compounds in regular pest-control spray procedures, some interest attaches to the possibility that these landparcels are underlain by soils with above-background Cu, Pb and As levels. Interpreta- tion of Land-cover changes allowed land parcels previously occupied by orchards to be identified in the 1950s through time-series air-photos. A comparison of soil analysis results referring to soil samples from control sites, and from land parcels formerly occupied by orchardists, shows that contamination （above-background） levels of cations in the pesticides can be found in the top 6 cm of former orchard soils. It is clear that digital spatial data handling and culturally-informed air photo interpretation has a place in soil contamination studies, land-use planning （with particular reference to re-development） and in administration of public health.     

Landscape controls on long‐term runoff in subhumid heterogeneous Boreal Plains catchments

We compared median runoff (R) and precipitation (P) relationships over 25 years from 20 mesoscale (50 to 5,000 km²) catchments on the Boreal Plains, Alberta, Canada, to understand controls on water sink and source dynamics in water‐limited, low‐relief northern environments. Long‐term catchment R and runoff efficiency (RP^?1) were low and varied spatially by over an order of magnitude (3 to 119 mm/year, 1 to 27%). Intercatchment differences were not associated with small variations in climate. The partitioning of P into evapotranspiration (ET) and R instead reflected the interplay between underlying glacial deposit texture, overlying soil‐vegetation land cover, and regional slope. Correlation and principal component analyses results show that peatland‐swamp wetlands were the major source areas of water. The lowest estimates of median annual catchment ET (321 to 395 mm) and greatest R (60 to 119 mm, 13 to 27% of P) were observed in low‐relief, peatland‐swamp dominated catchments, within both fine‐textured clay‐plain and coarse‐textured glacial deposits. In contrast, open‐water wetlands and deciduous‐mixedwood forest land covers acted as water sinks, and less catchment R was observed with increases in proportional coverage of these land covers. In catchments dominated by hummocky moraines, long‐term runoff was restricted to 10 mm/year, or 2% of P. This reflects the poor surface‐drainage networks and slightly greater regional slope of the fine‐textured glacial deposit, coupled with the large soil‐water and depression storage and higher actual ET of associated shallow open‐water marsh wetland and deciduous‐forest land covers. This intercatchment study enhances current conceptual frameworks for predicting water yield in the Boreal Plains based on the sink and source functions of glacial landforms and soil‐vegetation land covers. It offers the capability within this hydro‐geoclimatic region to design reclaimed catchments with desired hydrological functionality and associated tolerances to climate or land‐use changes and inform land management decisions based on effective catchment‐scale conceptual understanding.     

Microbial photosynthesis in coral reef sediments (Heron Reef, Australia)

We investigated microphytobenthic photosynthesis at four stations in the coral reef sediments at Heron Reef, Australia. The microphytobenthos was dominated by diatoms, dinoflagellates and cyanobacteria, as indicated by biomarker pigment analysis. Conspicuous algae firmly attached to the sand grains (ca. 100 μm in diameter, surrounded by a hard transparent wall) were rich in peridinin, a marker pigment for dinoflagellates, but also showed a high diversity based on cyanobacterial 16S rDNA gene sequence analysis. Specimens of these algae that were buried below the photic zone exhibited an unexpected stimulation of respiration by light, resulting in an increase of local oxygen concentrations upon darkening. Net photosynthesis of the sediments varied between 1.9 and 8.5 mmol O₂ m⁻² h⁻¹ and was strongly correlated with Chl a content, which lay between 31 and 84 mg m⁻². An estimate based on our spatially limited dataset indicates that the microphytobenthic production for the entire reef is in the order of magnitude of the production estimated for corals. Photosynthesis stimulated calcification at all investigated sites (0.2–1.0 mmol Ca²⁺ m⁻² h⁻¹). The sediments of at least three stations were net calcifying. Sedimentary N₂-fixation rates (measured by acetylene reduction assays at two sites) ranged between 0.9 to 3.9 mmol N₂ m⁻² h⁻¹ and were highest in the light, indicating the importance of heterocystous cyanobacteria. In coral fingers no N₂-fixation was measurable, which stresses the importance of the sediment compartment for reef nitrogen cycling.